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The Salina Cruz and Puerto Ángel beach areas in the Gulf of Tehuantepec, Mexican Pacific coast represent an important economic sector of the region. In this study, the mineralogy and geochemistry of bulk sediments, and geochronology of 400 detrital zircons recovered from the beach sediments were analysed to investigate their origin. The sediments are abundant in quartz, feldspar, ilmenite, cordierite, aragonite and anorthite. The chemical index of weathering revealed a moderate to intense weathering in the source area. The chondrite normalized REE patterns of bulk sediments are similar to the found in the Upper Continental Crust, suggesting the derivation of sediments from felsic igneous rocks. The REE patterns of zircons and the trace elemental ratios reveal a continental crust origin. Zircon U–Pb ages in the Salina Cruz beach were represented by Proterozoic (~545.1–1314.1 Ma; n = 170) and Cenozoic (~0.01–66 Ma; n = 20). The Puerto Ángel beach was abundant in Proterozoic zircon grains (~600.9–1171.4 Ma; n = 109) and followed by Mesozoic grains (~73.78–246.9 Ma; n = 40). The comparison of zircon U–Pb ages of this study with probable source rocks reveals that the Oaxaquia Terrane and Chiapas Massif Complex were the major contributors of Proterozoic zircons to the coastal areas. Similarly, the results indicate that the Cenozoic zircons were contributed by the Chiapas Massif Complex, coastal batholith and Cuicateco Terrane. The Mesozoic zircons are very few, derived from the nearby Xolapa Complex and the Chuacús Terrane. [ABSTRACT FROM AUTHOR]

Key message: Thchit42 constitutive expression for fungal resistance showed synchronisation with leaf augmentation and transcriptome analysis revealed the Longifolia and Zinc finger RICESLEEPER gene is responsible for plant growth and development. Pelargonium graveolens essential oil possesses significant attributes, known for perfumery and aromatherapy. However, optimal yield and propagation are predominantly hindered by biotic stress. All biotechnological approaches have yet to prove effective in addressing fungal resistance. The current study developed transgenic geranium bridging molecular mechanism of fungal resistance and plant growth by introducing cassette 35S::Thchit42. Furthermore, 120 independently putative transformed explants were regenerated on kanamycin fortified medium. Primarily transgenic lines were demonstrated peak pathogenicity and antifungal activity against formidable Colletotrichum gloeosporioides and Fusarium oxysporum. Additionally, phenotypic analysis revealed ~ 2fold increase in leaf size and ~ 2.1fold enhanced oil content. To elucidate the molecular mechanisms for genotypic cause, de novo transcriptional profiles were analyzed to indicate that the auxin-regulated longifolia gene is accountable for augmentation in leaf size, and zinc finger (ZF) RICESLEEPER attributes growth upregulation. Collectively, data provides valuable insights into unravelling the mechanism of Thchit42-mediated crosstalk between morphological and chemical alteration in transgenic plants. This knowledge might create novel opportunities to cultivate fungal-resistant geranium throughout all seasons to fulfil demand. [ABSTRACT FROM AUTHOR]

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We studied the microtextures of quartz grains recovered from the Salina Cruz and Puerto Angel beaches in the Oaxaca State, Mexican Pacific coast. Quartz grains in both beaches are angular to sub-rounded in shape, revealed short and long transport with heterogeneous source. The mechanical features like conchoidal fractures, parallel striations/ridges, percussion marks, shock-melted grains, and meandering ridges were abundant, which indicates high energy in the beach environment. Rare microtexture slickenside surface suggested shear zones adjacent to fault. We identified microtextures of chemical origin such as silica globules, solution pits, and crystal overgrowth that indicated the diagenetic environment in a silica-saturated zone. The elongated depression, adhering particles, and medium relief revealed high influence of mechanical/chemical origin. [ABSTRACT FROM AUTHOR]

