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Copyright of Baghdad Science Journal is the property of Republic of Iraq Ministry of Higher Education & Scientific Research (MOHESR) and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Intact tropical peatlands are dense long-term stores of carbon. However, the future security of these ecosystems is at risk from land conversion and extensive peatland drainage. This can enhance peat oxidation and convert long-term carbon sinks into significant carbon sources. In Southeast Asia, the largest land use on peatland is for oil palm plantation agriculture. Here, we present the first annual estimate of exported fluvial organic carbon in the drainage waters of four peatland oil palm plantation areas in Sarawak, Malaysia. Total organic carbon (TOC) fluxes from the plantation second- and third-order drains were dominated (91 %) by dissolved organic carbon (DOC) and ranged from 34.4 ± 9.7 C m -2 yr -1 to 57.7 %, 16.3 g C m -2 yr -1 (± 95 % confidence interval). These fluxes represent a single-year survey which was strongly influenced by an El Ninõ event and therefore lower discharge than usual was observed. The magnitude of the flux was found to be influenced by water table depth, with higher TOC fluxes observed from more deeply drained sites. Radiocarbon dating on the DOC component indicated the presence of old (pre-1950s) carbon in all samples collected, with DOC at the most deeply drained site having a mean age of 735 years. Overall, our estimates suggest fluvial TOC contributes ∼ 5 % of total carbon losses from oil palm plantations on peat. Maintenance of high and stable water tables in oil palm plantations appears to be key to minimising TOC losses. This reinforces the importance of considering all carbon loss pathways, rather than just CO2 emissions from the peat surface, in studies of tropical peatland land conversion. [ABSTRACT FROM AUTHOR]

Intact tropical peatlands are dense, long-term stores of carbon. However, the future security of these ecosystems is at risk from land conversion and extensive peatland drainage. This can enhance peat oxidation and convert long-term carbon sinks into significant carbon sources. In Southeast Asia, the largest land use on peatland is for oil palm plantation agriculture. Here, we present the first annual estimate of exported fluvial organic carbon in the drainage waters of four peatland oil palm plantation areas in Sarawak, Malaysia. Total organic carbon (TOC) fluxes from the plantation second and third order drains were dominated by dissolved organic carbon (DOC) and ranged from 34.4 ± 9.7 C m-2 yr-1 to 57.7 ± 16.3 g C m-2 yr-1 (± 95 % confidence interval). The magnitude of the flux was found to be influenced by water table depth, with higher TOC fluxes observed from more deeply drained sites. Radiocarbon dating on the DOC component indicated the presence of old (pre-1950s) carbon in all samples collected, with DOC at the most deeply drained site having a mean age of 735 years. Overall, our estimates suggest fluvial TOC contributes ~ 5 % of total carbon losses from oil palm plantations on peat. Maintenance of high and stable water tables in oil palm plantations appears to be key to minimising TOC losses. This reinforces the importance of considering all carbon loss pathways, rather than just CO2 emissions from the peat surface, in studies of tropical peatland land conversion. [ABSTRACT FROM AUTHOR]

Estimating daily evapotranspiration is challenging when ground observation data are not available or scarce. Remote sensing can be used to estimate the meteorological data necessary for calculating reference evapotranspiration ETₒ. Here, we assessed the accuracy of daily ETₒ estimates derived from remote sensing (ETₒ-RS) compared with those derived from four ground-based stations (ETₒ-G) in Kurdistan (Iraq) over the period 2010-2014. Near surface air temperature, relative humidity and cloud cover fraction were derived from the Atmospheric Infrared Sounder/Advanced Microwave Sounding Unit (AIRS/AMSU), and wind speed at 10 m height from MERRA (Modern-Era Retrospective Analysis for Research and Application). Four methods were used to estimate ETₒ: Hargreaves-Samani (HS), Jensen-Haise (JH), McGuinness-Bordne (MB) and the FAO Penman Monteith equation (PM). ETₒ-G (PM) was adopted as the main benchmark. HS underestimated ETₒ by 2%-3% (R² = 0.86 to 0.90; RMSE = 0.95 to 1.2 mm day-1 at different stations). JH and MB overestimated ETₒ by 8% to 40% (R² = 0.85 to 0.92; RMSE from 1.18 to 2.18 mm day-1). The annual average values of ETₒ estimated using RS data and ground-based data were similar to one another reflecting low bias in daily estimates. They ranged between 1153 and 1893 mm year-1 for ETₒ-G and between 1176 and 1859 mm year-1 for ETₒ-RS for the different stations. Our results suggest that ETₒ-RS (HS) can yield accurate and unbiased ETₒ estimates for semi-arid regions which can be usefully employed in water resources management. [ABSTRACT FROM AUTHOR]

