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Electrochemical energy storage has utility in wide range of systems, therefore scientific community and energy stakeholders have been significantly focusing especially on it. By utilizing the novel BaS3:La2S3:Ho2S3 semiconductor, an alkaline earth-lanthanide composite chalcogenide (AE-LCC), which is developed by chelating with the diethyldithiocarbamate ligand, the current work, for the first time, seeks to enhance the performance of charge retaining devices in addition to electro-catalysis. This photo-active material exhibits exceptional optical properties with a band gap of 3.95 eV and heterogeneous crystallographic modes with a median crystallite size of 17.78 nm, due to its sustainable manufacturing process. Furthermore, infrared spectroscopy was used to identify metallic sulfide connections, which vary between 545 and 887 cm−1. Differently shaped particles that fused into a rod-like structure showed a higher volume-surface area ratio at multiple locations. The electrochemical performance of the BaS3:La2S3:Ho2S3 AE-LCC was assessed using a conventional three-electrode configuration with an initial electrolyte of 1 M KOH. BaS3:La2S3:Ho2S3 AE-LCC exhibits excellent specific capacitance of as high as 779 F g−1 and a power density of 10,145.28 W kg−1, making it an excellent electrode material for power storage applications. This remarkable electrochemical performance was further substantiated by comparable series resistance (Rs) = 1.25 Ω. The electrode generated an OER overpotential and a matching Tafel slope of 417 mV and 113 mV/dec by electro-catalysis. Conversely, the Tafel slope of HER activity was 310 mV/dec, and its overpotential was 233 mV. Highlights: Novel BaS3:La2S3:Ho2S3 semiconducting chalcogenide. Qualities with potential applications in the energy industry. Sustainable electrode adorned with BaS3:La2S3:Ho2S3. 10,145.28 W kg−1 of specific power density. Excellent energy storage with a specific capacitance of 779 F g−1. Commendably lower OER and HER overpotential and Tafel slopes. [ABSTRACT FROM AUTHOR]

Soil contamination with toxic heavy metals [such as aluminum (Al)] is becoming a serious global problem due to the rapid development of the social economy. Although plant growth-promoting rhizo-bacteria (PGPR) are the major protectants to alleviate metal toxicity, the study of these bacteria to ameliorate the toxic effects of Al is limited. Therefore, the present study was conducted to investigate the combined effects of different levels of Acinetobacter calcoaceticus (5 ppm and 10 ppm) of accession number of MT123456 on plant growth and biomass, photosynthetic pigments, gas exchange attributes, oxidative stress and response of antioxidant compounds (enzymatic and nonenzymatic), and their specific gene expression, sugars, nutritional status of the plant, organic acid exudation pattern and Al accumulation from the different parts of the plants, which was spiked with different levels of Al [0 µM (i.e., no Al), 50 µM, and 100 µM] using aluminum sulfate [Al2(SO4)3] in wheat (Triticum aestivum L.). Results from the present study revealed that the Al toxicity induced a substantial decreased in shoot length, root length, number of leaves, leaf area, shoot fresh weight, root fresh weight, shoot dry weight, root dry weight, chlorophyll-a, chlorophyll-b, total chlorophyll, carotenoid content, net photosynthesis, stomatal conductance, transpiration rate, soluble sugar, reducing sugar, non-reducing sugar contents, calcium (Ca2+), magnesium (Mg2+), iron (Fe2+), and phosphorus (P) contents in the roots and shoots of the plants. In contrast, increasing levels of Al in the soil signifcantly (P < 0.05) increased Al concentration in the roots and shoots of the plants, phenolic content, malondialdehyde (MDA), hydrogen peroxide (H2O2), electrolyte leakage (EL), fumaric acid, acetic acid, citric acid, formic acid, malic acid, oxalic acid contents in the roots of the plants. Although, the activities of enzymatic antioxidants such as superoxidase dismutase, peroxidase, catalase, ascorbate peroxidase and their specific gene expression in the roots and shoots of the plants and non-enzymatic such as phenolic, favonoid, ascorbic acid, and anthocyanin contents were initially increased with the exposure of 50 µM Al, but decreased by the increasing the Al concentration 100 µM in the soil. Addition of A. calcoaceticus into the soil signifcantly alleviated Al toxicity effects on T. aestivum by improving photosynthetic capacity and ultimately plant growth. Increased activities of antioxidant enzymes in A. calcoaceticus-treated plants seem to play a role in capturing stress-induced reactive oxygen species as was evident from lower levels of MDA, H2O2, MDA, and EL in A. calcoaceticus-treated plants. Research findings, therefore, suggested that A. calcoaceticus application can ameliorate Al toxicity in T. aestivum seedlings and resulted in improved plant growth and composition under metal stress as depicted by balanced exudation of organic acids. [ABSTRACT FROM AUTHOR]

Introduction: Heat stress caused by global warming adversely affects wheat yield through declining most nutritional quality attributes in grains, excluding grain protein content. Methods: This research investigated the biochemical, physiological, and antioxidant responses of wheat plants under heat stress, focusing on the role of plant growth-promoting bacteria (Micromonospora sp.). Two wheat genotypes were studied: one heat-sensitive and one heat-tolerant, examining their responses to heat stress with and without bacterial inoculation. Results: Under heat stress, the sensitive cultivar experienced significant reductions in photosynthesis rate, chlorophyll content, and RuBisCO activity (57-61%), while the tolerant cultivar had milder reductions (24-28%). Micromonospora sp. treatment notably improved these parameters in the sensitive cultivar (+48-78%), resulting in a substantial increase in biomass production (+43-53%), which was not seen in the tolerant cultivar. Additionally, oxidative stress markers (H2O2 and MDA) were elevated more in the sensitive cultivar (82% and 90% higher) compared to the tolerant one. Micromonospora sp. treatment effectively reduced these markers in the sensitive cultivar (-28% and -27%). Enhanced activity of antioxidant enzymes and ASC-GSH pathway enzymes was particularly evident in Micromonospora sp.-treated sensitive plants. Carbohydrate metabolism shifted, with increased soluble sugars and significant rises in sucrose content in Micromonospora sp.-treated plants under stress. Discussion: The higher soluble sugar levels facilitated amino acid synthesis, contributing to biosynthesis of secondary metabolites, including flavonoids, polyphenols, and anthocyanins. This was reflected in increased activity of phenylalanine ammonia-lyase, cinnamate (CA) 4-hydroxylase, and chalcone synthase enzymes, indicating the activation of phenylpropanoid pathways. Overall, the findings suggest that Micromonospora sp. can mitigate heat stress effects by enhancing photosynthetic efficiency, antioxidant defense, and metabolic adaptations in heat-sensitive wheat cultivars. [ABSTRACT FROM AUTHOR]

A new hybrid metal oxide (MnO/ZrO2) has been synthesized by an environmentally benign material from the Olea ferruginea royle (OFR)plant leaf extract as a green precursor. The hybrid material has improved oxygen evolution reaction (OER) electrochemical performance. The existence of [OFR-MnO/ZrO2] particles is confirmed by spectroscopic techniques, X-ray photoelectron spectroscopy (XPS), and elemental diffraction spectroscopic (EDS) investigations, emphasizing the role of organic species (N, O and C) during synthesis. To assess the electrode's electrochemical performance, linear sweep voltametric and impedance measurements were performed. The electrode showed a lower linear sweep measurement of 382 mV and a Tafel value of 79 mV dec−1, suggesting MnO/ZrO2 as an efficient electrocatalytic material. These results demonstrate the potential of MnO/ZrO2 as an excellent, long-term and economical solution for a variety of applications, particularly in the area of water splitting research. [ABSTRACT FROM AUTHOR]

The approaches of nanoparticles (NPs) usage have been successfully applied to increase the growth and biological activity of aromatic and medicinal plants. In this context, we studied the effects of zinc–aluminum layered double hydroxide (Zn–Al LDH) and magnesium–Al LDH (Mg–Al LDH) NPs on geranium plants. Both LDH NPs were synthesized using the co-precipitation technique and characterized with SEM, FTIR, XRD, and Zeta potential. Using the spray method, Zn–Al LDH and Mg–Al LDH NPs (10 ppm) were used in a factorial experiment with a fully randomized design. Applying LDH NPs increased Mg and Zn content, which boosted plant growth, photosynthetic pigments, and soluble sugar levels. The administration of both LDH NPs results in a constant increase in secondary metabolites such as essential oils (EOs). Monoterpenes such as geraniol (32.7%) and β-citronellol (29.18%) were found to be the main components of the EO. Geranium plants treated with Mg–Al LDH NPs exhibited the highest levels of polyphenols (44.5%), flavonoids (33.5%), and total antioxidant capacity (31.7%). Additionally, LDH NPs had a favorable effect on antioxidant enzyme activity including catalase and peroxidase activities. Overall, Zn–Al LDH and Mg–Al LDH NPs foliar application acted as an elicitor to enhance growth and bioactive metabolite accumulation in geranium plants. Despite these promising results, several challenges remain for the broader application of LDH NPs in agriculture. [ABSTRACT FROM AUTHOR]

