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Olivine crystals in alkaline basalts preserve important information about the Oxygen fugacity and thermal condition of the mantle‐derived magma. This paper presents new olivine mineral chemistry and whole‐rock geochemistry for Early‐Cretaceous alkali basalts in the Ganjia area, northeastern margin of the Tibetan Plateau. The olivine phenocrysts of Ganjia basalts have low Ni (74–2261 ppm) and high Ca contents (1217–4443 ppm), similar to the olivines in MORB, suggesting that they were crystallized from peridotite‐derived basaltic magma. Al‐in‐olivine/spinel thermometer results indicate crystallization temperatures of olivine around 1202 ± 46°C, corresponding to a mantle potential temperature of 1279 ± 47°C, with low oxygen fugacity of FMQ −1 to FMQ 0, suggesting a reduced mantle source. Whole‐rock geochemical compositions of the Ganjia basalts were characterized by low SiO2 contents (45.39%–48.70 wt%), high alkali contents (3.88–5.11 wt%), positive Nb and Ta anomalies, and enrichment in LREEs, HFSEs and LILEs, similar to those of OIB rocks, with high ratios of (Dy/Yb)N (1.38–1.54) and (La/Yb)N (5.37–7.42) ratios, indicating garnet residue. The above results suggest that the Early Cretaceous intraplate alkaline basalts in West Qinling were formed by a low degree of partial melting of peridotite and that no high‐temperature mantle plume existed. The Qinling Orogenic Belt may have been affected by the subduction of the Palaeo‐Pacific. We propose that the Ganjia basalts originated from the interaction between the upwelling asthenosphere and a lithospheric source. [ABSTRACT FROM AUTHOR]

Early Palaeozoic alkaline magmatism is widely preserved in the North Daba Mountains, South Qinling Belt (SQB), predominately composed of basalt–diabase and trachyte–syenite. The petrogenesis of the felsic rocks and their genetic connections with the mafic members remain controversial. Here, an integrated investigation, combining geochronology and whole-rock and Sr–Nd isotopic geochemistry, is conducted to further constrain the origin and tectono-magmatic evolution of the trachytes in Pingli–Zhuxi area, North Daba Mountains. Zircon U–Pb dating for the Pingli–Zhuxi trachytes yield ages of 406.0 to 427.9 Ma, which are close to those of the mafic rocks (420–455 Ma) in research area. The trachytes show relatively high SiO2 (60.88–63.87 wt.%) and total alkali (Na2O + K2O = 10.19–12.24 wt.%) contents, and are characterized by pronounced enrichment in LREEs and HFSEs, with insignificantly negative Eu anomalies and significantly negative Sr anomalies. All of the samples display low and variable initial 87Sr/86Sr ratios of 0.6959 to 0.7083 and narrow range initial 143Nd/144Nd ratios of 0.5123 to 0.5125 with positive εNd(t) values of +3.0 to +7.3, suggesting a depleted source. Together with the published data from coeval SQB diabases, our geochemistry evidences show regular and linear variations between mafic and felsic end-members, suggesting their closely genetic link. A plausible petrogenetic hypothesis for the genesis of the Pingli–Zhuxi trachytes implies a protracted process of fractional crystallization driven by separation of K-feldspar, plagioclase, biotite, apatite, and Ti-magnetite from a basaltic melt. Enrichment in REEs and HFSEs and similar geochemical characteristics point to that the Pingli–Zhuxi trachytes and the coeval mafic rocks originate from a cogenetic metasomatized lithosphere source in rift setting. Asthenospheric upwelling is a key factor for continental break up and lithosphere metasomatism. Collectively, melting of the metasomatized source, followed by protracted K-feldspar-dominated fractional crystallization, leading to the occurrence of the Pingli–Zhuxi trachytes in the North Daba Mountains. [ABSTRACT FROM AUTHOR]