Palaeo‐Mesoarchean Banded Iron formations (BIFs) of central Bundelkhand greenstone belts occur from Babina (in the west) to Mahoba (in the east) via Mauranipur along with the E–W trending of the Bundelkhand Tectonic Zone (BTZ). In the present study, we report petrological, geochemical, and mineralogical data of BIFs from the Babina, Mauranipur, and Mahoba greenstone belts of central Bundelkhand Greenstone Complex to address their source characteristics and deposition environment. The lithological association of BIFs in the Babina and Mauranipur greenstone belts consists of pillowed basic–ultrabasic volcanics and metasediments, whereas in the Mahoba greenstone belt, BIFs and quartzite occur within basic volcanics. These lithological associations collectively suggest that the entire succession was deposited in a marine environment. Based on geological setting, they are classified as Algoma‐type. The main mineral assemblages of the Babina and Mauranipur BIFs are composed of magnetite, quartz, ±garnet, hornblende, chlorite, and apatite, whereas the Mahoba BIFs along with magnetite and quartz, poised of two distinct mineral assemblages; the first one is Opx–Cpx–Grt and the other one is Grt–Hbl. The preliminary P–T study of these BIFs implies that they had gone through amphibolite‐ to granulite‐facies metamorphism. The geochemical characteristics show that BIFs from the Babina and Mauranipur greenstone belts are dominated by higher quartz and magnetite (total content = 90.63–99.95 wt.%), whereas the Mahoba greenstone belt is characterized by lesser quartz and magnetite components (total content = 86.68–94.58 wt.%). The PAAS (Post Archean Average of Australian Sediments)‐normalized REE patterns display significant positive Eu anomaly (Eu/Eu* up to 2.50) with well‐represented negative Ce anomalies (Ce/Ce* = 0.27–1.20). The REE and trace element ratios of BIFs from the Babina and Mauranipur greenstone belts suggest that they were formed by high‐T hydrothermal fluid activity without or very less continental input. Moreover, the Mahoba greenstone belt BIFs are formed by low‐T hydrothermal fluid activity with substantial continental input. Their chemical variation suggests the shallowing of the proto‐basin from the Babina in the west to Mahoba in the east. Tectonic discrimination plots imply the BIFs of the Babina, Mauranipur, and Mahoba greenstone belts of the central Bundelkhand Greenstone Complex are formed in a back‐arc tectonic setting. [ABSTRACT FROM AUTHOR]

Based on scanning electron microscopy (SEM) images, we studied the microtextures of quartz grains recovered from the Boca del Cielo and Chocohuital beach sediments in the Chiapas state, Mexico. Microtextures of mechanical, chemical, and mechanical/chemical origins were identified. Quartz grains in both beaches were sub-angular to sub-rounded in shape, indicating high energy, short transport, and nearby source. The microtextures of mechanical origin like percussion marks, conchoidal fractures, and V-shaped marks were abundant in the Chocohuital beach, which revealed high energy subaqueous beach environment. Large-scale conchoidal fractures are characteristic of crystalline rocks, and abrasion features are due to energetic grain-to-grain collision during eolian transport. However, quartz grains in the Boca del Cielo beach were dominated with microtextures of chemical origin such as adhered particles, solution pits, and crystal overgrowth, and are abundant with trapped diatoms, which indicated the diagenetic processes in a silica saturated environment. Two diatoms Navicula incertata and Cyclotella bodanica of 15-μm size are identified in Boca del Cielo quartz grains. [ABSTRACT FROM AUTHOR]