This study presents a comprehensive investigation into the evolutionary trajectories of Rhipicephalus ticks (Ixodidae) through the interpretation of molecular phylogenetics, elucidating their chromatographic spectrum. The use of advanced chromatographic tools in this study explored the dynamics chemical profiling, providing valuable insights into the evolutionary history and ecological adaptations. Prevalence of Rhipicephalus ticks was 4.5% in sheep and 3.9% in goats. The ITS2 sequence of the Rhipicephalus sanguineus (OK642408) and Rhipicephalus microplus (OK642409) form a distinct clade with sequences from other countries. The 16S rRNA sequences of R. sanguineus (OK560870) clustered with sequences form three lineages, tropical, temperate, and south‐eastern. The Cox I gene‐identified Rhipicephalus turanicus (OK623472) and R. microplus (OK623463) form separate clades with sequences. The HPLC chromatogram of tick samples reveals a diverse array of identified hydrocarbons, explained the complex chemical composition of their exoskeletons. This analytical approach provides valuable insights into the specific hydrocarbon profiles, allowing for potential applications in species differentiation, ecological studies, and a deeper understanding of the functional roles played by hydrocarbon compounds in tick physiology. The findings revealed the potential of applying molecular phylogenetics tools with chromatography not only to enhance our understanding of tick evolution but also to inform strategies for disease control and management in regions where Rhipicephalus ticks (Ixodidae) are endemic. Research Highlights: Chemical mapping utilizing advanced chromatographic techniques.Scanning microscopic insights high‐resolution scanning tool to observe structural and morphological features of ticks at a molecular level.Molecular phylogeny data elucidate the evolutionary relationships among tick species. [ABSTRACT FROM AUTHOR]

Conservation management and sustainable use of Moringa peregrina are needed to overcome overexploitation coupled with potential environmental changes. This study demonstrates the energy dynamics of M. peregrina, how stored energy influences species persistence amidst environmental challenges, and the importance of energy reserves in the resilience of the species population. Field, greenhouse, and lab experiments were conducted at the levels of population cohorts, plant organs, seeds, and seedlings to demonstrate the relationship between energy content and the persistence of the species. Seedlings and juveniles stored around 12,000 joule/g in roots, while uncoppiced adults stored about 9,000 joule/g in stems, and coppiced adults stored 1,800-4,000 joule/g in lignotubers. In adult trees, the number of sprouting stems is correlated with the energy content in lignotubers. Over the ten years of seed storage, a rapid rate of energy depletion was observed, ranging from 16,821 to 5,059 joule/g, which is associated with decreased germination and viability. The energy content in two-month-old seedlings varied from 240 to 800 joule/seedlings under 200 and 800 mm rainfall, respectively. The unstable population structure could be ascribed to the depletion of stored energy in lignotubers following uncontrolled coppicing and the rapid depletion of seed energy, which hinders the population resilience. [ABSTRACT FROM AUTHOR]

This study investigates the mechanical, thermal, and morphological properties of abaca-polyester composites made using lignin from fluorescent perianths of jack fruit. The primary scope of this research is to study the viability of producing lignin from waste jack fruit fluorescent perianths and how it influence the mechanical, wear, creep and flammability properties of abaca-polyester composite. The lignin biopolymer was extracted via thermo-chemical method and composites were prepared using hand layup method. The produced composites were evaluated based on American society of testing and materials (ASTM) standards and the results revealed significant improvements in tensile and flexural strength. The addition of abaca fiber and 3.0 vol% of lignin in PA2 composite shows the highest tensile strength, while the PA3 at 5.0 vol% of lignin shows slight shortfall due to clustering of particle. However the PA3 outperform in impact strength, hardness, and wear resistance. The Flammability test reveals effective self-extinguishing properties for PA3 exhibiting superior performance due to lignin's char-forming capabilities. Moreover, creep and TGA analysis demonstrated that the incorporation of abaca fiber and lignin of 5 vol% contributed to reduced creep strain and mass loss at initial, middle and final stages. SEM analysis confirms the effective interaction of lignin particle with resin matrix and ensured effective toughening. The study concludes the optimization potential of abaca-polyester composites, with 3.0% lignin identified as an optimal concentration for balanced improvements across various properties, providing valuable insights for composite material design and applications. [ABSTRACT FROM AUTHOR]

Panicum maximum is planted extensively in tropical and subtropical areas, due to its high-quality forage and high biomass yield. This study aims to assess the varied metabolic dynamics of P. maximum subject to different pollution-related wastewater levels, thus providing information for sustainable agriculture and soil restoration. We analyzed the primary and secondary metabolites in P. maximum subject to two different types of polluted wastewater (WW), compared to a control group. The alterations observed in the metabolite profiles were affected by several factors, including nutrient imbalances and oxidative stress induced by heavy metal accumulation. Initially, the increased nutrient availability stemming from wastewater treatment promoted plant growth; however, this positive effect was later diminished by the adverse impacts of heavy metals, which generated oxidative stress, resulting in metabolic disturbances and a decrease in the plant biomass. Importantly, the substantial increase in antioxidant enzymes, related to primary (e.g., sugars) and secondary metabolites (e.g., phenolics and flavonoids), underscores plants' adaptive strategies to cope with stress. The increased biosynthesis of flavonoids and phenolic compounds is a protective mechanism against oxidative stress, which also improves the antimicrobial activity, following the activation of key biosynthetic pathways involved in their synthesis. These complex interactions among diverse metabolites suggest that plants exposed to polluted wastewater use various biochemical strategies to increase both their survival and defenses against pathogens. Collectively, these findings emphasize the significance of understanding how wastewater management practices can affect plant health, metabolic responses, and the broader implications for food safety and ecosystem stability. [ABSTRACT FROM AUTHOR]

Sprouts are well known for having a remarkable nutritional profile. Enhancing plant chemical composition and quality of sprouts is essential since these metabolites offer numerous health advantages. To this end, this study aimed to investigate the effects of priming with multiwalled carbon nanotubes (MWCNTs) on the growth and nitrogen (N) metabolism of four horticultural plants, namely, Trigonella foenum-graecum, Linium grandiflorum, Lepidium sativum, and Anethum gravelones. The properties of our synthesized MWCNTs included three characteristic peaks 3434, 1539, and 1068 cm−1 attributable to the stretching vibration of O–H, bending vibration, and C − O, respectively. MWCNT priming increased the sprouting process by inducing biomass and protein accumulation. MWCNT priming improved N metabolism, including amino acid and polyamine metabolism. At the amino acid level, there was an increase in amino acid levels (e.g., glycine, lysine, asparagine, and glutamic acid) as well as their metabolic enzyme activities, including glutamine synthetase (GS), threonine synthetase (TS), and glutamate synthetase (GOGAT). Increased polyamine levels like spermine, putrescine, and spermidine were also associated with boosting their related biosynthetic enzyme activities, i.e., arginine decarboxylase (ADC), ornithine decarboxylase (ODC), spermidine synthase, and spermine synthase (SpmS). This improvement of nitrogen metabolic pathways highlights the potential of MWCNT to boost the chemical composition of horticultural plants. [ABSTRACT FROM AUTHOR]

The Pteridaceae family, known for its taxonomic complexity, presents challenges in identification due to high variability among its species. This study investigates the spore morphology employing both SEM and LM techniques in 10 Pteridaceae taxa phytogeographicaly Sino‐Himalayan, Malesian, and European elements in Pakistan. The taxa include Adiantum capillus‐veneris, A. incisum, A. venustum, Aleuritopteris bicolor, Oeosporangium nitidulum, O. pteridioides, Onychium cryptogrammoides, O. vermae, Pteris cretica, and P. vittata. The objective is to assess their taxonomic relevance and develop a spore‐based taxonomic key. Findings indicate differences in spore shape, sizes, exospore thickness, and in surface ornamentation highlighting the potential for taxonomic differentiation. Spores are trilete, and notable differences are observed in the dimension of spores in both distal and proximal sides. Equatorial dimensions vary between 35 and 50 μm, while the polar diameter ranges from 29 to 50 μm. SEM revealed different spore ornamentation types that show several useful characteristics establishing valuable taxonomic variations. The studied Adiantum taxa feature a perispore with tubercules and a micro‐granulose surface. The spores of examined Oeosporangium and Aleuritopteris taxa shows cristate sculptures with variable ornamentations. Both species of Onychium have tuberculate‐pleated tubercles with sinuous folds on both distal and proximal sides. The surface ornamentation among examined Pteris taxa show variability. PCA analysis indicated that spore quantitative data identified distinct groups, underscoring taxonomic significance. Nevertheless, there was variation observed in surface ornamentation and spore shape, indicating the potential for discrimination among taxa. Research Highlights: Spore morphology of 10 Pteridaceae taxa has been investigated through LM and SEM.Investigated species shows differences in spore shape, sizes, exospore thickness, and in surface ornamentation.Ornamentation on the perispore provides several valuable characteristics, establishing useful taxonomic distinctions.Spore morphological analysis is effective at the generic level, with minor distinctions discernible at the species level. [ABSTRACT FROM AUTHOR]