High-K calc-alkaline to shoshonitic suites are widespread and generally volumetrically small but provide key information on magmatic mantle-crust interactions. Limited work has addressed the multi-stage formation of relatively high-volume high-K to shoshonitic rocks. A newly identified, Late-Cretaceous to Early-Cenozoic high-volume high-K to shoshonitic association (ca. 28,000 km3) is described, from the southeastern Himalayan–Tibetan orogen. The mafic intrusions are shoshonitic (K2O contents, ~ 3.3 wt.%), have high-Mg contents (~ 5.1 wt.%) with high-Mg# (57), LREE and LILEs with low Ba/Th, Ba/La, Sm/La (< 0.3), Nb/Yb and 208Pb/206Pb ratios but high Hf/Sm (> 0.70), Th/Yb, Th/La (> 0.2) and La/Sm, and lack an Eu anomaly. Their mafic minerals are hydrous, dominated by magnesio-hornblende (Mg#, ~ 0.69–0.73) and Mg- and K-biotite (MgO, 7.27–9.26 wt.%; K2O, 9.65–10.1 wt.%). Such characteristics strongly suggest derivation from the sub-continental lithospheric mantle (SCLM), metasomatized by sediment-derived melts/fluids. The associated felsic intrusions have high SiO2, alkali content (Na2O + K2O contents up to 10.0 wt.%) and incompatible elements (e.g., K, Rb), with ferropargasite-hastingsite and ferrobiotite-siderophyllite as the mafic phases. These characteristics point to derivation from the continental crust enriched by fluids, likely those released from the contemporaneous mafic magmas crystallising at depth. In contrast to low-volume potassic magmatism from post-collision and earliest arc-rift settings, these high-volume high-K and shoshonitic intrusions define a mantle-to-upper crust pathway at an active continental margin. Alongside geophysical data, these observations are consistent with the contemporary subduction history, arising from subduction of the Neo-Tethyan ocean slab to initial collision of India-Asia, from steepening subduction to slab rollback and breakoff. [ABSTRACT FROM AUTHOR]

The relationship between the Shangdan and Erlangping suture zone (ESZ) and the initiation stretch time of the Early Paleozoic back‐arc system in the Qinling Orogen still remains unclear. This paper reports the chronological and geochemical data of the Miaogou mafic intrusion along the southern margin of the Shangdan suture. The pyroxenite in the mafic intrusion has a zircon U–Pb age of 485 ± 5 Ma (Mean Standard Weighted Deviation (MSWD) = 0.08, n = 18). It has low SiO2 (45.41–46.02 wt%), K2O (0.42–0.44 wt%), and TiO2 (0.73–0.83 wt%) contents, high MgO (13.9–15.13 wt%) contents with high Mg# (74–77). In combination with its high clinopyroxene portion, the pyroxenite represented the accumulates from the mafic magma. Some sieve rims of the clinopyroxene indicate that the primitive pyroxenite was metasomatized by subduction‐related fluids. However, their consistent trace element and rare earth element (REE) patterns suggest that the metasomatism process has insignificant effects on their geochemical features. Zircons from the pyroxenite have positive εHf(t) (+7.18 to +11.75) values, reveal a depleted source region. In combination with its high V (322–1,093 ppm) contents, low Ti/V (10–15) ratios and smooth REE patterns, we propose that the pyroxenite was derived from metasomatized depleted mantle wedge in a back‐arc basin. In considering the duration limit (<475 Ma) of the back‐arc basin along the ESZ, we argued that the ~485 Ma Miaogou pyroxenite represented the initiation back‐arc basin in the Shangdan suture, which might represent the initial rifting of the North Qinling microcontinent induced by the northward subduction of the Shangdan Ocean. [ABSTRACT FROM AUTHOR]

Proterozoic igneous rocks in the southern margin of the North China Craton can place constraints on its crustal evolution. This paper reports geochemistry, zircon U-Pb ages, Sr-Nd isotopes and Lu-Hf isotopes for the Proterozoic Angou granite from the southwestern margin of the North China Craton (NCC). The Angou granite has zircon LA-ICP-MS U-Pb age of 1819 ± 14Ma (MSWD = 1.3, n = 37), which is synchronous with the Proterozoic Xiong'er Group in the southeastern margin of the NCC. The granite has A-type granite affinity: (1) high SiO2 (67.12% to 73.16%) and alkali (Na2O+K2O = 7.18% to 8.75%) contents, with K2O/Na2O ratios of 1.04 to 4.78; (2) high FeOT/MgO values (4 to 36); (3) significantly negative Eu anomalies (Eu*/Eu = 0.33 to 0.53) and negative Sr anomalies (38.1 to 102ppm); (4) high 104× Ga/Al (2.55 to 4.75, with an average of 3.43) values and Zr+Ce+Nb+Y (634 to 1022ppm) contents; (5) high zircon saturation temperatures (871 to 957°C). In combination with its slightly peraluminous (A/CNK = 1.02 to 1.26) nature, the Angou granite can be classified as slightly peraluminous A-type granite. It displays negative ɛNd(t) values of −2.0 to −3.9, variable εHf(t) values (−8.81 to +1.98) with Hf model ages of 2194 to 2721Ma, combined with its high Rb/Sr (1.05 to 3.26) and low Rb/Ba (0.08 to 0.18) ratios, suggesting that the Angou granite was derived from high temperature melting of tonalite in middle-lower crust. The formation of Angou A-type granite is consistent with the mafic dyke swarms and Xiong'er bimodal volcanic rocks in NCC, indicating a Paleoprotozoic extensional setting in the southwestern margin of the NCC. [ABSTRACT FROM AUTHOR]

