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Facing the challenge of the degradation of global water quality, it is urgent to realize the Sustainable Development Goal 6.3.2 (SDG 6.3.2), which focuses on improving global water quality. Currently, remote sensing technology is widely used for water quality monitoring. Existing water quality-monitoring studies have been conducted based on quantitative water quality inversion. It requires a high degree of the synchronization of the time and location of the collection of station monitoring data and remote sensing data (air–ground spatiotemporal synchronization), which can be resource intensive and time consuming. However, policymakers and the public are more interested in the quality of water (good or poor) than in the specific values of the water quality parameters, as evidenced by the emergence of SDG 6.3.2. In this study, we change the traditional idea of quantitative water quality research, focus on water quality qualitative research combined with the characteristics of water pollution, propose a remote sensing water quality sample enhancement method under the condition of "air–ground spatiotemporal asynchrony", and construct a remote sensing water quality sample library. On the basis of this sample library, a random forest water quality classification model was constructed to classify water quality qualitatively. We obtained the distribution of good water bodies in Deqing County, China, for example, from 2013 to 2022. The results show that the model has high accuracy (Kappa = 0.6004, OA = 0.8387), and we found that the water quality in Deqing County improved in the order of "major rivers, lakes, and tributaries" during the period from 2013 to 2015. This also verifies the feasibility of using this sample enhancement method to conduct qualitative research on water quality. Based on this water quality classification model, a set of spatial-type evaluation processes of SDG 6.3.2 based on image elements was designed. The evaluation results show that the water quality situation in Deqing County can be divided into two stages: there is a trend of substantial improvement from 2013 (evaluated value of SDG 6.3.2 = 63.25) to 2015 (evaluated value of SDG 6.3.2 = 83.16); and it has remained stable and fluctuating after reaching the good environmental water quality since 2015. This study proposes a simple method for rapidly evaluating SDG 6.3.2 via utilizing easily accessible Landsat 8 and water quality-monitoring data to classify water quality. The method can directly obtain water quality category information without the need for additional sampling, thus saving costs. It is a very simple process that is easy to implement, while also providing a high level of accuracy. This significantly reduces the barriers to evaluating SDG 6.3.2, supports the realization of the sustainable management of water resources globally, and is highly generalizable. [ABSTRACT FROM AUTHOR]