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In this work, we designed and synthesized a series of novel triazolopyridine fused-ring compounds with alternating nitro and amine groups. Three compounds showed remarkable thermal stability at 256, 310, and 294 °C, respectively, and a low mechanical sensitivity [impact sensitivity (IS) = 40 J, friction sensitivity (FS) = 324 N; IS = 35 J, FS = 240 N; and IS > 40 J, FS = 324 N, respectively]. Significantly, two of these compounds exhibited a better detonation performance [detonation velocity (D) = 8200 and 8335 m s–1 , Detonation pressure (P) = 25.6 and 27.2 GPa, respectively] than the widely used heat-resistant explosive hexanitrostilbene (HNS; D = 7612 m s–1 , P = 24.3 GPa). Additionally, a nitramine derivative displayed a detonation performance (D = 8569 m s–1 , P = 31.3 GPa) similar to that of the high-energy explosive RDX. The superior properties of the materials were further confirmed by X-ray diffraction analysis and by several theoretical calculations (ESP, LOL–π, Hirshfeld surfaces, RDG, and NCI analyses). These results indicated that the three compounds might be potential candidates for use as heat-resistant energetic materials. [ABSTRACT FROM AUTHOR]

With the increase in the demand for high‐performance composite explosives, the search for advanced energetic melt‐castable compounds has attracted increasing attention in the field of energetic materials. Herein, two new energetic materials with nitromethyl and azidomethyl substituents (1‐(nitromethyl)‐3,4‐dinitro‐1H‐pyrazole (NMDNP) and 1‐(azidomethyl)‐3,4‐dinitro‐1H‐pyrazole (AMDNP) were prepared by the substituent modification of a potential melt‐castable molecule ((3,4‐dinitro‐1H‐pyrazol‐1‐yl) methyl nitrate, MC‐4), respectively. NMDNP exhibited a suitable melting point (90 °C), good thermal stability (Td: 185 °C) and excellent detonation performance (8484 m s−1) and impact sensitivity (25 J), thereby demonstrating promise as an energetic melt‐castable material. Simultaneously, compared with the nitrato‐methyl and azidomethyl substituents, the nitromethyl substituent exhibited greater advantages in regulating performance. [ABSTRACT FROM AUTHOR]

A new strategy for hybrid deep eutectic solvents (DESs) that are hypergolic with hydrogen peroxide is developed, in which the introduction of transition metal components can effectively release the latent and generally unrecognized flammability of common DESs. This strategy illustrates a uniquely modular platform to develop cost-effective and green propellants. [ABSTRACT FROM AUTHOR]

N,N-Dimethyl-3,5-dinitro-1H-pyrazol-4-amine was prepared by the reaction of 4-chloro-3,5-dinitropyrazole and DMF at 100°C for 4 h. Based on this compound, four new energetic derivatives, i.e., N,N,1-trimethyl-3,5-dinitro-1H-pyrazol-4-amine, 1,1'-methanediylbis- (N,N-dimethyl-3,5-dinitro-1H-pyrazol-4-amine), 1,1'-ethane-1,2-diylbis(N,N-dimethyl-3,5-dinitro-1H-pyrazol-4-amine), and 1,1'-propane- 1,3-diylbis(N,N-dimethyl-3,5-dinitro-1H-pyrazol-4-amine), were prepared through nucleophilic reactions. The structures of the compounds were confirmed by single crystal X-ray diffraction. One of the synthesized compounds has promising melting point and thermal stability and can be considered as potential melt-castable explosive. [ABSTRACT FROM AUTHOR]

Energetic isomers often exhibit different properties. To understand the effect of arrangement and connection of isomers on energetic properties and sensitivity, in this study, we designed and synthesized a series of oxadiazole nitramine compounds including N-(5-(5-(nitramino)-1,3,4-oxadiazol-2-yl)-1,2,4-oxadiazol-3-yl)nitramide (NOON) and its ionic derivatives. NOON exhibits comparable performance (D = 8888 m s−1, P = 34.1 GPa) to highly explosive RDX. A comparative study of detonation properties, sensitivity, and thermal stability of the three oxadiazole nitramine isomers (NOON, ICM-101, and DNBO) is carried out. The results show that due to the proton transformation, strong intramolecular hydrogen bonding interaction, and formation of six-membered ring conformation, the 2-nitramino-1,3,4-oxadiazole building block exhibits better detonation properties and higher thermal stability than its isomer 2-nitramino-1,2,4-oxadiazole. [ABSTRACT FROM AUTHOR]

