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Introduction: TiO anatase nanoplates and hollow microspheres were fabricated by a solvothermal-hydrothermal method using titanium isopropoxide as a titanium precursor and hydrofluoric acid as a capping agent in order to enhance the formation of the {001} crystal facets of the anatase nanocrystals. Methods: These different morphological structures of TiO anatase can be achieved by only changing the solvent, keeping the amount of the precursor and of the capping agent identical during the solvothermal-hydrothermal process. Results and discussion: After calcination of the samples, the adsorbed fluoride atoms on the {001} crystal facets of the TiO anatase nanocrystals were completely removed from their surface according to XPS analysis. The calcined TiO anatase structures were higher crystallized and the specific surface area of the catalysts increased, enhancing their photocatalytic activity in comparison to the non-calcined TiO anatase structures. All TiO anatase samples with adsorbed as well as non-adsorbed fluoride atoms on their {001} crystal facets, exhibited a higher photonic efficiency than Degussa P25, which was used as a reference. Conclusion: The fluoride free TiO anatase nanoplates exhibited the best photocatalytic activity in oxidizing the NO gas to NO and NO. [ABSTRACT FROM AUTHOR]