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1. First examples of oxaphosphirane pentacarbonylchromium(0) and -molybdenum(0) complexes: synthesis, structures and reactionsElectronic supplementary information (ESI) available. CCDC reference numbers 792187(8a), 792188(8b), 792185(8c), 792186(8d), 792183(8e), 792190(9a), 792189(9c), 792194(15a), 792195(15b), 792184(15e), 792192(16a), 792193(16b), 792191(16c), 792196(17), 792197(18). For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c0dt01509a

2. Activation of Aryl Germanium(II) Chlorides by [Mo(PMe3)6] and [W(η2-CH2PMe2)H(PMe3)4]: A New Route to Metal–Germanium Triple BondsWe are grateful to the Humboldt-Universität zu Berlin and the Deutsche Forschungsgemeinschaft (project FI 445/6-1) for the generous financial support of this work, Dr. B. Ziemer and P. Neubauer for technical assistance with the X-ray diffraction studies, Dr. U. Hartmann and U. Kätel for the elemental analyses, and Dr. C. Mügge, W.-D. Bloedorn, A. Thiesies, C. Schmidt, and K. Prochnicki for NMR experiments. N.W. thanks the Fonds der Chemischen Industrie for a fellowship.

3. Activation of Aryl Germanium(II) Chlorides by [Mo(PMe3)6] and [W(η2-CH2PMe2)H(PMe3)4]: A New Route to Metal–Germanium Triple BondsWe are grateful to the Humboldt-Universität zu Berlin and the Deutsche Forschungsgemeinschaft (project FI 445/6-1) for the generous financial support of this work, Dr. B. Ziemer and P. Neubauer for technical assistance with the X-ray diffraction studies, Dr. U. Hartmann and U. Kätel for the elemental analyses, and Dr. C. Mügge, W.-D. Bloedorn, A. Thiesies, C. Schmidt, and K. Prochnicki for NMR experiments. N.W. thanks the Fonds der Chemischen Industrie for a fellowship.

4. Ge2 Trapped by Triple Bonds between Two Metal Centers: The Germylidyne Complexes trans,trans-[Cl(depe)2M≡Ge—Ge≡M(depe)2Cl] (M=Mo, W) and Bonding Analyses of the M≡Ge—Ge≡M ChainWe are grateful to the Humboldt-Universität zu Berlin, the Deutsche Forschungsgemeinschaft (project FI 445/6-1), and the IKYDA program (D/03/40387) for the generous financial support of this work, Dipl. Ing. I. Hinz for assistance in the experimental work, Dr. U. Hartmann and U. Kätel for the elemental analyses and Dr. M. Feist for the STA analysis. N. Weidemann thanks the Fonds der Chemischen Industrie for a fellowship. depe=Et2PCH2CH2PEt2.

7. Tungsten–Lead Triple Bonds: Syntheses, Structures, and Coordination Chemistry of the Plumbylidyne Complexes trans-[X(PMe3)4W≡Pb(2,6-Trip2C6H3)]We are grateful to the Humboldt-Universität zu Berlin and the Deutsche Forschungsgemeinschaft (project FI 445/6-1) for the generous financial support of this work, Dr. B. Ziemer and P. Neubauer for the X-ray diffraction studies, Dr. U. Hartmann and U. Kätel for the elemental analyses, and W.-D. Bloedorn and A. Thiesies for the 2D NMR spectra. N. Weidemann thanks the Fonds der Chemischen Industrie for a fellowship. X=Br, I; Trip=2,4,6-iPr3C6H2.

8. Tungsten–Lead Triple Bonds: Syntheses, Structures, and Coordination Chemistry of the Plumbylidyne Complexes trans-[X(PMe3)4W≡Pb(2,6-Trip2C6H3)]We are grateful to the Humboldt-Universität zu Berlin and the Deutsche Forschungsgemeinschaft (project FI 445/6-1) for the generous financial support of this work, Dr. B. Ziemer and P. Neubauer for the X-ray diffraction studies, Dr. U. Hartmann and U. Kätel for the elemental analyses, and W.-D. Bloedorn and A. Thiesies for the 2D NMR spectra. N. Weidemann thanks the Fonds der Chemischen Industrie for a fellowship. X=Br, I; Trip=2,4,6-iPr3C6H2.

9. Triple Bond to Lead: Synthesis and Characterization of the Plumbylidyne Complex trans-[Br(PMe3)4Mo≡Pb—C6H3-2,6-Trip2] ( Financial support of this work was provided by the Humboldt-Universität zu Berlin and the Graduiertenkolleg GRK-352/3 “Synthetische, mechanistische und reaktionstechnische Aspekte von Metallkatalysatoren”. We thank Dr. A. I. Philippopoulos and Dr. P. Portius for the initiative work in this area. Trip=2,4,6-iPr3-C6H2. )

10. Triple Bond to Lead: Synthesis and Characterization of the Plumbylidyne Complex trans-[Br(PMe3)4Mo≡Pb—C6H3-2,6-Trip2] ( Financial support of this work was provided by the Humboldt-Universität zu Berlin and the Graduiertenkolleg GRK-352/3 “Synthetische, mechanistische und reaktionstechnische Aspekte von Metallkatalysatoren”. We thank Dr. A. I. Philippopoulos and Dr. P. Portius for the initiative work in this area. Trip=2,4,6-iPr3-C6H2. )

13. Diastereoselective self-assembly of dinuclear heterochiral metallosupramolecular rhombs in a self-discriminating processCCDC 707180. For crystallographic data in CIF format, see DOI: 10.1039/b819335e.

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