With the growth of chemical data, computation power and algorithms, machine learning-assisted high-throughput virtual screening (ML-assisted HTVS) is revolutionizing the research paradigm of new materials. Herein, a combined ML-assisted HTVS and experimental approach was applied to accelerate the search for energetic melt-castable materials with promising properties. The ML-assisted HTVS system is composed of high-throughput molecular generation (in a heuristic enumeration method) and five machine learning-based property prediction models (including density, melting point, decomposition temperature, detonation velocity, and detonation pressure). Using this system, we rapidly targeted 136 promising candidates from a generated molecular space containing 3892 molecules. With extensive efforts on experimental synthesis, eight new energetic melt-castable materials (MC-1 to MC-8) were obtained, and their measured properties were in good agreement with the predicted results. This work verifies the effectiveness of the combined ML-assisted HTVS and experimental approach for the accelerated discovery of energetic melt-castable materials. [ABSTRACT FROM AUTHOR]

The combination of Energetic Ionic Liquid (EIL) "green" fuels and high test peroxide (>90% H2O2; HTP), as a "green" oxidizer, is a very promising platform for the development of fully "green" bipropellants for space exploration. In this work, two new "tandem-action" promoters – [FcCH2N(CH3)3+]2[Cu2I42−] (P1) and [FcCH2N(CH3)3+]n[Cu2I3−]n (P2) – and two reference "single-action" promoters, [FcCH2N(CH3)3+][H3BCN−] (P3) and [CH3N(CH2CH3)3+]n[Cu2I3−]n (P4), were prepared, comprehensively characterized and evaluated for their ability to significantly shorten the Ignition Delay (ID) times of hypergolic reactions between a series of EILs and H2O2. These promoters exhibited high solubility and long-term chemical stability in a typical EIL fuel – 1-ethyl-3-methylimidazolium dicyanamide (F1). Upon screening the performance of promoter–EIL formulations, the best ID result of 31 ms was observed for the combination of 1-ethyl-3-methylimidazolium cyanoborohydride (F2) fuel and promoter P2 (10 wt%), with H2O2 (95%), whereas an ID time of 58 ms was observed for the F2/P2 formulation with commercially available H2O2 (70%), respectively. Remarkably, the latter formulation remained fully homogeneous even at −40 °C, and showed an ID time of 66 ms at this temperature with H2O2 (95%), indicating the advantages of our approach for the development of novel fully "green" bipropellants. [ABSTRACT FROM AUTHOR]

A series of novel fused‐ring pyrazolo[4,3‐c]pyrazole derivatives featuring N‐dinitromethyl and N‐fluorodinitromethyl energetic groups (compounds 3–7) were synthesized using a nine‐step reaction. All these compounds were characterized using multinuclear nuclear magnetic resonance (NMR) spectroscopy, infra‐red (IR) spectroscopy, and elemental analysis. X‐ray diffraction analysis was performed, and the single‐crystal structures of compounds 3, 4, 6, and 7 were obtained. For these newly prepared energetic materials, the thermal stability was determined using differential scanning calorimetry (DSC), while the sensitivities were evaluated using BAM drop hammer and friction test. The calculated heat of formation values and the measured densities were used to determine the detonation parameters, including detonation velocity and pressure, using the EXPLO5 program. Of all the prepared compounds, dipotassium 1,4‐bis(dinitromethyl)‐3,6‐dinitro‐1,4‐dihydropyrazolo[4,3‐c]pyrazole (3) was crystallized as a three‐dimensional energetic metal‐organic framework (MOF) and showed outstanding detonation performances, which even outperformed the traditional primary explosive lead azide. Compound 7 exhibited a high crystal density of 1.939 g cm−3, the high decomposition temperature of 213 °C and desirable impact and friction sensitivities (IS: 12 J; FS: 240 N). These combined properties and performances make these novel fused‐ring energetic compounds suitable candidates for high‐performance energetic materials. [ABSTRACT FROM AUTHOR]

Energetic materials with a graphite-like crystal structure always demonstrate better energy-sensitivity balance than the common ones. However, the knowledge on how to design a graphite-like energetic material is still limited and a rational design procedure for graphite-like energetic materials is much desired. Here, a set of systematic methods for discovering new graphite-like energetic materials is presented. We analyzed the intermolecular self-assembled behavior of graphite-like energetic materials and proposed a combined method of coplanar configuration searching (CCS) and point-chain-plane progressive intermolecular assembly (pcp-PIA) to predict and screen new graphite-like energetic materials. Furthermore, with a self-established high-throughput design system, we rapidly focused on a potential graphite-like energetic molecule (namely, 2-azido-5-nitropyrimidine-4,6-diamine, DANAP) from 426 candidates and finally experimentally verified its graphite-like crystal structure. We believe that the method presented here will have potential applications in guiding the crystal engineering of graphite-like energetic materials, thereby accelerating the discovery of new energetic materials with promising properties. [ABSTRACT FROM AUTHOR]

