1. Enhanced photoelectrocatalytic performance of ZnIn2S4 modified TiO2 nanotube array toward methylene blue.
- Author
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Wang, Junxiang, Chen, Zhenyu, Song, Qianqian, He, Qingming, Zhou, Xindong, Chen, Ping, Wang, Jingang, Wang, Tao, Yang, Hui, and Li, Lin
- Subjects
METHYLENE blue ,NANOTUBES ,X-ray photoelectron spectroscopy ,WATER pollution ,SEMICONDUCTOR materials ,POLLUTION ,VISIBLE spectra - Abstract
Environmental pollution caused by organic pollutants has been attracted more and more attention by the researchers. In this paper, ZnIn
2 S4 modified TiO2 nanotube array (ZnIn2 S4 /TiO2 ) composite electrodes are prepared by loading chalcogenide semiconductor material ZnIn2 S4 on the surface of TiO2 nanotube array (TiO2 NTA) for the degradation of methylene blue (MB). The physicochemical properties of ZnIn2 S4 /TiO2 composite electrodes are analyzed by X-ray photoelectron spectroscopy, X-ray diffraction, photoluminescence spectroscopy and so on. The photoelectrocatalytic degradation rate of ZnIn2 S4 /TiO2 composite electrode with the concentration of ZnIn2 S4 as 0.5 mmol/L (ZISTO-2) reaches 93.3% under the bias voltage of 0.7 V and simulated sunlight irradiation for 180 min against MB, which is 22.44% higher than that of pure TiO2 NTA electrode, and the degradation rate of ZISTO-2 composite electrode toward MB is maintained at 78.2% after five cycles. The radical trapping experiments indicate that h+ , ·O2− and ·OH has significant contribution in the photoelectrocatalytic degradation. This paper provides a new ideal way to solve the problem of water pollution under visible light. [ABSTRACT FROM AUTHOR]- Published
- 2024
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