The Lesser Xing'an–Zhangguangcai Range is located in the eastern part of the Central Asian Orogenic Belt (CAOB). Early Mesozoic igneous rocks in this area can place constraints on the crustal growth mechanism in the Northeastern China. This paper reports a suite of Late Triassic high‐Mg diorites and mafic dikes from the southern Lesser Xing'an–Zhangguangcai Range. The mafic dikes have younger zircon U–Pb ages of 195 ± 2 Ma. They display intermediate SiO2 (50.58% to 58.20%) and high Na2O/K2O ratios of 1.90 to 3.20, low A/CNK ratios of 0.75 to 0.84, low (87Sr/86Sr)i ratios of 0.7045 to 0.7046, and high εNd(t) values of +3.1 to +3.5. Most zircons in the mafic dikes exhibit positive εHf(t) values from +8.6 to +16.0, with single‐stage Hf model ages ranging from 0.2 to 0.5 Ga in combination with their enrichment in LREE and LILEs and depletion in HFSEs. They are considered to be formed by melting of metasomatized subarc lithosphere mantle. The diorite and quartz diorite have older zircon U–Pb ages of 200 ± 3 and 202 ± 2 Ma, respectively. They have SiO2 = 54.45% to 61.18%, Al2O3 = 17.16% to 19.10%, TiO2 = 0.74% to 1.13%, and Mg# = 46.6 to 49.5, and they also display moderately depleted Sr–Nd (εNd(t) = +2.3 to +4.3) and zircon Lu–Hf (εHf(t) = +8.6 to +16.0) isotopic compositions. These features suggest that they were formed by melting of juvenile arc crust in active continental margin. Considering the occurrence of the contemporaneous and latter igneous rocks in the Zhangguangcai Range, we argue that the diorite, quartz diorite, and mafic dikes from the Lengshan area were also related to the westward subduction of Palaeo‐Pacific Plate (Izanagi Plate) beneath the Eurasian Plate. The strike‐like fault along the eastern margin of the Songneng–Zhuangguangcai Block may play an important role in the genesis of diorite melt. [ABSTRACT FROM AUTHOR]

Neoproterozoic igneous rocks along the northern Yangtze Block are closely related to the evolution of the Rodinia supercontinent. This paper presents zircon U–Pb dating, whole‐rock geochemistry and Sr‐Nd isotopes of the gabbro–granite association from the Micangshan area, northern Yangtze Block. Zircon LA‐ICP MS U–Pb dating indicates that the tonalite and monzogranite from the Pinghe display identical ages of 869 ± 4 Ma (MSWD = 1.3, 2σ) and 859 ± 8 Ma (MSWD = 1.9, 2σ), respectively. According to the regional geology, the gabbro may be younger. The monzogranite and tonalite display almost identical geochemical features, both of them have high Na2O/K2O ratios, with insignificant negative Eu anomalies, relatively juvenile Sr‐Nd isotopic compositions. The monzogranite has initial (87Sr/86Sr)i ratios of 0.703403 to 0.705218, and positive ɛNd(t) values of +1.23 to +2.98. The tonalite have (87Sr/86Sr)i ratios of 0.700387 to 0.706222, positive ɛNd(t) values of +1.98 to +7.79, indicating that they were derived from juvenile source. The 860 Ma monzogranite–tonalite association suggests crustal growth event in an active continental margin. The gabbro has low (La/Yb)N ratios (1.80 to 7.61) and total rare earth element contents (∑REE = 44.95 to 83.92 ppm), they have initial (87Sr/86Sr)i ratios of 0.701913 to 0.704815, positive ɛNd(t) values of +0.65 to +5.73, indicating an island‐arc affinity. In combination with the other Neoproterozoic igneous rocks along the western and northern margin of the Yangtze Block, we propose that the gabbro and granitoid association from the Micangshan area represent two stage crustal growth events in the active continental margin setting, and these results imply that the Neoproterozoic crustal growth events in the Yangtze Block may be controlled by subduction. [ABSTRACT FROM AUTHOR]