The crystal structures and stability of energetic compounds are closely related to the energy, safety and reliability of weapons. Searching for new solid forms of an energetic compound has become an integral part of its development. The studied compound, carbonic dihydrazidinium bis[3-(5-nitroimino-1,2,4-triazolate)] (CBNT), is a recently synthesized high energy and low sensitivity energetic ionic salt with promising applications. Herein, we have investigated the crystal structure evolution and searched for new solid forms of CBNT under different conditions via the solvent induction method. The phase composition of all screened samples was analysed by powder or single-crystal X-ray diffraction. Four new solid forms of CBNT·2H2O (1), H2BNT·2DMSO (2), H2BNT·2H2O (3) and [NH2(CH3)2+]2[BNT2−]·2H2O (4) (BNT2− = bis[3-(5-nitroimino-1,2,4-triazolate)2−]) were obtained from water, DMSO, BL/H2O and DMF/H2O, respectively. Their molecular interactions were analysed by theoretical simulations of the Hirshfeld surface and molecular electrostatic potentials. Furthermore, the energetic properties have been verified through EXPLO5. [ABSTRACT FROM AUTHOR]

A new design strategy for zwitterionic energetic materials was developed, and two gem-dinitromethyl functionalized 5-amino-1,3,4-oxadiazolate inner salts were synthesized and characterized. Compared with common energetic salt analogues, both zwitterionic energetic compounds exhibited higher densities, better detonation performances, and comparable mechanical sensitivities. This design strategy may stimulate the development of additional zwitterionic energetic materials. [ABSTRACT FROM AUTHOR]

In the development of advanced high-energy-density materials (HEDMs), the traditional strategy of integrating oxidant and fuel components into an organic molecule makes it very difficult to balance the energy and safety of materials. Herein, we present an intermolecular host–guest inclusion strategy for constructing advanced HEDMs with well-balanced energy and safety. By gradually introducing high-energy oxidants into the supramolecular voids of the deliberately selected energetic host crystal, three host–guest inclusion HEDMs (i.e., HGI-1, HGI-2 and HGI-3) were prepared, which show detonation performances separately comparable to those of three classical HEDMs, namely RDX, HMX and ε-CL-20, but with mechanical sensitivities that are much superior to those of these classical HEDMs. In addition, these self-assembled HEDMs have excellent combustion properties and exhibit great potential as high-energy low signature propellants. This presented host–guest inclusion strategy shows enormous potential for tailoring the energy and sensitivity of energetic materials and will accelerate the development of advanced HEDMs in the future. [ABSTRACT FROM AUTHOR]

New derivatization reactions of 1,1-diamino-2,2-dinitroethylene (FOX-7) are explored, which afford three cyclic triazinane-based energetic compounds 1, 2 and 3 featuring the FOX-7 backbone. Their structures were characterized by X-ray single crystal diffraction analysis. Among them, compound 1 shows a high detonation performance (vD: 8899 m s−1, P: 35.83 GPa) comparable to that of FOX-7. Compound 2 exhibits a good detonation performance (vD: 8332 m s−1, P: 26.47 GPa) and good thermal stability (Td = 188 °C), which is superior to that of most FOX-7-derived energetic compounds. Both of them inherit the low-sensitivity characteristic of FOX-7 because of strong inter- and intra-molecular hydrogen bonds. The presented derivatization reaction has contributed to the ever-expanding chemistry of FOX-7. [ABSTRACT FROM AUTHOR]

Protonated g-C3N4 nanosheets were prepared by refluxing a mixture containing g-C3N4 and 95% H2SO4 at 80 °C for 1 hour. The obtained g-C3N4 nanosheets showed a similar layer structure to that of g-C3N4 and high water adsorption capacities. They also depicted superior conductivities reaching up to 1.44 × 10−2 S cm−1 at 80 °C and 98% RH, with promising features for proton conductivity materials. [ABSTRACT FROM AUTHOR]

A novel fused-ring polynitro compound (5) and a cyclic compound featuring gem-dinitromethylene and nitroso groups (7) were synthesized from 1,1-diamino-2,2-dinitroethylene (FOX-7). Both compounds exhibit high density, decent thermal stability, high detonation performances, and low mechanical sensitivities. This newly developed derivatization strategy enriches the ever-expanding reactive chemistry of FOX-7. [ABSTRACT FROM AUTHOR]