The Compostela area is located in the western Trans‐Mexican Volcanic Belt, which consists of volcanic rocks that produced during the Pliocene to Recent volcanism. In this paper, we present petrography, whole‐rock major‐ and trace‐element concentrations, Ar–Ar ages, and Sr–Nd isotopic data of volcanic rocks from the Compostela area in the south of the city of Tepic, Nayarit, Mexico. These volcanic rocks are of intermediate composition and belong to the transitional series: basaltic trachyandesites [52.72–53.94 wt% SiO2; 0.69–2.53 wt% MgO] and subalkaline series: low‐Si [55.11–60.94 wt% SiO2; 0.79–2.74 wt% MgO] and high‐Si [61.60–62.71 wt% SiO2; 0.36–0.80 wt% MgO] andesites. The 40Ar/39Ar dating of two basaltic trachyandesites yields plateau ages of 1.05 ± 0.15 Ma and 1.07 ± 0.17 Ma and the andesites yielded a plateau age of 2.42 ± 0.36 Ma. These results indicate that the studied rocks were formed during the Pleistocene in two discrete episodes. The basaltic trachyandesites show enriched light rare earth elements patterns relative to high rare earth elements [(La/Yb)N = 5.81–8.07] with negligible Eu anomalies. The andesites display enriched large‐ion lithophile elements (Ba, K) with anomalies of Nb (Th/Ce) and Ti in the three groups identified in the subalkaline series. The basaltic trachyandesites appear in a tight cluster of initial 87Sr/86Sr ratios (0.703519–0.703882) as compared to the basaltic andesite 87Sr/86Sr (0.704073) and positive ɛNd(t) values of +5.6 to +3.4, respectively, indicating that the basaltic trachyandesites were derived from intermediate magmas from a shallow mantle source. Geochemical modelling reveals that both basaltic trachyandesite and andesite rocks were derived by a process of crystal fractionation accompanied by assimilation of crustal rocks at the lower or middle level. Geochemical ratios and multidimensional discrimination diagrams, combined with the cross‐section of the subduction zone indicates that basaltic trachyandesites were generated from a rift and/or Ocean Island Basalt‐type source, whereas andesites were generated from a slab‐derived source in a subduction environment. [ABSTRACT FROM AUTHOR]

The Mesa Virgen Calerilla (MVC) is located in the state of Zacatecas, Mexico. The most intense volcanism, which occurred during the Eocene, formed extensive ignimbrite deposits exposed in some parts as lava spills of rhyolitic (felsic) composition. This felsic volcanism may represent much of the MVC. This study describes whole‐rock geochemistry and mineralogy data from felsic volcanic rocks in the MVC to address their petrogenesis and tectonic setting. The MVC covers a compositional spectrum ranging from trachyte, dacite, to high‐silica rhyolite. The petrography and mineral assemblages indicate that the felsic rocks are composed of K‐feldspar (sanidine), quartz, plagioclase, and biotite. The felsic volcanic rocks have a composition of 64.08–78.17 wt% (SiO2)adj, 0.14–0.69 wt% (TiO2)adj, and 0.11–0.62 wt% (MgO)adj with 12–54 Mg number [Mg# = 100 × (Mg2+/[Mg2+ + Fe2+])]. These felsic volcanic rocks showed enrichment in light rare earth elements (LREE; [La/Sm]N = 3.80–7.19), and are depleted in heavy rare earth elements [HREE; (Tb/Yb)N ratios 0.35–1.84], along with negative Ba, Nb, Sr, P, Eu, and Ti anomalies. The geochemical characteristics and petrogenetic modelling indicate that felsic volcanic rocks are derived from partial melting process of an upper‐middle continental crust. The tectono‐magmatic model and multidimensional tectonic discrimination diagram indicate that an extensional‐related setting prevails for the MVC. [ABSTRACT FROM AUTHOR]