This paper presents precise zircon U–Pb, bulk-rock geochemical, and Sr–Nd–Pb isotopic data for metagabbro, quartz diorite, and granite units within the Tengchong Block of SW China, which forms the southeastern extension of the Himalayan orogeny and the southwestern section of the Sanjiang orogenic belt, a key region for furthering our understanding of the evolution of the eastern Paleo-Tethys. These data reveal four groups of zircon U–Pb ages that range from the late Paleozoic to the early Mesozoic, including a 263.6 ± 3.6 Ma quartz diorite, a 218.5 ± 5.4 Ma two-mica granite, a 205.7 ± 3.1 Ma metagabbroic unit, and a 195.5 ± 2.2 Ma biotite granite. The quartz diorite in this area contains low concentrations of SiO2 (60.71–64.32 wt%), is sodium-rich, and is metaluminous, indicating formation from magmas generated by a mixed source of metamafic rocks with a significant metapelitic sedimentary material within lower arc crust. The two-mica granites contain high concentrations of SiO2 (73.2–74.3 wt%), are strongly peraluminous, and have evolved Sr–Nd–Pb isotopic compositions, all of which are indicative of a crustal source, most probably from the partial melting of felsic pelite and metagreywacke/psammite material. The metagabbros contain low concentrations of SiO2 (50.17–50.96 wt%), are sodium-rich, contain high concentrations of Fe2O3T (9.79–10.06 wt%) and CaO (6.88–7.12 wt%), and are significantly enriched in the Sr (869–894 ppm) and LREE (198.14–464.60 ppm), indicative of derivation from magmas generated by a metasomatized mantle wedge modified by the sedimentary-derived component. The biotite granites are weakly peraluminous and formed from magmas generated by melting of metasedimentary sources dominated by metagreywacke/psammite material. Combining the petrology and geochemistry of these units with the regional geology of the Indosinian orogenic belt provides evidence for two stages of magmatism: an initial stage that generated magmas during partial melting of mantle-derived material associated with late Permian-to-Early Triassic subduction of the Paleo-Tethys, and a second stage that generated granitoid magmas by the partial melting of crustal-derived sources during the Late Triassic collision between the Lhasa and Tengchong blocks and the northern margin of the Australian continent. These rocks, therefore, provide evidence of a systematic late Permian-to-Late Triassic transition from a pre-collision/volcanic arc setting through a collisional setting to a final within-plate phase of magmatism. The previous research involving bulk-rock Sr–Nd analyses of units from the southern Sanjiang orogenic belt and zircon Hf isotopic analyses of units from the Tengchong Block suggests that these areas may record similar magmatic evolutionary trends from mantle- to crustal-derived sources during the evolution of the eastern Paleo-Tethys. [ABSTRACT FROM AUTHOR]

Voluminous Neoproterozoic mafic–ultramafic, felsic, and alkaline intrusions are found in the northern Yangtze Block, South China. Here, we present whole-rock major and trace element, and Sr–Nd isotopic compositions, together with zircon U–Pb ages, for syenite and gabbro samples from the Shuimo–Zhongziyuan alkaline intrusive complex in the Micang Mountains region at the northwestern margin of the Yangtze Block. Zircon U–Pb dating yields crystallization ages for the Na- and K-rich Shuimo syenites of 869 ± 4 (MSWD = 0.85, 2σ) and 860 ± 5 Ma (MSWD = 0.47, 2σ), respectively, and for the Zhongziyuan gabbros of 753 ± 4 Ma (MSWD = 0.23, 2σ), indicating that the syenites and gabbros represent different stages of magmatism. The syenites include both Na- and K-rich types and have high values of the Rittman index (σ), and high SiO2and Na2O + K2O contents. These syenites are enriched in light rare earth elements (LREE) and large-ion lithophile elements (LILE), but depleted in high-field-strength elements (HFSE), with high (La/Yb)Nvalues and small negative and positive Eu anomalies (Eu/Eu* = 0.74–1.17). In contrast, the gabbros have lower SiO2and Na2O + K2O contents, are only slightly enriched in LREEs, are enriched in LILE but depleted in HFSEs, and have small negative and positive Eu anomalies (Eu/Eu* = 0.86–1.37). The syenites have low initial87Sr/86Sr (0.703340) andɛNd(t) values (+1.9 to +7.7). The gabbros have relatively high initial87Sr/86Sr (0.703562–0.704933) and positiveɛNd(t) values (+1.6 to +4.5). These data suggest that the syenites and gabbros are isotopically similar and were largely derived from melts of depleted mantle. The syenites underwent significant fractional crystallization and small amounts of crustal contamination during magma evolution. In contrast, the gabbros were formed by partial melting (>15%) of a garnet lherzolite source and might also have experienced crustal assimilation. Taking into account the geochemical signatures and magmatic events, we propose that the Shuimo syenites formed in an intra-arc rifting setting, however, the Zhongziyuan gabbros were most likely produced in a subduction-related, continental margin arc setting during the Neoproterozoic, thus suggesting that the alkaline intrusive complex were formed by the arc-related magmatism in the Micang Mountains. [ABSTRACT FROM PUBLISHER]