In this work, we prepared and comprehensively characterized four novel iodocuprate-containing ionic liquids, CuILs 1–4. In addition to their interesting molecular structures and physical properties CuILs exhibited capability to efficiently promote hypergolic reactions between boron-containing [EMIM+][H3BCN−] and [MIM]·[BH3] fuels and a highly concentrated H2O2 (95%) oxidizer. The most promising promoter CuIL 3 has the decomposition temperature well above the decomposition temperature of the fuels, was stable in promoter-in-fuel mixtures for weeks and showed ignition delay times down to 14 ms. We believe that further development of our new iodocuprate ionic liquids can lead to promising “green” H2O2-based bipropellant systems for space applications. [ABSTRACT FROM AUTHOR]

A number of energetic ionic liquids (EILs) have been reported as promising hydrazine-replacement fuels for hypergolic rocket propulsion. However, most of these EILs were ignited using corrosive and hazardous concentrated fuming nitric acid. Very significant efforts were recently made to utilize “rocket grade” highly concentrated H2O2 (＞90%) as a “green” alternative to fuming nitric acid and N2O4 oxidizers. Although “rocket grade” H2O2 is more challenging to use and less safe for storage than commercially available H2O2 (70%), the latter is not considered as a viable oxidizer for hypergolic propulsion. In this work, we focused on the development of novel iodine-rich promoters, capable of initiating hypergolic ignition reactions between a typical EIL fuel – 3-ethyl-1-methyl-1H-imidazol-3-ium cyanotrihydroborate – and H2O2. Among the prepared and evaluated promoters, the top performing [FcCH2NEtMe2+]2[B12I122−] compound 5 showed ignition delay times of 45 ms in the reaction of the tested EIL with H2O2 (70%) and 17 ms with H2O2 (95%). We believe that these findings provide a platform for the development and utilization of commercially available H2O2 as a potential “green” oxidizer for rocket propulsion. [ABSTRACT FROM AUTHOR]

A novel derivatization strategy was developed for the exciting reactive chemistry of FOX-7. The as-synthesized FOX-7-derived polynitro compounds exhibited high crystal densities, excellent detonation performances, and good impact and friction sensitivities. This study opens a new path for the ever-expanding chemistry of FOX-7. [ABSTRACT FROM AUTHOR]

Abstract: A novel family of hydrophobic triaminocyclopropenium cation based ionic liquids have been synthesized, and their structures and physicochemical properties characterized by NMR and IR spectroscopy, elemental analysis, differential scanning calorimetry, and hypergolic tests. The experimental results showed that all of these ionic liquids exhibited the expected hypergolic reactivity with the oxidizer white fuming nitric acid. Among them, the hypergolic ionic liquid based on the cyanoimidazolylborohydride anion showed excellent integrated properties, including high decomposition temperature (194 °C), high density (0.95 g cm−3), moderate viscosity (44 MPa s), ultrafast ignition delay time (6 ms), and high specific impulse (301.9 s); this demonstrates its potential as an environmentally friendly alternative to toxic hydrazine derivatives. [ABSTRACT FROM AUTHOR]

Abstract: The experimental detection and synthesis of pentazole (HN5) and its anion (cyclo‐N5−) have been actively pursued for the past hundred years. The synthesis of an aesthetic three‐dimensional metal–pentazolate framework (denoted as MPF‐1) is presented. It consists of sodium ions and cyclo‐N5− anions in which the isolated cyclo‐N5− anions are preternaturally stabilized in this inorganic open framework featuring two types of nanocages (Na20N60 and Na24N60) through strong metal coordination bonds. The compound MPF‐1 is indefinitely stable at room temperature and exhibits high thermal stability relative to the reported cyclo‐N5− salts. This finding offers a new approach to create metal–pentazolate frameworks (MPFs) and enables the future exploration of interesting pentazole chemistry and also related functional materials. [ABSTRACT FROM AUTHOR]

Abstract: The experimental detection and synthesis of pentazole (HN5) and its anion (cyclo‐N5−) have been actively pursued for the past hundred years. The synthesis of an aesthetic three‐dimensional metal–pentazolate framework (denoted as MPF‐1) is presented. It consists of sodium ions and cyclo‐N5− anions in which the isolated cyclo‐N5− anions are preternaturally stabilized in this inorganic open framework featuring two types of nanocages (Na20N60 and Na24N60) through strong metal coordination bonds. The compound MPF‐1 is indefinitely stable at room temperature and exhibits high thermal stability relative to the reported cyclo‐N5− salts. This finding offers a new approach to create metal–pentazolate frameworks (MPFs) and enables the future exploration of interesting pentazole chemistry and also related functional materials. [ABSTRACT FROM AUTHOR]

Two new metal phosphates, namely, Zn(HPO4)(dl-C3H7NO2) (SCU-4) and In(HPO4)(H2PO4)(dl-C3H7NO2) (SCU-12), were prepared in the presence of the amino acid l-alanine. SCU-4 has a ladderlike structure with edge-sharing 4-rings. SCU-12 represents the first example of a three-dimensional metal phosphate templated by an amino acid. It remains stable in boiling water and shows a high proton conductivity at room temperature under 98% relative humidity. [ABSTRACT FROM AUTHOR]