Plants are subjected to various biotic and abiotic stresses that significantly impact their growth and productivity. To achieve balanced crop growth and yield, including for leafy vegetables, the continuous application of micronutrient is crucial. This study investigates the effects of different concentrations of copper sulphate (0, 75, 125, and 175 ppm) on the morphological and biochemical features of Spinacia oleracea and Avena sativa. Morphological parameters such as plant height, leaf area, root length, and fresh and dry weights were optimized at a concentration of 75 ppm copper sulfate. At this concentration, chlorophyll a & b levels increased significantly in Spinacia oleracea (462.9 and 249.8 휇푔/푔), and Avena sativa (404.7 and 437.63휇푔/푔). However, carotenoid content and sugar levels in Spinacia oleracea were negatively affected, while sugar content in Avena sativa increased at 125 ppm (941.6 µg/ml). Protein content increased in Spinacia oleracea (75 ppm, 180.3 µg/ml) but decreased in Avena sativa. Phenol content peaked in both plants at 75 ppm (362.2 and 244.5 µg/ml). Higher concentrations (175 ppm) of copper sulfate reduced plant productivity and health. Plants exposed to control and optimal concentrations (75 and 125 ppm) of copper sulpate exhibited the best health and growth compared to those subjected to higher concentrations. Maximum plant height, leaf area, root length, fresh and dry weights were observed at lower concentrations (75 and 125 ppm) of copper sulfate, while higher concentrations caused toxicity. Optimal copper sulfate levels enhanced chlorophyll a, chlorophyll b, total chlorophyll, protein, and phenol contents but inhibited sugar and carotenoid contents in both Spinacia oleracea and Avena sativa. Overall, increased copper sulfate treatment adversely affected the growth parameters and biochemical profiles of these plants. [ABSTRACT FROM AUTHOR]

We present a new selective Metamaterial Perfect Absorber (MPA) consisting of zinc oxide embedded silver (Ag@ZnO), designed for applications in infrared stealth technology. The numerical simulation included a wide frequency range from 1 to 1000 THz and shows that the design MPA structure presented two absorption peaks at the desired wavelengths of 1.7 µm and 6.5 µm. The absorptivity of both peaks reached approximately 93.1% and 93.5%. The first peak at 1.7 µm decreases the scattering of IR laser beams from the surface of the MPA structure and also lowers the infrared tracks that could direct laser-guided devices to its specific target. On the other hand, the second peak reduces the surface heat wave. The suggested MPA (Ag@ZnO) structure is activated by a plane wave using a full wave vector and a broad frequency domain solution. In the framework of computer simulation technology (CST) Microwave Studio, uses both Finite-Difference-Time-Domain (FDTD) and Finite-Element-Method (FEM) techniques to predict the optical behavior of the proposed MPA structure. Both peaks achieved a high value of absorptivity due to the simultaneous excitation of the electric and magnetic dipole at resonance wavelength. [ABSTRACT FROM AUTHOR]

Wheat (Triticum aestivum L.) is a staple food crop that plays a crucial role in global food security. A suitable planting pattern and optimum nitrogen (N) split management are efficient practices for improving wheat production. Therefore, an experiment was performed to explore the effect of N split management and sowing patterns on wheat at the Agronomy Research Farm, The University of Agriculture Peshawar, during rabi season 2020-21 and 2021-22. The treatments consisted of different nitrogen rates of 0, 80, 120, and 160 kg ha− 1 and planting patterns of W, M, broadcast and line sowing. The pooled analysis of both cropping seasons showed that application of 120 kg N ha− 1 increased spikelets spike− 1, grains spike− 1, 1000 grains weight, grain yield, grain N content, evapotranspiration and water use efficiency by 21.9, 16.7, 21.8, 70, 13, 19.9 and 40% as compared to control, respectively. In addition, W and M were observed the best management practices among all planting patterns. The M planting pattern enhanced chlorophyll a, b, carotenoids and evapotranspiration while W plating pattern improved yield components and yield of wheat as compared to broadcast planting patterns. The principal component analysis biplot showed a close association of M and W planting patterns with 120 kg N ha− 1 in most of the studied traits. Hence, it is concluded that split application of 120 kg N ha− 1 in W and M sowing patterns enhanced growth, biochemical traits and water use efficiency, reducing N fertilization from 160 to 120 kg ha− 1 while increasing grain yield of wheat. Hence, it is recommended that application of 120 kg N ha⁻¹ in combination with W and M planting patterns offer a sustainable approach to enhancing wheat production in the alkaline soil conditions of the Peshawar valley. [ABSTRACT FROM AUTHOR]

Introduction: Salinity negatively affects maize productivity. However, calcium lignosulfonate (CLS) could improve soil properties and maize productivity. Methods: In this study, we evaluated the effects of CLS application on soil chemical properties, plant physiology and grain quality of maize under salinity stress. Thus, this experiment was conducted using three CLS application rates, CLS0, CLS5, and CLS10, corresponding to 0%, 5%, and 10% of soil mass, for three irrigation water salinity (WS) levels WS0.5, WS2.5, and WS5.5 corresponding to 0.5 and 2.5 and 5.5 dS/m, respectively. Results and discussion: Results show that the WS0.5 × CLS10 combination increased potassium (K 0.167 g/kg), and calcium (Ca, 0.39 g/kg) values while reducing the sodium (Na, 0.23 g/kg) content in soil. However, the treatment WS5.5 × CLS0 decreased K (0.120 g/kg), and Ca (0.15 g/kg) values while increasing Na (0.75 g/kg) content in soil. The root activity was larger in WS0.5 × CLS10 than in WS5.5 × CLS0, as the former combination enlarged K and Ca contents in the root while the latter decreased their values. The leaf glutamine synthetase (953.9 µmol/(g.h)) and nitrate reductase (40.39 µg/(g.h)) were higher in WS0.5 × CLS10 than in WS5.5 × CLS0 at 573.4 µmol/(g.h) and 20.76 µg/(g.h), leading to the improvement in cell progression cycle, as revealed by lower malonaldehyde level (6.57 µmol/g). The K and Ca contents in the leaf (881, 278 mg/plant), stem (1314, 731 mg/plant), and grains (1330, 1117 mg/plant) were greater in WS0.5 × CLS10 than in WS5.5 × CLS0 at (146, 21 mg/plant), (201, 159 mg/plant) and (206, 157 mg/plant), respectively. Therefore, the maize was more resistance to salt stress under the CLS10 level, as a 7.34% decline in yield was noticed when salinity surpassed the threshold value (5.96 dS/m). The protein (13.6 %) and starch (89.2 %) contents were greater in WS0.5 × CLS10 than in WS5.5 × CLS0 (6.1 %) and (67.0 %), respectively. This study reveals that CLS addition can alleviate the adverse impacts of salinity on soil quality and maize productivity. Thus, CLS application could be used as an effective soil amendment when irrigating with saline water for sustainable maize production. [ABSTRACT FROM AUTHOR]

This study investigates the differential responses of two maize genotypes, SC180 and SC168, to salt stress, aiming to elucidate the mechanisms underlying salinity tolerance and identify traits associated with improved stress resilience. Salinity stress, imposed by 150 mM NaCl, adversely affected various growth parameters in both genotypes. SC180 exhibited a more pronounced reduction in shoot length (13.6%) and root length (13.6%) compared to SC168, which showed minimal reductions (3.0% and 2.3%, respectively). Additionally, dry weight losses in SC180's leaves, stems, and roots were significantly greater than those in SC168. Under salinity stress, both genotypes accumulated Na+ in all organs, with SC168 showing higher Na + concentrations. However, K+ levels decreased more significantly in SC180's leaves than in SC168's. The study also assessed physiological responses, noting that SC180 experienced a substantial reduction in relative water content (RWC) in leaves (22.7%), while SC168's RWC remained relatively stable (5.15%). Proline accumulation, a marker for osmotic adjustment, increased 2.3-fold in SC168 compared onefold in SC180. Oxidative stress indicators, such as electrolyte leakage and hydrogen peroxide levels, were elevated in both genotypes under salt stress, with SC180 showing higher increases (48.5% and 48.7%, respectively) than SC168 (35.25% and 22.0%). Moreover, antioxidant enzymes (APX, CAT, POD, SOD, GR) activities were significantly enhanced in SC168 under salinity stress, whereas SC180 showed no significant changes in these activities. Stress indices, used to quantify and compare salinity tolerance, consistently ranked SC168 as more tolerant (average rank = 1.08) compared to SC180 (average rank = 1.92). Correlation analyses further confirmed that SC168's superior tolerance was associated with better Na + regulation, maintenance of K+ levels, and a robust antioxidant defense system. In conclusion, SC168 demonstrated greater resilience to salinity stress, attributed to its efficient ion regulation, stable water status, enhanced osmotic adjustment, and strong antioxidant response. These findings provide valuable insights for breeding and developing salinity-tolerant maize varieties. [ABSTRACT FROM AUTHOR]

In present years, the use of zinc oxide nanoparticles (ZnO‐NPs) has received great attention due to increase in the nutrient accumulation by plants for improving the capability of agronomic Zn biofortification. Although, the emergence of polyvinyl chloride (PVC) microplastics (MPs) as pollutants in agricultural soils is increasingly alarming, presenting significant toxic threats to soil ecosystems. The present work studied the impact of different levels of PVC‐MPs, namely 0 (no PVC‐MPs), 2, and 4 mg L−1, along with mercury (Hg) levels of 0 (no Hg), 10, and 25 mg kg−1 in the soil, while concurrently applying with ZnO‐NPs at 0 (no ZnO‐NPs), 50, and 100 μg mL−1 to rye (Secale cereale L.) plants. This study aimed to examine plant growth and biomass, photosynthetic pigments and gas exchange characteristics, oxidative stress indicators, and the response of various antioxidants (enzymatic and non‐enzymatic) and their specific gene expression, proline metabolism, the ascorbic acid–dehydroascorbic acid (AsA–GSH) cycle, and cellular fractionation in the plants. The research outcomes indicated that elevated levels of PVC‐MPs and Hg stress in the soil notably reduced plant growth and biomass, photosynthetic pigments, and gas exchange attributes. However, PVC‐MPs and Hg stress also induced oxidative stress in the roots and shoots of the plants by increasing malondialdehyde (MDA), hydrogen peroxide (H2O2), and electrolyte leakage (EL) which also induced increased compounds of various enzymatic and non‐enzymatic antioxidants, and also the gene expression and sugar content. Furthermore, a significant increase in proline metabolism, the AsA–GSH cycle, and the pigmentation of cellular components was observed. Although, the application of ZnO‐NPs showed a significant increase in plant growth and biomass, gas exchange characteristics, enzymatic and non‐enzymatic compounds, and their gene expression and also decreased oxidative stress. In addition, the application of ZnO‐NPs enhanced cellular fractionation and decreased the proline metabolism and AsA–GSH cycle in S. cereale plants. These results open new insights for sustainable agriculture practices and hold immense promise in addressing the pressing challenges of heavy metal contamination in agricultural soils. [ABSTRACT FROM AUTHOR]

