1. A universal cooperative assembly-oriented strategy for VS4 nanorod decoration on carbon nanostructures with enhanced magnesium storage properties.
- Author
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Man, Yuehua, Li, An, Tang, Haowei, Sun, Jianlu, Fei, Yating, Du, Yichen, and Zhou, Xiaosi
- Abstract
VS
4 has a unique layered atomic chain structure and has the potential to become a high-performance cathode material of magnesium-ion batteries with a high capacity and long cycle life. However, low conductivity and sluggish Mg2+ diffusivity during cycling limit its practical application in large-scale energy storage. Herein, a cooperative assembly-directed strategy is adopted to synthesize VS4 nanorods grown in situ on carbon nanotubes (CNTs/VS4 ). VS4 nanorods are tightly anchored to CNTs through V–O–C interface covalent bonds, and CNTs can enhance the electronic conductivity of the nanocomposite. In addition, the ion insertion reaction using Mg2+ and MgCl+ as carriers reduces the polar barrier for divalent Mg2+ ion transport. This rationally designed architecture promotes ion diffusion and electron transfer, thus facilitating reaction kinetics. The cooperative assembly-oriented strategy can endow CNTs/VS4 with excellent magnesium storage properties, including a high reversible capacity of 223.2 mAh g−1 at a current density of 50 mA g−1 , a remarkable discharge capacity of 91.8 mAh g−1 even at 2,000 mA g−1 , and an impressive capacity retention of 85.2% after 1,000 cycles at 500 mA g−1 . Moreover, this strategy can serve as a general synthetic method for the complexation of VS4 with other carbon nanostructures. [ABSTRACT FROM AUTHOR]- Published
- 2024
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