1. Optimizing the gasification performance of biomass chemical looping gasification: enhancing syngas quality and tar reduction through red mud oxygen carrier.
- Author
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Wang, Zhonghui, Han, Long, Shen, Zewei, Ma, Kaili, Wu, Yuelun, Zhang, Jianhao, and Mao, Shengxiao
- Abstract
Biomass chemical looping gasification (BCLG) is a promising technology for producing high-quality syngas. In this study, the BCLG of corn cob using inexpensive industrial waste red mud (RM) as an oxygen carrier was carried out in a fixed bed reactor, focusing on enhancing syngas quality and tar reduction. The gasification performance of BCLG was investigated under different conditions, including O/C ratio, steam flow rate, and reaction temperature. RM improved gas yield and quality with a maximum H
2 /CO ratio of 2.39 while reducing tar yield by 38.75%. High temperature led to the polymerization of polyaromatic hydrocarbons (PAHs) in tar, but steam effectively reduced PAHs by 33.25% via the tar homogeneous conversion. The degree of tar cracking and conversion to gases in the presence of steam was more than the thermal decomposition in the pure N2 atmosphere. Additionally, metal oxides within RM participated in reactions with steam. The limitation of intensive reduction of RM through iron-steam reactions enhanced H2 yield and prevented RM sintering. XRD analyses revealed the evolution of iron compounds in RM during BCLG: Fe2 O3 —Fe3 O4 —FeO/Fe—Fe3 O4 . Under the optimal conditions of BCLG, the carbon conversion efficiency, gasification efficiency, and gas yield reached 70.74%, 92.95%, and 1.24 m3 /kg, respectively. Meanwhile, the H2 /CO ratio reached 1.82 while the tar yield was reduced to 0.196 g/gfuel . This study highlighted the potential of using RM as an effective oxygen carrier in the BCLG, which would contribute to the advancement of sustainable biomass gasification. [ABSTRACT FROM AUTHOR]- Published
- 2024
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