Zircon U–Pb ages and geochemical and isotopic data for Late Ordovician granites in the Baoshan Block reveal the early Palaeozoic tectonic evolution of the margin of East Gondwana. The granites are high-K, calc-alkaline, metaluminous to strongly peraluminous rocks with A/CNK values of 0.93–1.18, are enriched in SiO2, K2O, and Rb, and depleted in Nb, P, Ti, Eu, and heavy rare earth elements, which indicates the crystallization fractionation of the granitic magma. Zircon U–Pb dating indicates that they formed at ca. 445 Ma. High initial87Sr/86Sr ratios of 0.719761–0.726754, negative ɛNd(t) values of –6.6 to –8.3, and two-stage model ages of 1.52–1.64 Ga suggest a crustal origin, with the magmas derived from the partial melting of ancient metagreywacke at high temperature. A synthesis of data for the early Palaeozoic igneous rocks in the Baoshan Block and adjacent Tengchong Block indicates two stages of flare-up of granitic and mafic magmatism caused by different tectonic settings along the East Gondwana margin. Late Cambrian to Early Ordovician granitic rocks (ca. 490 Ma) were produced when underplated mafic magmas induced crustal melting along the margin of East Gondwana related to the break-off of subducted Proto-Tethyan oceanic slab. In addition, the cession of the mafic magmatism between late Cambrian-Early Ordovician and Late Ordovician could have been caused by the collision of the Baoshan Block and outward micro-continent along the margin of East Gondwana and crust and lithosphere thickening. The Late Ordovician granites in the Baoshan Block were produced in an extensional setting resulting from the delamination of an already thickened crust and lithospheric mantle followed by the injection of synchronous mafic magma. [ABSTRACT FROM AUTHOR]

The geological record of the Neoproterozoic to early Palaeozoic Proto-Tethyan Ocean in Southeast Asia is not clear. To better constrain the evolution of the Proto-Tethys, we present new geochronology, geochemistry, and petrology of the late Cambrian to Ordovician Pinghe pluton monzogranite from the Baoshan block, western Yunnan, southwest China. Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) analyses of four zircon samples yield ages of 482–494 and 439–445 Ma for the pluton, interpreted as two episodes within one magmatic event accompanying the whole process of subduction–collision–orogeny between buoyant blocks and oceanic crust of the Proto-Tethys. The monzogranite belongs to the strong peraluminous, high-K, calc-alkaline series and shows characteristics of both I-type and S-type granitic rocks. It is characterized by extremely high Rb/Sr and Rb/Ba but low TiO2, MgO, FeOt, and CaO/Na2O ratios. The monzogranite is also moderately enriched in light rare earth elements (LREEs), depleted in heavy rare earth elements (HREEs), lacks HREE fractionation, and has strongly negative Eu (Eu/Eu* = 0.06–0.49), Ba, Nb, Ta, Sr, and Ti anomalies. Whole-rockεNd(t) andεHf(t) values range from −8.7 to −11.6 and −5.55 to −9.58, respectively. Nd and Hf two-stage model ages range from 1.66 to 2.06 Ga and 2.14 to 3.00 Ga, respectively, with variable radiogenic206Pb/204Pb(t)(16.547–18.705),207Pb/204Pb(t)(15.645–15.765), and208Pb/204Pb(t)(38.273–38.830). These signatures suggest that the monzogranite magma was derived from partial melting of heterogeneous metapelite, which was generated from Neoarchean to Palaeoproterozoic materials mixed with basaltic magma. The monzogranite magma underwent crystallization differentiation of plagioclase, K-feldspar, and ilmenite. Magmatism to form the Pinghe pluton occurred in a post-collisional setting. Based on the comparison of coeval granites throughout adjacent regions (e.g. Himalayan orogen, Lhasa Terrane, and parts of Gondwana supercontinent), we propose that the Baoshan block was derived from the northern Australian Proto-Tethyan Andean-type active continental margin of Gondwana and experienced subduction of the Proto-Tethyan oceanic crust and accretion of an outboard micro-continent. The Pinghe pluton could have formed when a subducting oceanic slab broke off during collision. [ABSTRACT FROM AUTHOR]