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1. “Gating” the Pores of a Metal Oxide Based Capsule: After Initial Cation Uptake Subsequent Cations Are Found Hydrated and Supramolecularly Fixed above the PoresWe thank Prof. D. Rehder (Hamburg) for useful discussions regarding the NMR spectra and Dr. L. Zhang (Bielefeld) for metal analyses. Financial support from the Deutsche Forschungsgemeinschaft, the Fonds der Chemischen Industrie, the Volkswagenstiftung, the European Union, and the German–Israeli Foundation for Scientific Research & Development (GIF) is gratefully acknowledged.

2. “Gating” the Pores of a Metal Oxide Based Capsule: After Initial Cation Uptake Subsequent Cations Are Found Hydrated and Supramolecularly Fixed above the PoresWe thank Prof. D. Rehder (Hamburg) for useful discussions regarding the NMR spectra and Dr. L. Zhang (Bielefeld) for metal analyses. Financial support from the Deutsche Forschungsgemeinschaft, the Fonds der Chemischen Industrie, the Volkswagenstiftung, the European Union, and the German–Israeli Foundation for Scientific Research & Development (GIF) is gratefully acknowledged.

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