BACKGROUND: Coffee farming constitutes a substantial economic resource, representing a source of income for several countries due to the high consumption of coffee worldwide. Precise management of coffee crops involves collecting crop attributes (characteristics of the soil and the plant), mapping, and applying inputs according to the plants' needs. This differentiated management is precision coffee growing and it stands out for its increased yield and sustainability. RESULTS: This research aimed to predict yield in coffee plantations by applying machine learning methodologies to soil and plant attributes. The data were obtained in a field of 54.6 ha during two consecutive seasons, applying varied fertilization rates in accordance with the recommendations of soil attribute maps. Leaf analysis maps also were monitored with the aim of establishing a correlation between input parameters and yield prediction. The machine‐learning models obtained from these data predicted coffee yield efficiently. The best model demonstrated predictive fit results with a Pearson correlation of 0.86. Soil chemical attributes did not interfere with the prediction models, indicating that this analysis can be dispensed with when applying these models. CONCLUSION: These findings have important implications for optimizing coffee management and cultivation, providing valuable insights for producers and researchers interested in maximizing yield using precision agriculture. © 2024 Society of Chemical Industry. [ABSTRACT FROM AUTHOR]

Developing special textiles (for patients in hospitals for example) properties, special antimicrobial and anticancer, was the main objective of the current work. The developed textiles were produced after dyeing by the novel formula of natural (non-environmental toxic) pigments (melanin amended by microbial-AgNPs). Streptomyces torulosus isolate OSh10 with accession number KX753680.1 was selected as a superior producer for brown natural pigment. By optimization processes, some different pigment colors were observed after growing the tested strain on the 3 media. Dextrose and malt extract enhanced the bacteria to produce a reddish-black color. However, glycerol as the main carbon source and NaNO3 and asparagine as a nitrogen source were noted as the best for the production of brown pigment. In another case, starch as a polysaccharide was the best carbon for the production of deep green pigment. Peptone and NaNO3 are the best nitrogen sources for the production of deep green pigment. Microbial-AgNPs were produced by Fusarium oxysporum with a size of 7–21 nm, and the shape was spherical. These nanoparticles were used to produce pigments-nanocomposite to improve their promising properties. The antimicrobial of nanoparticles and textiles dyeing by nanocomposites was recorded against multidrug-resistant pathogens. The new nanocomposite improved pigments' dyeing action and textile properties. The produced textiles had anticancer activity against skin cancer cells with non-cytotoxicity detectable action against normal skin cells. The obtained results indicate to application of these textiles in hospital patients' clothes. [ABSTRACT FROM AUTHOR]

Secondary metabolites produced by Bacillus species from marine sources encompass a variety of compounds such as lipopeptides, isocoumarins, polyketides, macrolactones, polypeptides and fatty acids. These bioactive substances exhibit various biological activities, including antibiotic, antifungal, antiviral, and antitumor properties. This study aimed to isolate and identify a particular species of Bacillus from marine water and organisms that can produce bioactive secondary metabolites. Among the 73 Bacillus isolates collected, only 5 exhibited antagonistic activity against various viral and bacterial pathogens. The active isolates were subjected to 16S rRNA sequencing to determine their taxonomical affiliation. Among them, Bacillus tequilensis CCASU-2024-66 strain no. 42, with the accession number ON 054302 in GenBank, exhibited the highest inhibitory potential. It displayed an inhibition zone of 21 mm against Bacillus cereus while showing a minimum zone of inhibition of 9 mm against Escherichia coli and gave different inhibition against pathogenic fungi, the highest inhibition zone 15 mm against Candida albicans but the lowest inhibition zone 10 mm was against Botrytis cinerea, Fusarium oxysporum. Furthermore, it demonstrated the highest percentage of virucidal effect against the Newcastle virus and influenza virus, with rates of 98.6% and 98.1%, respectively. Furthermore, GC-MS analysis was employed to examine the bioactive substance components, specifically focusing on volatile and polysaccharide compounds. Based on these results, Bacillus tequilensis strain 42 may have the potential to be employed as an antiviral agent in poultry cultures to combat Newcastle and influenza, two extremely destructive viruses, thus reducing economic losses in the poultry production sector. Bacteria can be harnessed for the purpose of preserving food and controlling pathogenic fungi in both human and plant environments. Molecular docking for the three highly active derivatives 2,3-Butanediol, 2TMS, D-Xylopyranose, 4TMS, and Glucofuranoside, methyl 2,3,5,6-tetrakis-O-(trimethylsilyl) was carried out against the active sites of Bacillus cereus, Listeria monocytogenes, Candida albicans, Newcastle virus and influenza virus. The data obtained from molecular docking is highly correlated with that obtained from biology. Moreover, these highly active compounds exhibited excellent proposed ADMET profile. [ABSTRACT FROM AUTHOR]

The integration of trees into diverse land-use systems holds potential for India to meet nationally determined contribution (NDC) targets under the Paris Climate Agreement. With a target of sequestering 2.5–3 billion tons of CO2 equivalent by 2030, the study focused on the widespread and economically viable eucalyptus-based agroforestry, practiced widely in various planting geometries tailored to meet industrial end-use requirements. In this context, a detailed study was conducted to quantify the influence of five planting geometries [3 m × 3 m, 6 × 1.5 m, 17 × 1 × 1 m (paired row) and two boundary plantations (east–west and north–south directions) at 2 m away from tree to tree] of eucalyptus on intercrops [dhaincha (Sesbania aculeata)—barley (Hordeum vulgare L.) rotation] biomass, soil properties, and carbon stock of the system during 2009–2016. Results revealed that biomass accumulation of different tree components was 62.50%–74.09% in stem; 6.59%–9.14% in branch; 3.18%–5.73% in leaves; 12.20%–20.44% in stump roots; and 1.71%–3.48% in fine roots across the planting geometries. The mean carbon content of the stem, branch, leaves, and roots was 49.00, 47.00, 43.00, and 49.00%, respectively. Over the 8-year period, geometry of 3 × 3 m performed better in terms of total biomass production (344.60 Mg ha− 1 by tree biomass and 62.53 Mg ha−1 by intercrops). The independent parameter, DBH²H (DBH: diameter at breast height and H: tree height), was found to be a very good predictor of dry weight, followed by DBH alone. Among various functions (linear, allometric, logistic, Gompertz, Chapman, and exponential), the best-fit equation was allometric, i.e., B = 300.96 × DBH²H0.93 (adjusted R² = 0.96) for eucalyptus based on universal model adequacy and validation criteria. The carbon sequestration rate was maximum (20.79 Mg C ha−1 year−1) in 3 × 3 m followed by 17 × 1 × 1 m. The total carbon stock of eucalyptus-based system (tree + crop + soil) varied significantly under different planting geometries and sole crop rotation (dhaincha–barley). The higher carbon stock (237.27 Mg ha−1) was obtained from 3 × 3 m spacing and further partitioning carbon stock in trees—166.29 Mg ha−1, crops—25.01 Mg ha−1 and soil—45.97 Mg ha−1. The paired row spacing (17 × 1 × 1 m) yielded higher crop yield and net returns (Rs. 600,475 ha−1), underscoring wide spacing’s role in system productivity and sustainability. Tree-based systems were valuable components of agriculture, advocating for their widespread adoption to reduce CO2 emissions and generate income through carbon credits. These findings will provide crucial insights into sustainable land-use practices and advance India’s commitment toward adaptation of climate change mitigation strategies. [ABSTRACT FROM AUTHOR]

Soil salinity caused a widespread detrimental issue that hinders productivity in agriculture and ecological sustainability, while waste-derived soil amendments like biochar have drawn attention for their capacity to act as a mitigating agent, by enhancing the physical and chemical features of soil, and contributing to the recovery of agricultural waste resources. However, the information concerning biochar and salinity which affect the physicochemical characteristics of soils, crop physiology, and growth is limited. To investigate whether biochar mitigates the salinity stress on wheat crop seedlings, we grow them with salinity stress (120 mM), and biochar (20 tons ha−1), and its interactive effects. The soil properties of soil organic carbon (SOC), soil organic matter (SOM), dissolved organic carbon (DOC), and soil available phosphorus (SAP) decreased in the saline soil by 36.71%, 46.97%, 26.31%, and 15.00%, while biochar treatment increased SOC, DOC, and SAP contents by 7.42%, 31.57%, and 15.00%, respectively. On the other hand, dissolved organic nitrogen (DON) contents decreased in all the treatments compared to the control. The root growth traits, SPAD values, leaf nitrogen, photosynthetic parameters, antioxidant enzymes, and reactive oxygen species decreased in the saline treatment while increasing in the biochar and interactive treatment. Thus, these activities resulted in higher leaves and root biomass in the biochar treatment alone and interactive treatment of salinity and biochar. According to principal component analysis, redundancy analysis, and the mantel test, using biochar in conjunction with salinity treatment was found to be more effective than salinity treatment alone. The results of this study suggest that biochar can be used as a sustainable agricultural technique and a means of mitigation agent by lowering soil salinity while increasing the biomass of crops. Biochar improves the physical and nutritional quality of soil and plant function. Salinity stress declined the physiological activities and biomass of the crop. Biochar mitigates the salinity stress in soil and enhances the plant functioning. Exposure to both treatments enhances the antioxidant enzyme activity and biomass. [ABSTRACT FROM AUTHOR]