Rainfall-runoff modelling is a useful tool for water resources management. This study presents a simple daily rainfall-runoff model, based on the water balance equation, which we apply to the 11,630 km2 Lesser Zab catchment in northeast Iraq. The model was forced by either observed daily rain gauge data from four stations in the catchment or satellite-derived rainfall estimates from two TRMM Multi-satellite Precipitation Analysis (TMPA) data products (TMPA-3B42 and 3B42RT) based on the Tropical Rainfall Measuring Mission (TRMM) from 2003 to 2014. As well as using raw TMPA data, we used a bias-correction method to adjust TMPA values based on rain gauge data. The uncorrected TMPA data products underestimated observed mean catchment rainfall by [ABSTRACT FROM AUTHOR]

Widespread pollution of groundwater by nutrients due to 20th century agricultural intensification has been of major concern in the developed world for several decades. This paper considers the River Thames catchment (UK), where water-quality monitoring at Hampton (just upstream of London) has produced continuous records for nitrate for the last 140 years, the longest continuous record of water chemistry anywhere in the world. For the same period, data are available to characterize changes in both land use and land management at an annual scale. A modeling approach is used that combines two elements: an estimate of nitrate available for leaching due to land use and land management; and, an algorithm to route this teachable nitrate through to surface or groundwaters. Prior to agricultural intensification at the start of World War II, annual average inputs were around 50 kg ha-1, and river concentrations were stable at 1 to 2 mg l-1, suggesting in-stream denitrification capable of removing 35 (±15) kt N yr-1. Postintensification data suggest an accumulation of 100 (±40) kt N yr-1 in the catchment, most of which is stored in the aquifer. This build up of reactive N species within the catchments means that restoration of surface nitrate concentrations typical of the preintensification period would require massive basin-wide changes in land use and management that would compromise food security and take decades to be effective. Policy solutions need to embrace long-term management strategies as an urgent priority. [ABSTRACT FROM AUTHOR]

Widespread pollution of groundwater by nutrients due to 20th century agricultural intensification has been of major concern in the developed world for several decades. This paper considers the River Thames catchment (UK), where water-quality monitoring at Hampton (just upstream of London) has produced continuous records for nitrate for the last 140 years, the longest continuous record of water chemistry anywhere in the world. For the same period, data are available to characterize changes in both land use and land management at an annual scale. A modeling approach is used that combines two elements: an estimate of nitrate available for leaching due to land use and land management; and, an algorithm to route this leachable nitrate through to surface or groundwaters. Prior to agricultural intensification at the start of World War II, annual average inputs were around 50 kg ha−1, and river concentrations were stable at 1 to 2 mg l−1, suggesting in-stream denitrification capable of removing 35 (±15) kt N yr−1. Postintensification data suggest an accumulation of 100 (±40) kt N yr−1 in the catchment, most of which is stored in the aquifer. This build up of reactive N species within the catchments means that restoration of surface nitrate concentrations typical of the preintensification period would require massive basin-wide changes in land use and management that would compromise food security and take decades to be effective. Policy solutions need to embrace long-term management strategies as an urgent priority. [ABSTRACT FROM AUTHOR]

Environmental persistence is an important property that can enhance the potential of a chemical substance to exert adverse effects and be transported to remote environments. The persistence of organic compounds is governed by the rates at which they are removed by biological and chemical processes, such as biodegradation, hydrolysis, atmospheric oxidation, and photolysis. The persistence workgroup in a recent Society of Environmental Toxicology and Chemistry (SETAC) Pellston workshop (Pensacola, FL, USA, January 2008) focused on evaluating persistence of organic compounds in environmental media (air, water, soil, sediment) in terms of their single-medium degradation half-lives. The primary aim was to provide guidance to authors and reviewers of chemical dossiers for persistent organic pollutants (POPs) and persistent, bioaccumulative, and toxic substances (PBTs) proposed for action. A second objective was to provide a summary of the current state of the science with respect to POP fate assessment. Assessing the persistence of chemical substances in the environment is not straightforward. A common misconception is that, like many chemical properties, environmental persistence is an inherent property of the substance and can be readily measured. In fact, rates of degradation of a substance in the environment are determined by a combination of substance-specific properties and environmental conditions. This article addresses how persistence can be evaluated based on an assortment of supporting information. Special attention is given to several critical issues, including transformation products, nonextractable residues, and treatment of uncertainty and conflicting data as part of a weight-of-evidence assessment. [ABSTRACT FROM AUTHOR]