1. Spin-glass transition in Ni carbide single crystal nanoparticles with Ni3C − type structure
- Author
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S. Fujieda, T. Kuboniwa, K. Shinoda, S. Suzuki, and J. Echigoya
- Subjects
Physics ,QC1-999 - Abstract
Hexagonal shaped nanoparticles about 60 nm in size were successfully synthesized in tetraethylene glycol solution containing polyvinylpyrrolidone. By the analysis of the electron diffraction pattern, these were identified as a single crystal of Ni carbide with Ni3C − type structure. Their magnetization curve at 5 K was not completely saturated under a magnetic field of 5 T. The thermomagnetization curves after zero-field cooling and after field cooling exhibited the magnetic cooling effect at low temperatures. Furthermore, the 2nd order nonlinear term of AC magnetic susceptibility exhibited a negative divergence at about 17 K. It is concluded that Ni carbide single crystal nanoparticles with the Ni3C − type structure exhibit spin-glass transition at low temperatures.
- Published
- 2016
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