Background: Nitrogen (N) availability is crucial in regulating plants' abiotic stress resistance, particularly at the seedling stage. Nevertheless, plant responses to N under salinity conditions may vary depending on the soil's NH4+ to NO3− ratio. Methods: In this study, we investigated the effects of different NH4+:NO3− ratios (100/0, 0/100, 25/75, 50/50, and 75/25) on the growth and physio-biochemical responses of soybean seedlings grown under controlled and saline stress conditions (0-, 50-, and 100-mM L− 1 NaCl and Na2SO4, at a 1:1 molar ratio). Results: We observed that shoot length, root length, and leaf-stem-root dry weight decreased significantly with increased saline stress levels compared to control. Moreover, there was a significant accumulation of Na+, Cl−, hydrogen peroxide (H2O2), and malondialdehyde (MDA) but impaired ascorbate-glutathione pools (AsA-GSH). They also displayed lower photosynthetic pigments (chlorophyll-a and chlorophyll-b), K+ ion, K+/Na+ ratio, and weakened O2•−-H2O2-scavenging enzymes such as superoxide dismutase, catalase, peroxidase, monodehydroascorbate reductase, glutathione reductase under both saline stress levels, while reduced ascorbate peroxidase, and dehydroascorbate reductase under 100-mM stress, demonstrating their sensitivity to a saline environment. Moreover, the concentrations of proline, glycine betaine, total phenolic, flavonoids, and abscisic acid increased under both stresses compared to the control. They also exhibited lower indole acetic acid, gibberellic acid, cytokinins, and zeatine riboside, which may account for their reduced biomass. However, NH4+:NO3− ratios caused a differential response to alleviate saline stress toxicity. Soybean seedlings supplemented with optimal ratios of NH4+:NO3− (T3 = 25:75 and T = 4 50:50) displayed lower Na+ and Cl− and ABA but improved K+ and K+/Na+, pigments, growth hormones, and biomass compared to higher NH4+:NO3− ratios. They also exhibited higher O2•−-H2O2-scavenging enzymes and optimized H2O2, MDA, and AsA-GSH pools status in favor of the higher biomass of seedlings. Conclusions: In summary, the NH4+ and NO3− ratios followed the order of 50:50 > 25:75 > 0:100 > 75:25 > 100:0 for regulating the morpho-physio-biochemical responses in seedlings under SS conditions. Accordingly, we suggest that applying optimal ratios of NH4+ and NO3− (25/75 and 50:50) can improve the resistance of soybean seedlings grown in saline conditions. [ABSTRACT FROM AUTHOR]

Background: Three Amino acid Loop Extension (TALE) belongs to the homeobox group of genes that are important constituents of plant systems. The TALE gene family is instrumental not only in growth and development but also plays an essential role in regulating plant response to environmental adversaries. Results: In the present study, we isolated 21 CsTALE genes from the cucumber (Cucumis sativus L.) genome database. Bioinformatics tools were put in place to understand the structural and functional components of the CsTALE gene family. The evolutionary analysis dissected them into seven subclades (KNOX-I, KNOX-II, and BELL-I to BELL-V). The cis-acting elements in the promoter region of CsTALE genes disclosed that they are key regulators of hormonal and stress-related processes. Additionally, the STRING database advocated the concerting role of CsTALE proteins with other key transcription factors potent in plant developmental biology. The CsmiR319 and CsmiR167a-3p targeting the CsTALE15 and CsTALE16, respectively, further assert the importance of the CsTALE gene family posttranscriptional-related processes. Tissue-specific gene expression unfolded the fundamental involvement of CsTALE genes as they were expressed throughout the developmental stages. Under waterlogging stress, the CsTALE17 expressed significantly higher values in WL, WL-NAA, and WL-ETH but not in WL-MeJA-treated samples. Conclusions: The present study reveals the evolution and functions of the CsTALE gene family in cucumber. Our work will provide a platform that will help future researchers address the issue of waterlogging stress in the Yangtze River Delta. [ABSTRACT FROM AUTHOR]

Background: Optimum planting date and appropriate fertilizer module are essential facets of chrysanthemum cultivation, to enhance quality yield, and improve soil health. A field-based study was undertaken over multiple growing seasons in 2022 and 2023, where six different planting dates, viz., P1:June 15, P2:June 30, P3:July 15, P4:July 30, P5:August 15 and P6:August 30 and two fertilizer modules, FM1:Jeevamrit @ 30 ml plant−1 and FM2:NPK @ 30 g m−2 were systematically examined using a Randomized Block Design (factorial), replicated thrice. Results: P6 planting resulted in early bud formation (44.03 days) and harvesting stage (90.78 days). Maximum plant height (79.44 cm), plant spread (34.04 cm), cut stem length (68.40 cm), flower diameter (7.83 cm), stem strength (19.38˚), vase life (14.90 days), flowering duration (24.08 days), available soil N (314 kg ha−1), available P (37 kg ha−1), available K (347 kg ha−1), bacterial count (124.87 × 107 cfu g−1 soil), actinomycetes count (60.72 × 102 cfu g−1 soil), fungal count (30.95 × 102 cfu g−1 soil), microbial biomass (48.79 µg g−1 soil), dehydrogenase enzyme (3.64 mg TPF h−1 g−1 soil) and phosphatase enzyme (23.79 mol PNP h−1 g−1 soil) was recorded in P1 planting. Among the fertilization module, minimum days to bud formation (74.94 days) and days to reach the harvesting stage (120.95 days) were recorded with the application of NPK @30 g m−2. However, maximum plant height (60.62 cm), plant spread (23.10 cm), number of cut stems m−2 (43.88), cut stem length (51.34 cm), flower diameter (6.92 cm), stem strength (21.24˚), flowering duration (21.75 days), available soil N (317 kg ha−1), available P (37 kg ha−1) and available K (349 kg ha−1) were also recorded with the application of NPK @300 kg ha−1. Maximum vase life (13.87 days), OC (1.13%), bacterial count (131.65 × 107 cfu g−1 soil), actinomycetes count (60.89 × 102 cfu g−1 soil), fungal count (31.11 × 102 cfu g−1 soil), microbial biomass (51.27 µg g−1 soil), dehydrogenase enzyme (3.77 mg TPF h−1 g−1 soil) and phosphatase enzyme (21.72 mol PNP h−1 g−1 soil) were observed with the application of Jeevamrit @ 30 ml plant−1. Conclusion: Early planting (P1) and inorganic fertilization (NPK @ 30 g m−2) resulted in improved yield and soil macronutrient content. The soil microbial population and enzymatic activity were improved with the jeevamrit application. This approach highlights the potential for improved yield and soil health in chrysanthemum cultivation, promoting a more eco-friendly and economically viable agricultural model. [ABSTRACT FROM AUTHOR]

Background: Lentil is a significant legume that are consumed as a staple food and have a significant economic impact around the world. The purpose of the present research on lentil was to assess the hydrothermal time model's capacity to explain the dynamics of Lens culinaris L. var. Markaz-09 seed germination, as well as to ascertain the germination responses at various sub-optimal temperatures (T) and water potentials (Ψ). In order to study lentil seed germination (SG) behavior at variable water potentials (Ψs) and temperatures (Ts). A lab experiment employing the hydrothermal time model was created. Seeds were germinated at six distinct temperatures: 15 0С, 20 0С, 25 0С, 30 0С, 35 0С, and 40 0С, with five Ψs of 0, -0.3, -0.6, -0.9, and − 1.2 MPa in a PEG-6000 (Polyethylene glycol 6000) solution. Results: The results indicated that the agronomic parameters like Germination index (GI), Germination energy (GE), Timson germination index (TGI), were maximum in 25 0C at (-0.9 MPa) and lowest at 40 0C in 0 MPa. On other hand, mean germination time (MGT) value was highest at 15 0C in -1.2 MPa and minimum at 40 0C in (-0.6 MPa) while Mean germination rate (MGR) was maximum at 40 0C in (0 MPa) and minimum at 15 0C in (-0.6 MPa). Conclusions: The HTT model eventually defined the germination response of Lens culinaris L. var. Markaz-09 (Lentil) for all Ts and Ψs, allowing it to be employed as a predictive tool in Lens culinaris L. var. Markaz-09 (Lentil) seed germination simulation models. [ABSTRACT FROM AUTHOR]

In this investigation, the leaf extract of Olea ferruginea royle was utilized to fabricate organic complexes of Ni (CH3CO2)24H2O, ZrO(CH3COO)2, and Mn (CH3CO2)24H2O, subsequently facilitating the successful preparation of nano-composites comprising NiO, ZrO2, and Mn3O4. Various spectroscopic methodologies were employed to meticulously characterize the synthesized nano-composites. Subsequently, the electrocatalytic prowess of the material for the oxygen evolution process (OER) was assessed. With an onset potential of 1.71V vs. the reversible hydrogen electrode (RHE) and a remarkably low Tafel value of 81mV/dec, the observed performance closely mirrored that of chemically synthesized metal oxide-based catalysts. Extraordinary electro-catalytic activity is attributed to the combined action of the mixed metal oxides and the organic capping agents, which speed up charge transfer and increase the number of active sites. The present work offers valuable perspectives on environmentally friendly synthesis methods for producing high-performance electrode materials for water electrolysis. By employing plant-derived extracts and organic capping agents, this more ecologically friendly synthesis technique has potential for durable and efficient electrocatalysts in a range of energy conversion applications. [ABSTRACT FROM AUTHOR]

