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This study presents a review of prognostic methods applied to automotive proton exchange membrane fuel cell (PEMFC). PEMFC durability is strongly affected when it is subjected to automotive load cycling (ALC). ALC is normally composed of four operation modes such as start‐up, idle, transient high‐current demand and shutdown. All of these operation modes drastically change the internal variables of the system like temperature, pressure, relative humidity etc. causing degradation of the fuel cell components in a short time. Prognostic methods could be a possible solution to tackle the PEMFC's low durability issue because they allow predicting the remaining useful life of the system in order to apply preventive maintenance plans. Therefore, the objective of this study is to review the prognostic techniques applied to PEMFC under ALC. In the first part of this study, a summary of PEMFC degradation mechanisms caused by ALC is realised based on literature review. In the second part, the prognostic methods review for automotive PEMFCs is carried out and a general synthesis and future challenges are given in the third part of the study. [ABSTRACT FROM AUTHOR]

This paper presents a study of the carbon support corrosion and mitigation strategies through the use of a pseudo-3D model. This model consists in coupling a 2D model along the channel with another model perpendicular to the flow at the rib/channel scale. Simulations offer a deeper understanding of the corrosion through the analysis of the local conditions. Rib/channel heterogeneities show the higher degradation in the zones facing the anodic rib. These results are validated qualitatively on literature data by analysis of SEM images and carbon dioxide concentration at the cathode outlet. Three mitigation strategies are studied using the model. The first one consists in speeding up the hydrogen filling of the cell. The second strategy involves an external electrical resistance to create a current leak during the startup. Third, a design study of the rib/channel is performed to minimize the cathode degradation. Whatever the mitigation strategy, it consists in reducing either the duration or the magnitude of the high cathode electrode potential. [ABSTRACT FROM AUTHOR]

One of the bottlenecks hindering the usage of polymer electrolyte membrane fuel cell technology in automotive applications is the highly load-sensitive degradation of the cell components. The cell failure cases reported in the literature show localized cell component degradation, mainly caused by flow-field dependent non-uniform distribution of reactants. The existing methodologies for diagnostics of localized cell failure are either invasive or require sophisticated and expensive apparatus. In this study, with the help of a multiscale simulation framework, a single polymer electrolyte membrane fuel cell (PEMFC) model is exposed to a standardized drive cycle provided by a system model of a fuel cell car. A 2D multiphysics model of the PEMFC is used to investigate catalyst degradation due to spatio-temporal variations in the fuel cell state variables under the highly transient load cycles. A three-step (extraction, oxidation, and dissolution) model of platinum loss in the cathode catalyst layer is used to investigate the cell performance degradation due to the consequent reduction in the electro-chemical active surface area (ECSA). By using a time-upscaling methodology, we present a comparative prediction of cell end-of-life (EOL) under different driving behavior of New European Driving Cycle (NEDC) and Worldwide Harmonized Light Vehicles Test Cycle (WLTC). [ABSTRACT FROM AUTHOR]