The Goochland Terrane is an enigmatic crustal block in the Appalachian Piedmont Province of central Virginia, USA. Sparse exposures of terminal Mesoproterozoic and late Neoproterozoic igneous rocks in the central Goochland Terrane offer the opportunity to investigate both the continental affinity of the terrane during the Proterozoic Eon and the timing and mechanisms of crustal growth. We apply multiple geochemical tools to these rocks: tectonic discrimination using whole-rock major and trace element abundances; whole-rock Sm-Nd isotopes; O, U-Pb, and Lu-Hf isotope analyses of spots in zircon; and measurement of O isotopes in multi-grain quartz separates. Eruption of the Sabot Amphibolite protolith is difficult to date, but we tentatively assign an age of 552 ± 11 Ma. Goochland Terrane continental crust first separated from the mantle prior to ca. 1050–1010 Ma intrusion of the Montpelier Anorthosite and the State Farm Gneiss protolith. The granitic magma that became the State Farm Gneiss protolith could have been derived entirely from partial melting of this initial Goochland Terrane crust. In contrast, the magmas that became the Montpelier Anorthosite, Neoproterozoic granitoid, and the Sabot Amphibolite were mixtures of mantle melt and preexisting Goochland Terrane crust. This production of juvenile continental crust occurred during continental extension and, eventually, rifting. The timing and compositions of terminal Mesoproterozoic magmatism in the Goochland Terrane closely match those in the nearby Blue Ridge Province. Although the compositions of the Neoproterozoic magmas in the two regions are similar, intrusion and possibly eruption occurred about 10 M.y. later in the Goochland Terrane. [ABSTRACT FROM AUTHOR]

Gneiss–migmatitic rocks and granites between the Cubatão and Itariri shear zones characterize the Mongaguá Complex-Coastal Terrane. Three major units are defined: (1) the Itariri Suite (IS) composed of monzogranites, granodiorites, tonalites, and locally gneiss–migmatitic rocks; (2) the Areado pluton composed of monzogranite and locally tonalite; and (3) the Ribeirão do Óleo Pluton mainly composed of monzogranites, which is the subject of this article. Combined field observations, petrography, Sr–Nd–Hf isotopes, U–Pb zircon data, and preliminary geochemical studies are presented for the Ribeirão do Óleo Pluton (ROP), intrusive in granite-gneisses of the IS. It is a plutonic association of weakly peraluminous, medium-to-high-K biotite monzogranites that surround microgranular intermediate enclaves, which are products of magma mingling. Different from the most examples of magma mingling described in the literature, the ROP mingling did not result from the intrusion of hot mafic magma into colder host felsic magma. Conversely, the emplacement of the monzogranite started most likely during the medium-to-final stage of crystallization of the quartz microdiorite. A detailed study of LA-ICP-MS U–Pb zircon ages, including zircon morphology and internal structure, was useful to determine more precisely the emplacement sequence and the relation between the units of the ROP. Intermediate and acid facies have Paleoproterozoic and Neoproterozoic inheritances, moreover a mixture of xenocrysts, antecrysts, and autocrysts, indicative of a complex evolution of the ROP. Several magma crystallization pulses are recorded at 655–624 Ma, 627–601 Ma, and 613–586 Ma. The negative εHf(t) ranging from − 17.26 to − 12.51 in monzogranites, εNd(t) values of − 10.66 to − 7.83 at t = 600 Ma in both facies, 87Sr/86Sr of ca. 0.708 for the monzogranite and 0.706 for the quartz microdiorite indicate a strong crustal contribution in the genesis of intermediate and acid magmas of this pluton. [ABSTRACT FROM AUTHOR]

We applied both the ordinary linear regression (OLR) and the new uncertainty weighted linear regression (UWLR) models for the calibration and comparison of a XRF machine through 59 geochemical reference materials (GRMs) and a procedure blank sample. The mean concentration and uncertainty data for the GRMs used for the calibrations (Supplementary Materials) (available here) filewere achieved from an up-to-date compilation of chemical data and their processing from well-known discordancy and significance tests. The drift-corrected XRF intensity and its uncertainty were determined from mostly duplicate pressed powder pellets. The comparison of the OLR (linear correlation coefficient r∼0.9523–0.9964 and 0.9771–0.9999, respectively, for before and after matrix correction) and UWLR models (r∼0.9772–0.9976 and 0.9970–0.9999, respectively) clearly showed that the latter with generally higher values of r is preferable for routine calibrations of analytical procedures. Both calibrations were successfully applied to rock matrices, and the results were generally consistent with those obtained in other laboratories although the UWLR model showed mostly narrower confidence limits of the mean (slope and intercept) or lower uncertainties than the OLR. Similar sensitivity (∼2.69–46.17 kc·s−1·%−1 for the OLR and ∼2.78–59.69 kc·s−1·%−1 for the UWLR) also indicated that the UWLR could advantageously replace the OLR model. Another novel aspect is that the total uncertainty can be reported for individual chemical data. If the analytical instruments were routinely calibrated from the UWLR model, this action would make the science of geochemistry more quantitative than at present. [ABSTRACT FROM AUTHOR]