Background: The rate of germination and other physiological characteristics of seeds that are germinating are impacted by deep sowing. Based on the results of earlier studies, conclusions were drawn that deep sowing altered the physio-biochemical and agronomic characteristics of wheat (Triticum aestivum L.). Results: In this study, seeds of wheat were sown at 2 (control) and 6 cm depth and the impact of exogenously applied salicylic acid and tocopherol (Vitamin-E) on its physio-biochemical and agronomic features was assessed. As a result, seeds grown at 2 cm depth witnessed an increase in mean germination time, germination percentage, germination rate index, germination energy, and seed vigor index. In contrast, 6 cm deep sowing resulted in negatively affecting all the aforementioned agronomic characteristics. In addition, deep planting led to a rise in MDA, glutathione reductase, and antioxidants enzymes including APX, POD, and SOD concentration. Moreover, the concentration of chlorophyll a, b, carotenoids, proline, protein, sugar, hydrogen peroxide, and agronomic attributes was boosted significantly with exogenously applied salicylic acid and tocopherol under deep sowing stress. Conclusions: The results of the study showed that the depth of seed sowing has an impact on agronomic and physio-biochemical characteristics and that the negative effects of deep sowing stress can be reduced by applying salicylic acid and tocopherol to the leaves. [ABSTRACT FROM AUTHOR]

Large amount of wastes are burnt or left to decompose on site or at landfills where they cause air pollution and nutrient leaching to groundwater. Waste management strategies that return these food wastes to agricultural soils recover the carbon and nutrients that would otherwise have been lost, enrich soils and improve crop productivity. The incorporation of liming materials can neutralize the protons released, hence reducing soil acidity and its adverse impacts to the soil environment, food security, and human health. Biochar derived from organic residues is becoming a source of carbon input to soil and provides multifunctional values. Biochar can be alkaline in nature, with the level of alkalinity dependent upon the feedstock and processing conditions. This study conducted a characterization of biochar derived from the pyrolysis process of eggplant and Acacia nilotica bark at temperatures of 300 °C and 600 °C. An analysis was conducted on the biochar kinds to determine their pH, phosphorus (P), as well as other elemental composition. The proximate analysis was conducted by the ASTM standard 1762-84, while the surface morphological features were measured using a scanning electron microscope. The biochar derived from Acacia nilotica bark exhibited a greater yield and higher level of fixed carbon while possessing a lower content of ash and volatile components compared to biochar derived from eggplant. The eggplant biochar exhibits a higher liming ability at 600 °C compared to the acacia nilotica bark-derived biochar. The calcium carbonate equivalent, pH, potassium (K), and phosphorus (P) levels in eggplant biochars increased as the pyrolysis temperature increased. The results suggest that biochar derived from eggplant could be a beneficial resource for storing carbon in the soil, as well as for addressing soil acidity and enhancing nutrients availability, particularly potassium and phosphorus in acidic soils. [ABSTRACT FROM AUTHOR]

In this manuscript, the first theoretical study of half Heusler compounds RuCrZ (Z = Si, Ge) has been carried out in the context of Density Functional Theory (DFT). The structural, elastic-o-mechanical, electronic, vibrational and magnetic properties of half heusler alloy RuCrZ (Z = Si, Ge) were explored by WIEN2K Code. The energy of ground state and lattice constants were obtained using the optimization curves for both compounds. The elastic and mechanical properties confirmed that RuCrZ (Z = Si, Ge) were elastically stable as well as ductile. The energy band gap result shows there is no band gap for spin up channel that depicts the full metallic nature for RuCrGe while for spin down channel RuCrSi has largest band gap of 0.4 eV that corresponds to its polar nature as compared to the other alloys. The computed values of the lattice constant, as well as the other calculated physical characteristics, were quite close to the experimental values. In phonon dispersion curves optical branches are less coupled in RuCrGe while this effect is not at all observed in RuCrSi while magnetic moments of these materials are comparable to about 1μB, i.e., MTot ≈ 1 μB. [ABSTRACT FROM AUTHOR]

This comprehensive study delves into the synthesis and characterisation of Cu2S:Ni3S4 thin films, fabricated using diethyldithiocarbamate as a sulphur source via physical vapour deposition. A systematic analysis employing various techniques elucidated the material's structural, morphological, and optical properties. The resulting thin film exhibited a well-defined crystalline structure, boasting an average crystallite size of 32.6 nm, indicative of a remarkable crystallinity of 74%. Optical characterisation shed light on the material's optical behaviour, revealing a band gap energy of 2.47 eV. X-ray photoelectron spectroscopy provided insights into the elemental composition and chemical bonding, unveiling distinct core level peaks attributed to Cu 2p, Ni 2p, and S 2p. Electrochemical evaluations through voltammetry measurements showcased exceptional specific capacitive performance, achieving an impressive value of 562 Fg−1. The thin film also demonstrated remarkable stability over multiple cycles, highlighting its immense potential for diverse energy storage applications. Furthermore, extensive investigations into the photocatalytic efficacy of the synthesised material unveiled its remarkable prowess in degrading various environmental pollutants. These significant findings underscore the versatility of Cu2S:Ni3S4 bimetallic sulphide thin films, extending their scope beyond energy storage and paving the way for further exploration and technological advancements in the realms of photocatalysis and beyond. [ABSTRACT FROM AUTHOR]

Phyto-mediated nanocomposite materials possess significant potential in morphological control as well as in electrocatalytic activity, which is the main reason for steered interest in the design of new materials for their applications in water splitting. In this work, nanocomposites of Bi2O3-ZrO2 have been prepared by using Amaranthus viridis L. (AVL)–based aqueous extract as a reducing agent. The synthesized nanomaterial's composition and charge storage properties have been examined in detail. A crystalline structure for the synthesized Bi2O3-ZrO2-based nanocomposite has been elucidated by XRD analysis, while analysis through FTIR, UV, and SEM along with EDX also confirmed the successful biogenic synthesis of the desired nanocomposite. The synthesized biocomposite material is further applied on the nickel foam to be utilized in supercapacitor applications as a working electrode. Results manifest an exceptional specific capacitance value of 283.9 F/g at 2 mV/s by the AVL-Bi2O3-ZrO2 electrode. The columbic efficiency of the electrode was determined to be 99% even after 5000 GCD cycles. The synthesized Bi2O3-ZrO2 nanocomposite is considered to be an efficient electrocatalyst with a comparatively lower band gap of 2.7 eV. This lower bandgap further manifests its potential role in environmental remediation processes through photocatalysis. Additionally, the Bi2O3-ZrO2 composite has also been tested for cyclic stability through chronoamperometry showing reasonable stability. The Ragone plot has been used to determine the power density and energy density as 12 WhKg−1 and 3 KWKg−1 manifesting the higher capacitive behavior of nanocomposite. The synthesized bio-based nanocomposite has a good potential as an electrocatalyst for water splitting having highest productivity of the electrode up to 16.5 h as displayed by hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). To the best of our knowledge, this study represents the first account on the green synthesis of Bi2O3-ZrO2 nanocomposites, wherein Amaranthus viridis L. (AVL) serves as the eco-friendly source, in combination with Bi2O3, which has reduced toxicity, and ZrO2, renowned for its exceptional stability. Our investigation further highlights the importance of synthesis of materials through phytoextract-assisted route for utilization in overall water splitting and energy storage applications. [ABSTRACT FROM AUTHOR]

Drought stress is an important challenge to global food security and agricultural output, and dramatic and rapid climate change has made the problem worse, causing unexpected impacts on the growth, development, and yield of different plants. Understanding the biochemical, ecological, and physiological reactions to these pressures is essential for improved management. Carbon materials' impacts on plants subjected to different stresses are still poorly studied. Thus, this study was carried out investigate the feasibility of applying carbon nanotubes (CNTs) (0, 20, and 40 mg/L) as a foliar treatment for mitigating the effect of water stress (100%, 75%, and 50% irrigation water, IW) on peanut plants growing in sandy soil through assessments of growth and productivity and some physiological and biochemical measurements. Exposure of peanuts to decreased irrigation water led to significant decreases in growth, yield, photosynthetic pigments, indole acetic acid (IAA), and some nutritional components in peanut seeds, but increased levels of osmolytes such as total soluble carbohydrates (TSS) and proline, in addition to free amino acids and phenolics. However, foliar spraying with CNTs could ameliorate the impacts of decreased irrigation water on growth and production via enhancing the studied physiological parameters, such as photosynthetic pigments, IAA, osmolytes, and phenolics. Furthermore, the application of carbon nanotubes improved the nutrient contents, as expressed by the oil yield, protein yield, total carbohydrates, antioxidant activities (DPPH), B-carotene, lycopene, and flavonoids in peanut seeds, either under normal or water stress conditions. The higher level of CNTs (40 mg/L) was more effective than the lower one (20 mg/L) at increasing the above-mentioned parameters. In conclusion, foliar treatment with carbon nanotubes has the ability to enhance peanut drought tolerance and increase its growth and productivity under sandy soil conditions. [ABSTRACT FROM AUTHOR]

