1. Recovery of no-carrier-added 41Ca, 44Ti, and 26Al from high-energy proton-irradiated vanadium targets.
- Author
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Wilson, Jennifer M., Mihalcea, Ionut, Veicht, Mario, Cvjetinović, Đorđe, and Schumann, Dorothea
- Subjects
COSMOGENIC nuclides ,NUCLEAR astrophysics ,ION exchange chromatography ,NUCLEAR research ,RADIOISOTOPES ,VANADIUM - Abstract
Many useful and needed radionuclides for medicinal, astrophysical, and environmental research are produced naturally in inefficient quantities or not-at-all. In the method described here, rare cosmogenic isotopes were produced via spallation reactions in metallic vanadium and separated without adding any carriers. In the SINQ facility at the Paul Scherrer Institut, the vanadium targets were irradiated for two years with high-energy protons (≤590 MeV). After a cooling period of eight years, only relatively long-lived radionuclides such as
32 Si,44 Ti,41 Ca, and26 Al remain present. After target dissolution,32 Si was first separated for a prospective half-life redetermination. The remaining32 Si-free solution was used for extracting44 Ti,41 Ca, and26 Al, three key isotopes which are scientifically interesting for nuclear astrophysics research as well as medical applications. Each separation scheme employed ion-exchange and extraction chromatography; developed and optimized using inactive model solutions analyzed with Inductively Coupled Plasma–Optical Emission Spectrometry (ICP–OES). The irradiated samples were tracked with γ-ray spectroscopy for γ-ray emitting impurities. As a result, radiochemically pure sample solutions of44 Ti,41 Ca, and26 Al were obtained as "ready for use" in different application fields. [ABSTRACT FROM AUTHOR]- Published
- 2023
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