Salinity is amajor abiotic factor affecting plant growth and secondary metabolism. However, no information is available about its effects on Schizonepeta tenuifolia Briq., a traditional Chinese herb. Here, we investigated the changes of plant growth, antioxidant capacity, glandular trichome density, and volatile exudates of S. tenuifolia exposed to salt stress (0, 25, 50, 75, 100 mM NaCl). Results showed that its dry biomass was reduced by salt treatments except 25 mM NaCl. Contents of antioxidants, including phenolics and flavonoids, increased at low (25 mM) or moderate (50 mM) levels, but declined at severe (75 and 100 mM) levels. On leaf surfaces, big peltate and small capitate glandular trichomes (GTs) were found. Salt treatments, especially at moderate and severe concentrations, enhanced the density of total GTs on both leaf sides. The most abundant compound in GT volatile exudates was pulegone. Under salinity, relative contents of this component and other monoterpenes decreased significantly; biosynthesis and accumulation of esters were enhanced, particularly sulfurous acid, 2-ethylhexyl hexyl ester, which became the second major compound as salinity increased. In conclusion, salt stress significantly influenced the growth and secondary metabolism of S. tenuifolia, enabling us to study the changes of its pharmacological activities. [ABSTRACT FROM AUTHOR]

A series of 1,2,4-oxadiazole-derived energetic compounds were successfully synthesized using 1,2,4-oxadiazole-3-chloroxime as a versatile starting material. These energetic compounds were fully characterized by NMR spectroscopy, IR spectroscopy, and elemental analysis. The structures of compounds 5, 6a, 6c, 8 and 8a were determined by single crystal X-ray diffraction. The physicochemical and energetic properties of all the synthesized energetic compounds, including density, thermal stability and energetic performance (e.g., detonation velocities and detonation pressures) were investigated. Among these energetic compounds, hydrazinium salts 6b and 8b and hydroxylammonium salts 6c and 8c exhibit satisfactory calculated detonation performances, which outperform the commonly used high explosive RDX. Potassium salt 5 shows good detonation performance, high density as well as high sensitivity, making it a potential primary explosive. Compound 9 is a potential candidate for melt-cast explosives due to its remarkable liquid range between melting point (Tm = 98 °C) and decomposition temperature (Td = 208 °C). [ABSTRACT FROM AUTHOR]

A series of C–N linked bistetrazolate nitramino compounds, i.e., 1-(2H-tetrazol-5-yl)-5-nitraminotetrazole (2) and its energetic salts (3–8), were successfully prepared from readily available 5-aminotetrazole. All new energetic compounds were fully characterized by IR and NMR spectra and elemental analysis, and six of them (1, 3–7) were further determined by single-crystal X-ray diffraction analysis. The nitrogen contents of these energetic bistetrazolate compounds, ranging from 59.3% (3) to 74.8% (7), are much higher than those of the commonly used high explosives such as RDX (N: 37.8%), HMX (N: 37.8%) and CL-20 (N: 38.3%). And theoretical calculations by using the Gaussian 09 program package demonstrate that compounds 1–8 have high positive heats of formation, of which the heats of formation of ammonium salt 4 (3.60 kJ g−1), aminonitroguanidinium 5 (3.11 kJ g−1) and dihydrazinium salt 7 (3.25 kJ g−1) are approximately eight times higher than those of RDX (0.39 kJ g−1) and HMX (0.39 kJ g−1), and four times higher than that of CL-20 (0.83 kJ g−1). The high nitrogen contents and high heats of formation have endowed these energetic compounds with prominent detonation performance. It is noteworthy that compound 7 exhibits an excellent calculated detonation velocity of 9822 m s−1 superior to that of CL-20 (9730 m s−1), while the impact and friction sensitivities of 7 (IS = 8 J, FS = 192 N) are comparable to those of HMX (IS = 7 J, FS = 112 N). The good detonation properties with moderate sensitivities demonstrate that compound 7 is a promising candidate for application as a high-performance energetic material. [ABSTRACT FROM AUTHOR]

