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The finite volume time domain (FVTD) method is proposed to accurately calculate the electromagnetic (EM) scattering of hypersonic vehicles coated with non-uniform plasma sheath. The plasma sheath in the actual flight environment is accurately established by solving the Navier–Stokes equations and combining appropriate thermochemical models. The radar cross section (RCS) of metal and uniform medium coated metal targets calculated by FVTD are in good agreement with those simulated by the software FEKO (MoM) and the Mie series. The calculated RCS of the vehicle under the reentry condition is consistent with the flight test data, too. The calculated electron number density distribution is consistent with the flight experiment results. The body fitted structure EM grid is adopted. The EM grid independence of the target coated with plasma sheath is studied. Then, the scattering and plasma EM parameters of the vehicle during the actual reentry are studied. The reentry altitude is from 78 to 55 km, and the reentry velocity is from 6406 to 6350 m/s. With the reentry altitude decreasing, the plasma angular frequency and collision frequency increased gradually. The scattering of different incident conditions and different wall catalytic conditions is analyzed in depth. This paper provides a valuable reference for vehicles' detection, recognition, and stealth during reentry flights. [ABSTRACT FROM AUTHOR]