Ametoctradin fungicide's ecotoxicological and lithospheric sorption properties have been thoroughly assessed through a variety of experimental techniques that mimic natural environmental circumstances. To achieve this, the current study examined the sorption and degradation of Ametoctradin in 10 different soil samples under carefully monitored laboratory conditions. The negative values of Gibbs-free energy (ΔG), which range from − 15.78 to − 23.56 kj/mol in thermodynamic analysis with a C-type curve are extensively assessed using both linear and Freundlich models. SS5 (soil with highest organic matter) depicted the maximum adsorption (Kd = 41.15 µg/ml), while SS8 (depicting low organic matter content) showed the lowest adsorption extent (Kd = 10.38 µg/ml). GC–MS analysis and UV–visible spectrophotometry were used to evaluate the hydrolytic and photolytic processes involved in Ametoctradin degradation. According to the findings, the hydrolytic and photolytic assays had lowest half-life values of 28.7 and 55.2 days, respectively. Furthermore, the Ametoctradin degradation followed first order reaction kinetics. Soil sample SS6 showed the maximum hydrolytic degradation (57%) due to higher sand content (42%), while SS3 showed the lowest hydrolytic degradation (21%) due to higher silt and clay content. The findings indicated that Ametoctradin exhibited above average binding to the chosen soils, resulting in medium to low persistence as shown by degradation values. Overall, this study offers insightful knowledge about the behavior and fate of Ametoctradin in various soil types, which can help with the creation of practical management plans and environmental risk assessments. [ABSTRACT FROM AUTHOR]

Cadmium significantly impacts plant growth and productivity by disrupting physiological, biochemical, and oxidative defenses, leading to severe damage. The application of Zn-Lys improves plant growth while reducing the stress caused by heavy metals on plants. By focusing on cadmium stress and potential of Zn-Lys on pea, we conducted a pot-based study, organized under completely randomized block design CRD-factorial at the Botanical Garden of Government College University, Faisalabad. Both pea cultivars were grown in several concentrations of cadmium @ 0, 50 and 100 μM, and Zn-Lys were exogenously applied @ 0 mg/L and 10 mg/L with three replicates for each treatment. Cd-toxicity potentially reduces plant growth, chlorophyll contents, osmoprotectants, and anthocyanin content; however, an increase in MDA, H2O2 initiation, enzymatic antioxidant activities as well as phenolic, flavonoid, proline was observed. Remarkably, exogenously applied Zn-Lys significantly enhanced the plant growth, biomass, photosynthetic attributes, osmoprotectants, and anthocyanin contents, while further increase in enzymatic antioxidant activities, total phenolic, flavonoid, and proline contents were noticed. However, application of Zn-Lys instigated a remarkable decrease in levels of MDA and H2O2. It can be suggested with recommendation to check the potential of Zn-Lys on plants under cadmium-based toxic soil. [ABSTRACT FROM AUTHOR]

The escalating presence of heavy metals (HMs) in the Panjkora River water and their impact on fish pose a significant challenge to both the ecological community and human health. Consequently, a study was conducted with the primary aim of elucidating their influence on human health-related issues. To address this, the concentrations of heavy metals, including arsenic (As), cadmium (Cd), iron (Fe), manganese (Mn), lead (Pb), and zinc (Zn), in both water and the fish species Crossocheilus diplocheilus were investigated across various locations within the study area. The quantification of HMs concentration was carried out utilizing an atomic absorption spectrophotometer. The highest concentration in water was found as 0.060 mg/L for Pb and lowest for Fe, whereas the highest concentration in fish was 2.028 mg/kg for Pb and lowest for As. Human health risk associated with fish eating was evaluated by using health risk indices (HRI) for non-carcinogenic health risks and targeted cancer risk (TR) for carcinogenic health risks. The values of the health risk index (HRI) were found greater than 1 except Fe (0.0792), Zn (0.782), and Mn (0.541). The highest mean HRI > 1 was recorded for As (62.99), Cd (26.85), and Pb (10.56). This implies that fish consumption from river Panjkora is not safe up to some extent. Similarly, the TR value for As, Cd, and Pb was found 2.8 × 10 - 2 , 1.6 × 10 - 2 , 2.8 × 10 - 3 which showed cancer risk. There is a detected risk to human health associated with the consumption of fish from the Panjkora River. The government must implement adaptive measures to address this significant issue of water pollution in the study area. Additionally, there is a need for further extensive and prolonged research studies in this context. [ABSTRACT FROM AUTHOR]

In this study, structural, electronic, optical and thermoelectric aspects of Zinc Sulfide (ZnS) and Zinc Telluride (ZnTe) have been explored in detail. These calculations have been done by utilizing FP‐LAPW method via Density Functional Theory (DFT). In order to attain accurate band gaps, opto‐electronic properties are evaluated with modified Becke Johnson potential (mBJ). From band structure plots, both ZnS and ZnTe reveals direct (Γv–ΓC) band gap semiconductors in nature with bandgap value equal to 3.5 and 2.3 eV while in Density Of States (DOS) major influence is observed due to p states of S/Te and d state of Zn. Prominent variation of optical responses such as high values of imaginary dielectric constants 휀1 (ω) and n (ω) refractive index suggests that ZnS and ZnTe are applicant materials for future photonics and microelectronic devices. The thermoelectric aspects were explored by Boltz Trap code to determine electrical and thermal conductivities, Seebeck coefficients, power factors and figure of merit. The figure of merits is closer to 1 while compared with p‐type ZnS and ZnTe, n‐type ZnS and ZnTe has good thermoelectric properties, which are attributed to low thermal conductivity of the hole and larger effective mass. The goal of this research is to investigate not only the detailed physical aspects but also to provide an overview of its future applications in optoelectronics, displays, sensors and microelectronic industry. [ABSTRACT FROM AUTHOR]

In the current industrial scenario, cadmium (Cd) as a metal is of great importance but poses a major threat to the ecosystem. However, the role of micronutrient − amino chelates such as iron − lysine (Fe − lys) in reducing Cr toxicity in crop plants was recently introduced. In the current experiment, the exogenous applications of Fe − lys i.e., 0 and10 mg L − 1, were examined, using an in vivo approach that involved plant growth and biomass, photosynthetic pigments, oxidative stress indicators and antioxidant response, sugar and osmolytes under the soil contaminated with varying levels of Cd i.e., 0, 50 and 100 µM using two different varieties of canola i.e., Sarbaz and Pea − 09. Results revealed that the increasing levels of Cd in the soil decreased plant growth and growth-related attributes and photosynthetic apparatus and also the soluble protein and soluble sugar. In contrast, the addition of different levels of Cd in the soil significantly increased the contents of malondialdehyde (MDA) and hydrogen peroxide (H2O2), which induced oxidative damage in both varieties of canola i.e., Sarbaz and Pea − 09. However, canola plants increased the activities of superoxide dismutase (SOD), peroxidase (POD), catalase (CAT), and non-enzymatic compounds such as phenolic, flavonoid, proline, and anthocyanin, which scavenge the over-production of reactive oxygen species (ROS). Cd toxicity can be overcome by the supplementation of Fe − lys, which significantly increased plant growth and biomass, improved photosynthetic machinery and sugar contents, and increased the activities of different antioxidative enzymes, even in the plants grown under different levels of Cd in the soil. Research findings, therefore, suggested that the Fe − lys application can ameliorate Cd toxicity in canola and result in improved plant growth and composition under metal stress. [ABSTRACT FROM AUTHOR]

Examining proficient electro‐catalyst from earth abundant and sustainable material is highly required for clean energy generation and a step toward fuel cell. In this study, ZnO/ZrO2 mixed metal oxide has been synthesized using organic chemicals in a straightforward and environmentally friendly manner. The greener routes are not only employed for the synthesis of nano structured material but they also improve the charge transfer properties of material in term of high surface area. The as prepared nano‐oxides were probed for phase structure, morphology, surface chemistry and optical properties by spectroscopic techniques. The embedded phyto‐functionalized compounds in the prepared nano‐material were probed by FTIR and GC–MS demonstrating the phyto‐functionalization of ZnO/ZrO2 nanomaterial. Thereafter, effects of functionalization were observed on the electrochemical behavior of synthesized material. The electrochemical investigation revealed remarkable catalytic activity of fabricated ZnO/ZrO2 with small overpotential and Tafel slope for current density of 10 mA cm−2. Therefore, current work demonstrated the promising electrocatalytic potential of fabricated mixed metal oxide and paved a cost effective and efficient organic template to synthesize binary or ternary mixed oxide with enhanced electrocatalytic properties. [ABSTRACT FROM AUTHOR]