A luminescent heterometallic MOF with an interrupted cap topology was synthesized and characterized. This compound exhibits a strong blue-light emission and shows naked-eye selective detection toward trinitrobenzene (TNB) even in the presence of other nitro explosives. Furthermore, the compound is also capable of selectively sensing nitroaromatic picric acid (PA) based on the fluorescence quenching mechanism. [ABSTRACT FROM AUTHOR]

gem-Dinitromethylated and fluorodinitromethylated 5,5′-dinitro-3,3′-bis-1,2,4-triazole (DNBT) ( 2 and 3) along with seven ionic derivatives 4- 9, were synthesized and characterized by NMR and IR spectroscopies, elemental analysis, single-crystal X-ray diffraction (XRD), and differential scanning calorimetry (DSC). XRD revealed that compounds 2 and 3 crystallized in the monoclinic P21/ n space group and compound 5 crystallized in the monoclinic P21/ c space group. The physicochemical properties of the as-synthesized compounds 2- 9 were investigated and the results indicated that compounds 3, 6, and 7 exhibited a good balance between high energy and low sensitivity, demonstrating their potential as new high-energy-density materials (HEDMs). The proposed synthetic strategy for introducing gem-dinitromethyl and fluorodinitromethyl groups into the DNBT framework to prepare materials with high energy and low sensitivity suitable for HEDMs looks promising. [ABSTRACT FROM AUTHOR]

In this study, a series of high-energy-density materials (1·2H2O–9) based on N-(3-nitro-1-(trinitromethyl)-1,2,4-triazol-5-yl)nitramide were synthesized and structurally characterized using 1H NMR, 13C NMR, IR spectroscopy, elemental analysis, and single-crystal X-ray diffraction. The crystal results demonstrated that potassium 3-nitro-5-(nitroimino)-1-(trinitromethyl)-1,2,4-triazolate hydrate (2·H2O) exhibits an infinite two-dimensional (2D) metal–organic framework (MOF) containing the coordination group NO2 and metal cation K+. Additionally, this 2D MOF exhibited a high oxygen content (46.41%) and a positive oxygen balance (14.77%). Heats of formation and the detonation properties of the newly prepared compounds were calculated using the Gaussian 09 and EXPLO 5 programs, respectively. Energetic evaluation indicated that these compounds demonstrate good detonation performances, all of which outperform traditional primary explosives mercury fulminate, lead azide, 2-diazo-4,6-dinitrophenol, and in some cases, even exceed the performance of high explosive RDX. Therefore, the high detonation parameters of the compounds enable these potential primary explosives to trigger the whole detonation easily. Furthermore, several attractive properties, such as an excellent density (2.00 g cm−3), an impact sensitivity of 2 J, a friction sensitivity of 32 N, and a low amount of toxic detonation products, make 2·H2O an eco-friendly primary explosive. [ABSTRACT FROM AUTHOR]

Two new beryllium phosphite anionic open-frameworks based on Be3P4O12H4 cluster building blocks, formulated as (Him)2·Be3(HPO3)4, were synthesized under solvothermal conditions, where im is imidazole. Interestingly, the use of different alcohols, i.e., isopropanol and n-propanol, as solvents afforded two new anionic open-frameworks with the same chemical composition, but different structures. Compound 1 crystallized in the monoclinic C2/c space group, whereas compound 2 crystallized in the triclinic P1̅ space group. Both compounds displayed intersected channels with 8-, 8-, 8-, and 12-membered windows along different directions. Considering Be3P4O12H4 clusters as four-connected nodes, both compounds showed a pcu topology. Notably, the frameworks of both open-frameworks remained stable after soaking in boiling water for one month. Furthermore, compound 1 exhibited a high proton conductivity of 2.03 × 10−3 S cm−1 at 363 K and 98% relative humidity, indicating its potential as a hydrothermally stable proton-conducting material. [ABSTRACT FROM AUTHOR]

Three anionic open frameworks, formulated as [Him]2Eu2(ox)4(H2O)2 ·2H2O ( 1), [Him]2Tb2(ox)4(H2O)2 ·2H2O ( 2), and [Hmim]2Eu2(ox)4(H2O)2 ·2H2O ( 3; ox = oxalate, im = imidazole, mim = methylimidazole), have been synthesized by a solvent-free method. In these solvent-free processes, in situ encapsulation of imidazolium in the channels of the anionic open frameworks was successfully achieved. These compounds show 1D channels with extensive hydrogen-bonding networks created between the guest molecules and adjacent oxalate oxygen atoms; the imidazolium or methylimidazolium cations are regularly arranged within the channels. Alternating current (AC) impedance measurements revealed that the three compounds display high proton conductivities (>10-3 S cm-1) at 298 K and 98 % relative humidity, with compound 2 showing the highest proton conductivity of 5.0 × 10-3 S cm-1 at 298 K. The high proton conductivities of compounds 1- 3 may be attributed to the extensive hydrogen-bonding networks existing in the open frameworks, which are constructed by water molecules, protonated imidazole or methylimidazole molecules, and adjacent oxalate oxygen atoms. This work provides an efficient synthetic strategy for the construction of high-performance solid proton conductors. [ABSTRACT FROM AUTHOR]

