1. Fabrication of sol-gel derived homogeneously doped Er3+/Yb3+:SiO2 microspheres using laser melting.
- Author
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Chen, Jie, Ma, Jianxing, Black, Charles M., Shao, Yuchen, Lei, Jincheng, Xiao, Hai, and Peng, Fei
- Abstract
Silica microspheres have been demonstrated as the optical micro-cavity for laser generation based on whispering-gallery modes (WGM). They can achieve a high-quality factor (Q) within a tiny volume. Traditionally, complex processes are needed to process a coating containing photoluminescent elements, with enough thickness and uniformity, for laser generation. We developed a novel sol-gel fabrication method of Er
3+ /Yb3+ doped silica microspheres with a homogeneous doping concentration over the entire microsphere volume. The sol-gel precursors were doped with 1–2 mol% Er3+ and/or Yb3+ . The viscosity of the precursor was controlled at around 4000 cP, and gel fibers can be conveniently drawn from the precursor. After firing at 1000 °C for 1 h, transparent fibers with diameters of 40–180 µm were obtained. The fiber tips were quickly melted into microspheres using a CO2 laser. The diameters of microspheres were determined by the fiber diameter and laser parameters, such as laser power and irradiation time duration. Typically, the microspheres had diameters between 90 to 160 µm. The emission spectrum under 357 nm and 527 nm excitation showed characteristic Er3+ emission peaks, that match the literature well. The UV-VIS spectra confirm the photoluminescence results and showed both Er3+ and Yb3+ characteristic absorptions. The optical behaviors of the microspheres indicate that the Er3+ and Yb3+ were well dispersed in the silica matrix and the microspheres had typical optical activities of Er3+ /Yb3+ glasses. Highlights: Silica microspheres, fabricated using laser melting, with homogeneously doped Er3+ /Yb3+ . No need for multiple layers of Er3+ /Yb3+ sol-gel coatings. Microspheres demonstrated strong optical activities with Er3+ /Yb3+ doping. [ABSTRACT FROM AUTHOR]- Published
- 2024
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