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We report the structural and chemical investigation of nine presolar silicate grains from the CH3/CBb3 chondrite Isheyevo and CR2 chondrite Northwest Africa (NWA) 801. Five of these grains belong to group 1, likely condensed in low- to intermediate-mass asymptotic giant branch (AGB) stars, super-AGB stars, or core-collapse supernovae, while the remaining four grains belong to group 4 and have a supernova origin. The advanced transmission electron microscopy and associated electron spectroscopy analyses show a diverse range of chemical and structural compositions for presolar silicates. Two GEMS (glass with embedded metal and sulfide)-like silicates, each from different groups, condensed under nonequilibrium conditions in stellar outflows. Two nonstoichiometric silicates from group 1 have dissimilar formation and alteration histories. An amorphous silicate from group 1 with olivine-like [(Mg,Fe)2SiO4] composition likely formed as a crystalline olivine that subsequently amorphized in the interstellar medium. An oldhamite (CaS) grain within a stoichiometric enstatite (MgSiO3) from group 1 probably formed by heterogeneous condensation in circumstellar outflows. Of the two crystalline grains from group 4, one is an antigorite [(Mg,Fe)3Si2O5(OH)4], while the other is a nontronite [Na,Fe2(Si,Al)4O10(OH)2.nH2O], both formed as a crystalline forsterite and later altered to have hydrated silicate composition. A group-4 silicate has a chemical composition similar to a low Ca-pyroxene [(Ca,Mg)(Si,Al)2O6]. Our data imply that presolar grains from different groups can have a similar range of grain-formation conditions. [ABSTRACT FROM AUTHOR]

The sputtering rate of presolar silicon carbide grains due to galactic cosmic rays has been computed for their experimentally deduced lifetimes (∼1 Gyr) in the interstellar medium. An ion target simulator, SDTrimSP, was used to model the sputtering of interstellar grains with varying sizes and thicknesses of the ice mantle formed around the grain during their journey through the interstellar medium. Temperature, composition, and density for four different types of molecular cloud environments (quiescent, low-mass young stellar objects (YSOs), intermediate-mass YSOs, and high-mass YSO weak processing) considered indicate the sputtering rate on the mantle ice composition depends on water composition to a certain extent. The model simulations indicate galactic cosmic ray(s) with an energy range from 10 MeV to 1 GeV are just capable of sputtering/destructing ∼13%–15% of the grain itself. This value, stretched over 1 Gyr is not as significant as the other destruction processes and therefore can be classified as a minor destruction process. The effect of galactic cosmic rays on the ice mantle and core is also noted with particular emphasis on amorphization/recoils generated inside the SiC core and their distribution within the grain. [ABSTRACT FROM AUTHOR]