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International programs have shown that implementing people-and-climate oriented cities goes through two processes in physical contexts: (i) urban regeneration of the existing city, particularly on public services for each urban unit, and (ii) planning of their accessibility. Therefore, there is a strong relationship between the goals of people-and-climate oriented and temporal-and-proximity perspectives. Moreover, the Covid-19 pandemic emergency highlighted the relevance of proximity again Nevertheless, an evaluation of how urban regeneration projects can contribute to achieving sustainability goals in ordinary practice still struggles to consolidate. Consequently, according to both perspectives, this contribution aims to observe and evaluate the effects of local urban regeneration projects on pedestrian mobility. Therefore, it presents a space-time and GIS-based methodology to assess the walkability scenarios in public open spaces. The analysis consists of double temporal analysis: (i) it analyses pedestrian accessibility in a cells grid and through a backtracking algorithm that measures the spatialized isochronous of access time, and (ii) it evaluates accessibility in two temporal moments, ex-ante and expost. The assessment framework proposed is applied to the case study of unit Tintoretto tower in Brescia. Results show how urban design produces different space-time effects on pedestrian accessibility and proximity connection within 15 minutes. [ABSTRACT FROM AUTHOR]

This paper investigates the shape memory capabilities of semicrystalline networks, focusing the attention on poly(ε-caprolactone) (PCL) systems, a class of materials that allows to satisfy important requirements for their applications as biomedical devices, such as the good biocompatibility, the fast recovery of large 'temporary' shape configurations, and the easy tailoring of the transformation temperatures. The materials were prepared with various crosslink densities and crosslinking methodologies; in particular, beside a thermal crosslinking based on reactive methacrylic end groups, a novel type of covalently crosslinked semicrystalline systems was prepared by a sol-gel approach from alkoxysilane-terminated PCL precursors, so as to avoid potentially toxic additives typically used for free-radical thermal curing. The materials were subjected to biological tests, to study their ability in sustaining cell adhesion and proliferation, and to thermal characterizations, to evaluate the possibility to tailor their melting and crystallization temperatures. The one-way shape memory (i.e., the possibility to set the material in a given configuration and to recover its pristine shape) and the two-way shape memory response (i.e., the triggered change between two distinguished shapes on the application of an on-off stimulus) were studied by applying optimized thermo-mechanical cyclic histories. The ability to fix the applied shape and to recover the original one on the application of heating (i.e., the one-way effect) was evaluated on tensile bars; further, to investigate a potential application as self-expandable stents, isothermal shape memory experiments were carried out also on tubular specimens, previously folded in a temporary compact configuration. The two-way response was studied through the application of a constant load and of a heating/cooling cycle from above melting to below the crystallization temperature, leading to a reversible elongation/contraction effect, involving maximum strain changes up to about 80%, whose extent may be controlled through the crosslink density. [ABSTRACT FROM AUTHOR]

The design, prototyping and validation of an innovative test bench for the characterization and the hysteresis measurement of flexion sensors are presented in this paper. The device, especially designed to test sensors employed in the biomedical field, can be effectively used to characterize also sensors intended for other applications, such as wearable devices. Flexion sensors are widely adopted in devices for biomedical purposes and in this context are commonly used in two main ways: to measure movements (i) with fixed radius of curvature and (ii) with variable radius of curvature. The test bench has been conceived and designed with reference to both of these needs of use. The technological choices have been oriented towards simplicity of manufacture and assembly, configuration flexibility and low cost of realization. For this purpose, 3D printing technology was chosen for most of the structural components of the device. To verify the test bench performances, a test campaign was carried out on five commercial bending sensors. To characterize each sensor, the acquired measurements were analysed by assessing repeatability and linearity of the sensors and hysteresis of the system sensor/test bench. A statistical analysis was performed to study the positioning repeatability and the hysteresis of the device. The results demonstrate good repeatability and low hysteresis. [ABSTRACT FROM AUTHOR]

How can urban policies and planning approaches help in achieving a safer mobility and carbon reduction in the transport sector? The attention of planners and policy makers towards the promotion of sustainability and reduction of environmental impacts has grown in recent years. This paper investigates the role that Urban Planning plays in the long term towards a safer and climate friendlier mobility, highlighting the need for integrated approaches gathering spatial planning and mobility management. After a review of several urban policies and planning strategies, initiatives, and approaches, mainly based on the urban scale, the paper presents an urban regeneration case study leading to an increase of pedestrian accessibility at the neighborhood level. This can be seen as a support tool to foster sustainable, safe, and climate friendly mobility in cities. The results of the performed analysis show a dependency of accessibility from two different factors: the distribution of services and the capillarity of the soft mobility network, which can contribute to creating a more walkable space. [ABSTRACT FROM AUTHOR]