With respect to the adverse effects of chemical fertilizers on the environment and their higher cost, an alternative method of improving soil fertility has been tested. Application of vermicompost (VC) (produced from de-oiled waste) along with efficient bioinoculants (nitrogen fixer: Bacillus sp., JN700924; phosphate solubilizer: Bacillus megaterium, ATCC 14581; plant growth promoter: Pseudomonas monteilii, HQ 995498; arbuscular mycorrhizal fungus (AMF): Glomus intraradices) in different combinations were evaluated on Ocimum basilicum. VC along with bioinoculants-treated plots showed a significant improvement in biomass (15.1-56%), essential oil content (26.7-48.2%), and essential oil yield (44.7-108.4%) over control. The major constituent of essential oil (i.e., methyl chavicol) was significantly improved in T3 (VC + Bacillus sp.), T5 (VC + P. monteilii), and T6 (VC + G. intraradices) treated plants as compared to control (T1). Significant improvement in microbial counts, percent root colonization of AMF, and alkaline phosphatase activity were recorded; maximum in bioinoculants along with VC-treated plots. Improvement in soil organic carbon (4.2-51.16%), NH4+-N (27.0-55.3%), NO3--N (−8 to 60.33%], available P (15.2-43.5%), and available K (0.4-20.8%) were found in VC along with bioinoculants-treated plots. The diethylene triamine pentaacetic acid extractable Fe (109-154 mg kg−1 soil) was more influenced by VC along with bioinoculants than other micronutrients (Cu, Mn, and Zn). The results suggest that an integrated use of VC with bioinoculants improves soil health and essential oil yield of O. basilicum. [ABSTRACT FROM AUTHOR]

Multidimensional discrimination diagrams (2006–2011) for basic and ultrabasic igneous rocks were applied to Precambrian rock suites from the Amazonian and São Francisco cratons, and the Tocantins Province, Brazil, to infer their possible tectonic settings. The chosen study cases in the Amazonian craton include the ca. 3.0 Ga metabasalts of the Identidade greenstone belt, 1.87–1.80 Ga Parauapebas anorogenic basalt-rhyolite dikes, 1.86–1.82 Ga Rio Branco anorogenic gabbro-basalt association, ca. 1.76–1.74 Ga Aripuanã and Teles Pires intracratonic basalt-felsic volcanic associations, and 1.76–1.74 Ga Jamari and 1.60–1.53 Ga Serra da Providência arc-related gabbroic rocks. In the São Francisco craton, we selected 1.48 Ga arc-related amphibolites of the Rio Capim greenstone belt, continental mafic dikes of Uauá (2.6 Ga), Curaçá and Chapada Diamantina (1.5 Ga), and Espinhaço (ca. 1.0 Ga). In the Tocantins Province, ca. 3.0 Ga komatiites associated with oceanic basalts of the Crixás and Guarinos greenstone belts were studied. The application of the diagrams generally provided consistent results with the authors’ proposed tectonic settings based on field relationships and geochemical data. The exceptions are some within-plate (continental) mafic dikes and basalts for which our diagrams do not work well. For comparison, we also used two ternary and two bivariate traditional discrimination diagrams for the data from the Amazonian craton, whose results were poorer than the newer multidimensional diagrams. [ABSTRACT FROM AUTHOR]