Textile dyes are one of the major water pollutants released into water in various ways, posing serious hazards for both aquatic organisms and human beings. Bioremediation is a significantly promising technique for dye decolorization. In the present study, the fungal strain Lasiodiplodia sp. was isolated from the fruiting bodies of Schizophyllum for the first time. The isolated fungal strain was examined for laccase enzyme production under solid-state fermentation conditions with wheat bran (WB) using ABTS and 2,6-Dimethoxyphenol (DMP) as substrates, then the fermented wheat bran (FWB) was evaluated as a biosorbent for Congo red dye adsorption from aqueous solutions in comparison with unfermented wheat bran. A Box–Behnken design was used to optimize the dye removal by FWB and to analyze the interaction effects between three factors: fermentation duration, pH, and dye concentration. Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), and scanning electron microscopy (SEM) were applied to study the changes in the physical and chemical characteristics of wheat bran before and after fermentation. An additional experiment was conducted to investigate the ability of the Lasiodiplodia sp. YZH1 to remove Congo red in the dye-containing liquid culture. The results showed that laccase was produced throughout the cultivation, reaching peak activities of ∼6.2 and 22.3 U/mL for ABTS and DMP, respectively, on the fourth day of cultivation. FWB removed 89.8% of the dye (100 mg L−1) from the aqueous solution after 12 h of contact, whereas WB removed only 77.5%. Based on the Box–Behnken design results, FWB achieved 93.08% dye removal percentage under the conditions of 6 days of fermentation, pH 8.5, and 150 mg L−1 of the dye concentration after 24 h. The fungal strain removed 95.3% of 150 mg L−1 of the dye concentration after 8 days of inoculation in the dye-containing liquid culture. These findings indicate that this strain is a worthy candidate for dye removal from environmental effluents. [ABSTRACT FROM AUTHOR]

The tolerance of Chenopodium ambrosioides to some heavy metals under in vitro environment was thoroughly investigated. A micropropagation protocol was developed to facilitate the mass production of plants and to identify metals-tolerant species for potential use in the restoration of polluted areas. Nodal explants exhibited callus formation when treated with N6-benzyladenin (BA) (1.5 mg/l) and a combination of BA/*-naphthalene acetic acid (NAA) at concentrations of 1.5/1.0 mg/l on the Murashige and Skoog (MS) medium. The optimal shoot formation was achieved with the callus grown on a medium enriched with 1.5/1.0 mg/l BA/NAA, resulting in an impressive number (21.89) and length (11.79 cm) of shoots. The in vitro shoots were rooted using NAA (1.0 and 1.5 mg/l) and were acclimatized in pots with 71% survival rate. After standardizing micropropagation protocol, the in vitro shoots were subjected to various doses of lead nitrate (Pb(NO3)2 and cadmium chloride (CdCl2). Pb(NO3)2 and CdCl2 in the media let to a reduction in shoot multiplication, decreasing from 18.73 in the control group to 11.31 for Pb(NO3)2 and 13.89 for CdCl2 containing medium. However, Pb(NO3)2 and CdCl2 promoted shoot length from 5.61 in the control to 9.86 on Pb(NO3)2 and 12.51 on CdCl2 containing medium. In the case of Pb(NO3)2 treated shoots, the growth tolerance index (GTI) ranged from117.64% to 194.11%, whereas for CdCl2 treated shoots, the GTI ranged from 188.23% to 264.70%. Shoots treated with high level of Pb(NO3)2 induced reddish-purple shoots, while a low level of Pb(NO3)2 induced shoots displayed both green and reddish-purple colors in the same explants. In CdCl2 treated culture, the toxic effects were narrow leaf lamina, elongated petiole and a dark reddish purple coloration. These findings highlight the remarkable potential of C. ambrosioides to maintain growth and organogenesis even in the presence Pb(NO3)2 and CdCl2 on the MS medium, indicating a high degree of metal tolerance. [ABSTRACT FROM AUTHOR]

Exotic plants usually exhibit problems for native species where they coexist. This study evaluated the effect of naturalized alien Cenchrus echinatus L. on native plants in urban vegetation. A field trial was conducted to assess the effect of this species on the cover and diversity of the native vegetation. The allelopathic potential of such species was examined. Sites comprising C. echinatus had a lower cover than some native species. Lower floristic diversity was observed at higher densities of this plant. The soil under this plant attained lower N, P, and K contents. This soil had no effect on the germination and growth of native species. It also comprised germinable seeds of some species which were absent from the standing vegetation. Exotic C. echinatus may exert negative effects on the native vegetation of the urban plant communities. A dense cover of this species may inhibit the germination of native species, leading to a reduction in their cover. Reduction in cover and diversity of native species may not be attributed to allelopathy. These results suggest that naturalized C. echinatus may be more competitive than the native ones, particularly at higher densities. Furthermore, it may represent a threat to the native plants in the urban vegetation. [ABSTRACT FROM AUTHOR]

Recent anthropogenic sources and excess usage have immensely threatened the communities and habitat ecology of this region's medicinally and economically significant crops. Therefore, our study aims to evaluate the community structure and related environmental characteristics sustaining Nasturtium officinale communities along the river basin (RB) in Northwest Pakistan, using the clustering procedure (Ward's method) and Redundancy analysis (RDA). From 340 phytosociological plots (34 x 10 = 340), we identified four ecologically distinct assemblages of N. officinale governed by different environmental and anthropogenic factors for the first time. The floristic structure shows the dominance of herbaceous (100%), native (77%), and annual (58.09%) species indicating relatively stable communities; however, the existence of the invasive plants (14%) is perturbing and may cause instability in the future, resulting in the replacement of herbaceous plant species. Likewise, we noticed apparent variations in the environmental factors, i.e., clay percentage (p = 3.1 x 10-5), silt and sand percentage (p< 0.05), organic matter (p< 0.001), phosphorus and potassium (p< 0.05), and heavy metals, i.e., Pb, Zn, and Cd (p< 0.05), indicating their dynamic role in maintaining the structure and composition of these ecologically distinct communities. RDA has also demonstrated the fundamental role of these factors in species-environment correlations and explained the geospatial variability and plants' ecological amplitudes in the Swat River wetland ecosystem. We concluded from this study that N. officinale communities are relatively stable due to their rapid colonization; however, most recent high anthropogenic interventions especially overharvesting and sand mining activities, apart from natural enemies, water deficit, mega-droughts, and recent flood intensification due to climate change scenario, are robust future threats to these communities. Our research highlights the dire need for the sustainable uses and conservation of these critical communities for aesthetics, as food for aquatic macrobiota and humans, enhancing water quality, breeding habitat, fodder crop, and its most promising medicinal properties in the region. [ABSTRACT FROM AUTHOR]

In the study, we have fabricated Ag@Li dual shell hallow nanosphere (Ag@Li DSHN) by chemical reduction method for the dual non-enzymatic detection of glucose and phosphorus. TEM image of Ag@Li DSHN confirms the dual shell hallow nanosphere with Li core and Ag shell. The XRD spectrum of Ag@Li DSHN shows the particle was crystalline in nature. The dual detection of glucose and phosphorus by Ag@Li DSHN showed high sensitivity, and selectivity as a potential sensing probe. Zeta potential and average particle size of Ag@Li DSNH was found to be − 32.9 mV ± 2.1 mV and 12 ± 1.3 nm respectively. The limit of detection of glucose and phosphorus by Ag@Li DSHN was 2.8 and 2.9 nM respectively. Furthermore, the environmental parameter (pH, temperature and saline concentration) on the detection of glucose and phosphorus by Ag@Li DSHN was studied. Additionally, the real sample detection by Ag@Li DSHN towards the detection of glucose and phosphorus was studied and the recovery % was from 97 to 99%. Hence, Ag@Li DSHN can be used for the effective detection of glucose and phosphorus form environmental sample. [ABSTRACT FROM AUTHOR]

Rapid industrialization demands for effective nano-photocatalyst that works under visible-light irradiation. The effective p–n interfacial engineering in nanoparticles (NPs) offers better photocatalytic performance. High performing nano-heterojunction of intimately coupled n-copper ferrite (CuFe2O4) NPs on p-nickel oxide (NiO) NPs was prepared that mitigates the charge recombination. X-ray diffraction confirmed the coexistence of the rhombohedral NiO and tetragonal CuFe2O4 in the prepared NCs. The bandgap energy of NiO/CuFe2O4 NCs-30 is 2.18 eV which supports visible light photocatalysis. The rate constant for degrading the methylene blue (MB) dye by NiO/CuFe2O4 NCs-30 was about 0.010 min−1 which is 1.42 times and 2 times higher when compared to NiO and CuFe2O4 NPs. The reusability efficiency was 94.54%. It has been found that both OH⋅ and ⋅O2− radical formed and contributed in degrading MB dye. The importance of the prepared NCs can be understood from its effective performance and it can be concluded that it has high photocatalytic potential to degrade the aquatic pollutants. [ABSTRACT FROM AUTHOR]

Introduction: Non-native species are globally successful invaders with negative impacts on vegetation communities’ social, economic, and ecological values. Hence, the current research was carried out to assess the spatial distribution patterns and vegetative diversity of the four non-native species in severely invaded areas of the semi-arid parts of northern Pakistan. Methods: The research was conducted using data from 1065 plots spread across 165 sites. These sites represented habitats throughout Northern Province, such as farm countryside, highlands, and abandoned places in rural and urban areas. Results and discussion: The communities were floristically diverse, represented by 107 plant species, and dominated mainly by annual and perennial life forms with herbaceous habits. Similarly, the floristic structure shows significant variation tested by the χ2 test (P< 0.05) for plant status, life forms, life cycle, and habitat base distribution. In addition, the diversity indices show significant variation having the highest diversity in C-III (P. hysterophorus-dominated sites) and lowest in C-IV (S. marianum-dominated sites, i.e., primarily pure communities), indicating non-native species may increase or decrease site diversity. The diversity communities were further supported by higher quantities of soil nutrients, i.e., organic percentage (2.22 ± 0.04). Altitude, soil nutrients, and texture were shown to be the environmental factors most associated with communities that non-native species had invaded. Recommendation: It is recommended that relevant, additional soil and climatic parameters be integrated into species distribution models to improve our understanding of the ecological niches of different species and to make a collective approach for preserving and conserving native plant communities. [ABSTRACT FROM AUTHOR]