Over the past few decades, toxic and highly volatile hydrazine derivatives have been the main fuel choices for liquid bipropellants, especially in traditional hypergolic rocket engines. The search for new hypergolic fuels as replacements for hydrazine derivatives is of great interest to researchers. In this study, a series of N-alkylimidazole borane compounds has been synthesized and characterized. Interestingly, these compounds display promising applications as potential hypergolic fuels owing to their excellent physiochemical properties including low melting points, high thermal stability, low viscosities, and unique hypergolic reactivity. Compared with popular hypergolic ionic liquids, the cost-effective and scaling-up advantages of these materials highlight their promising potential as high-performance fuels in liquid bipropellant formulations. [ABSTRACT FROM AUTHOR]

A series of three-dimensional fluorescent heterometallic MOFs based on rod- and cluster-like building blocks were readily prepared under solvothermal conditions. Among them, compounds 1–4 were constructed from rod-like building blocks {Cd–O–M}n (M = Na, K, Na–K, and Mg) and BDC2− ligands, featuring right-hand and left-hand channels with a cap topology. The framework charges of 1–4 can be tuned from negative to neutral via a strategy of changing the secondary metal centre (Na+, Na+–K+, K+ and Mg2+). It is worth noting that the rod-like building block of compound 2 contained three types of metal ion centres (Cd2+, Na+ and K+). Different from compounds 1–4, the topology of 5 changed from a cap net to a 610 net in the presence of Ca2+ as a secondary metal centre. Interestingly, the anionic framework of 5 features two types of linear trinuclear clusters as the building blocks, i.e. {Cd2CaO17} and {Cd2CaO16}, which are relatively rare in known heterometallic open frameworks. Moreover, fluorescent compound 5 with a microporous structure displayed sensing properties towards some nitro-containing compounds, suggesting its potential application as a fluorescent sensor for the sensitive detection of explosives. [ABSTRACT FROM AUTHOR]

Bis(4-nitraminofurazanyl-3-azoxy)azofurazan ( 1) and ten of its energetic salts were prepared and fully characterized. Computational analysis based on isochemical shielding surface and trigger bond dissociation enthalpy provide a better understanding of the thermal stabilities for nitramine-furazans. These energetic compounds exhibit good densities, high heats of formation, and excellent detonation velocity and pressure. Some representative compounds, for example, 1 ( vD: 9541 m s−1; P: 40.5 GPa), and 4 ( vD: 9256 m s−1; P: 38.0 GPa) exhibit excellent detonation performances, which are comparable with current high explosives such as RDX ( vD: 8724 m s−1; P: 35.2 GPa) and HMX ( vD: 9059 m s−1; P: 39.2 GPa). [ABSTRACT FROM AUTHOR]

Bis(4-nitraminofurazanyl-3-azoxy)azofurazan ( 1) and ten of its energetic salts were prepared and fully characterized. Computational analysis based on isochemical shielding surface and trigger bond dissociation enthalpy provide a better understanding of the thermal stabilities for nitramine-furazans. These energetic compounds exhibit good densities, high heats of formation, and excellent detonation velocity and pressure. Some representative compounds, for example, 1 ( vD: 9541 m s−1; P: 40.5 GPa), and 4 ( vD: 9256 m s−1; P: 38.0 GPa) exhibit excellent detonation performances, which are comparable with current high explosives such as RDX ( vD: 8724 m s−1; P: 35.2 GPa) and HMX ( vD: 9059 m s−1; P: 39.2 GPa). [ABSTRACT FROM AUTHOR]

Two microporous metal-organic frameworks (MOFs) based on zinc clusters, that is, [Zn3(BDC)2(HBDC)2] ·2DMA ·4CH3OH ·2H2O ( 1; H2BDC = 1,4-dicarboxybenzene, DMA = N, N-dimethylacetamide) and [(CH3)2NH2]2[Zn7(µ4-O)2(NDC)6] ·DMF ·H2O ( 2; H2NDC = 1,4-naphthalenedicarboxylic acid, DMF = N, N-dimethylformamide), were synthesized by a solvothermal method. Both compounds possess three-dimensional porous skeletons with square channels and exhibit interesting blue fluorescence. Compound 1 consists of trinuclear ZnII building units bridged by both BDC2- and HBDC- ligands, which results in the formation of a 2,8-connnected topological net (hex). Compound 2 features another 2,8-connected topological net (bcu) that is constructed by eight-connected Zn7(µ4-O)2 clusters and two-connected NDC2- ligands. The solid-state and solvent-dependent fluorescence of the two MOFs revealed that 1 and 2 showed fluorescence enhancement effects in the presence of acetone and chloroform, respectively, which thereby demonstrates their potential as fluorescent sensors for selective sensing towards acetone and chloroform. [ABSTRACT FROM AUTHOR]