Fifty-five new multi-dimensional diagrams, mostly based on log-ratio transformations, were used to decipher tectonic settings for 17 cases of Precambrian belts in Canada, the USA, Poland, Finland, Jordan, Democratic Republic of Congo and Zambia, China, and India. The results of different sets of diagrams for basic-ultrabasic, intermediate, and acid magmas were generally internally consistent. Possible reasons for some inconsistencies may be related to the use of a sample group of mixed ages because of their uncertainties, extreme element mobility caused by metamorphism especially of high-grade type, analytical data quality, different petrogenetic processes for basic to acid magmas such as mantleversuscrustal origin, and some deficiencies that still exist in the multi-dimensional diagrams. To partly overcome the last problem, one new multi-dimensional diagram is proposed and used to discriminate mid-ocean ridge and oceanic plateau settings. [ABSTRACT FROM AUTHOR]

Andrographis paniculata Nees is an annual erect herb with wide medicinal and pharmacological applications due to the presence of andrographolide and other active chemical constituents. The large-scale cultivation of the kalmegh is not in practice. The aim of this study was to establish sustainable production systems of A. paniculata cv CIM-Megha with the application of different bioinoculants and chemical fertilisers. A. paniculata herb and andrographolide yield in the dried leaves was found to be highest (218% and 61.3%, respectively) in treatment T3 (NPK+Bacillus sp.) compared with T1 (control). The soil organic carbon, soil microbial respiration, soil enzymes activity and available nutrients improved significantly with combined application of bioinoculants and chemical fertilisers. [ABSTRACT FROM AUTHOR]

Although for ultrabasic and basic magmas a plethora of tectonomagmatic diagrams have been used, with the exception of one bivariate diagram for refined tectonic setting of orogenic andesites, none is available for highly abundant intermediate magma. We present 3 sets of discrimination diagrams obtained from the correct statistical methodology of loge-ratio transformation and linear discriminant analysis. All major element loge-ratio variables in 3664 samples, only immobile major and trace element loge-ratio variables in 1858 samples, and immobile trace element loge-ratio variables in 1512 samples were used. These diagrams with probability-based tectonic field boundaries and high success rates (about 69%-96%, 63%-100%, and 64%-100%, respectively, for diagrams based on all major elements, immobile major and trace elements, and immobile trace elements) were first tested for fresh and highly altered rocks. The expected tectonic setting was indicated from our diagrams. The probability-based decisions and total percent probability estimates can fully replace the actual plotting of samples in the diagrams. The probability calculations were then used for tectonic discrimination of 7 case studies of Archean to Proterozoic rocks. An island arc setting was indicated for the Wawa greenstone belt (Canada), implying the existence of plate tectonic processes during the Late Archean, for western Tasmania (Australia) during the Cambrian, and for Chichijima Island (Bonin Islands, Japan) during the Eocene. Similarly, an arc setting (indecisive island or continental type) was obtained for south-central Sweden during the Paleoproterozoic and for Adola (southern Ethiopia) during the Neoproterozoic. A within-plate setting was inferred for the Neoproterozoic Malani igneous complex, Rajasthan, India. A collision setting was indicated for the Alps (France-Italy-Switzerland) during the Late Carboniferous. Modeling of likely as well as extreme processes indicates that these diagrams are robust against postemplacement compositional changes caused by analytical errors, element mobility, Fe-oxidation, alteration, and petrogenetic processes. [ABSTRACT FROM AUTHOR]

The article talks about geochemistry as an aiding tool to understand tectonic setting of igneous rocks associations, but continental mafic dykes and flood basalts are targets that even geochemical discrimination diagrams fail to correctly classify. It talks of this paradox explained through crustal contamination, degree of mantle melting and mantle source characteristics. It also makes a mention of plotting geochemical data for key continental mafic dyke swarms in multi-dimensional diagrams.