[Objectives] To provide a theoretical basis for the establishment of the best suitable nitrogen application forms and proportion in the cultivation of Isatis indigotica Fort., the effect on the dry matter, apparent quality and photosynthesis of I. indigotica was explored. [ Methods] Field experiment was going to analyze the growth, chlorophyll content and photosynthetie parameters of I indigotica from five different areas by using seven nitrogen treatment with three repeats, which were nitrogen control, N0-3-N,NH+4-N, NH+4-N/NO-3-N = 75/25,NH+4-N/N0-3-N = 50/50, NH+4-N/NO-3-N = 25/75 and CO ( NH2 )2, respectively. [Results] I. indigotica from Shaanxi Shangluo in ammonium nitrate mixed fertilizer( NH+4-N/NO-3-N = 75/25 and NH+4-N/NO-3-N = 50/50) ,grew well; While the group from Gansu Zhangye in the ammonium nitrogen and amide nitrogen processing conditions, underground biomass and total biomass had a larger accumulation. The treatment of amide nitrogen could improve the dry weight of roots of Anhui Bozhou, Gansu Zhangye, Anhui Fuyang and Shanxi Yuncheng. The main root diameter and the number of lateral root in the group of Gansu Zhangye and Shaanxi Shangluo all reached maximum in NH+4-N/NO-3-N = 25/75 and NH+4-N/NO-3-N = 50/50, respectively. Nitrogen treatment could effectively improve the chlorophyll content of I, indigotica, especially the Anhui Fuyang with nitrate nitrogen. Meanwhile, nitrogen treatment was also beneficial to improving its photosynthetie rate, stomatal conductance, transpiration rate and intercellular CO2 concentration, which significantly affected on the I. indigotica from Shaanxi Shangluo. [Conclusions] These results indicated that there are many differences between the response of nitrogen treatment in different areas. Therefore we could improve the yield of the I. indigotica by applying suitable nitrogen forms and proportions according to the different responses to nitrogen forms and proportion in different areas. [ABSTRACT FROM AUTHOR]

Two new open-framework beryllium phosphates, formulated as MV·Be2(HPO4)2(H2PO4)2 (1) and EV·Be2(HPO4)2(H2PO4)2 (2), have been synthesized under solvothermal conditions, where MV = methylviologen and EV = ethylviologen. The two compounds have large 16-membered ring (16 MR) channels with a zeolitic CrB4 topology. They contain in situ generated viologen dications from the alkylation of 4,4′-bipyridine (4,4′-bpy) molecules as the structure-directing agents (SDAs). In comparison, the use of 4,4′-bpy and 2,2′-bpy as the SDAs results in the formation of two different open-framework compounds, (4,4′-H2bpy)2·Be5(HPO4)7 (3) and (2,2′-H2bpy)0.5·Be3(OH)(HPO4)3 (4). Compounds 3 and 4 have different framework structures with 12 MR channels. The presence of large 41084124 cages in the structure of 3 is worth noting. [ABSTRACT FROM AUTHOR]

Four beryllium hydrogen phosphates, Be2(Hea)(PO4)(HPO4) ( 1), Him ·Be3(OH)(HPO4)3 ( 2a), Hpy ·Be3(OH)(HPO4)3 ( 2b), and Hma ·Be1.5(HPO4)2 ·0.5H2O ( 3) in which ea = ethanolamine, im = imidazole, py = pyridine, and ma = methylamine, were synthesized under solvothermal conditions. All compounds have open-framework structures with (3,4)-connected networks. Compound 1 features a neutral inorganic-organic hybrid framework with an interrupted zeolitic GIS topology. The dual role of the amine molecules as charge-balancing agents and coordinating agents to the beryllium atoms is noteworthy. Compounds 2a and 2b are isostructural, and they have an AFI-related framework with elliptical 12-ring channels. Compound 3 has a 3D structure with 4.82 layers pillared by corner-sharing four-ring chains. It represents the first example of an open-framework beryllium hydrogen phosphate with 16-ring channels. [ABSTRACT FROM AUTHOR]

A new family of gem ‐ dinitromethylated and fluorodinitromethylated energetic compounds based on 5,5’ ‐ dinitro ‐ 3,3’ ‐ bis ‐ 1,2,4 ‐ triazole (DNBT) shows high energy density, good thermal stability, and excellent detonation properties. The proposed strategy of introducing gem ‐ dinitromethyl and fluorodinitromethyl groups into DNBT frameworks demonstrates a great promise for developing new ‐ generation high ‐ energy ‐ density materials (HEDMs) with high ‐ performing detonation level and low sensitivity. More information can be found in the Full Paper by Q. Zhang et al. on page 12787. [ABSTRACT FROM AUTHOR]