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Zirconium mononitride (ZrN), among other nitrides, is of interest as a catalyst in general and especially for the electrochemical nitrogen reduction reaction (NRR). Synthesis of nanoparticulate ZrN is challenging due to the formation of undesired other phases and the need for hazardous precursors or high temperatures. The urea glass method (UGM) was used in this work to synthesise nanoparticulate zirconium nitride. A focused parameter variation of the precursor composition and process conditions lead to an optimised synthesis, greatly improving material purity in regard to minor phase and residual carbon content. The nitride starts to form at a pyrolysis temperature of 900 °C, likely by irreversible decomposition of previously‐formed oxynitride, which forms from amorphous ZrO2 and urea during pyrolysis. An increased pyrolysis temperature improves product purity but slightly lowers nitride purity. Calcium admixture slows the urea decomposition, yielding a more phase‐pure product with less residual carbon at low amounts. A classical carbothermal nitridation (CN) was used in comparison to the UGM to synthesise ZrN. This was successful in synthesising zirconium carbonitride Zr(N, C) without minor phase, but significant carbon remains if added overstoichiometrically. Using less carbon and a longer dwelling time yielded ZrN without significant carbide (ZrC) incorporation or residual carbon, but with some minor ZrO2 phase, proving a promising synthesis route. A limited electrochemical investigation of a synthesised ZrN material was carried out to scope the general material behaviour and to qualitatively derive the potential catalytic activity for the NRR. Higher reductive currents in nitrogen‐saturated electrolyte qualitatively point to NRR activity, but further and more in‐depth examination is required. [ABSTRACT FROM AUTHOR]

Infants born to mothers with phenylketonuria (PKU) may develop congenital abnormalities because of elevated phenylalanine (Phe) levels in the mother during pregnancy. Maintenance of blood Phe levels between 120 and 360 μmol/L reduces risks of birth defects. Sapropterin dihydrochloride helps maintain blood Phe control, but there is limited evidence on its risk–benefit ratio when used during pregnancy. Data from the maternal sub‐registries—KAMPER (NCT01016392) and PKUDOS (NCT00778206; PKU‐MOMs sub‐registry)—were collected to assess the long‐term safety and efficacy of sapropterin in pregnant women in a real‐life setting. Pregnancy and infant outcomes, and the safety of sapropterin were assessed. Final data from 79 pregnancies in 57 women with PKU are reported. Sapropterin dose was fairly constant before and during pregnancy, with blood Phe levels maintained in the recommended target range during the majority (82%) of pregnancies. Most pregnancies were carried to term, and the majority of liveborn infants were reported as 'normal' at birth. Few adverse and serious adverse events were considered related to sapropterin, with these occurring in participants with high blood Phe levels. This report represents the largest population of pregnant women with PKU exposed to sapropterin. Results demonstrate that exposure to sapropterin during pregnancy was well‐tolerated and facilitated maintenance of blood Phe levels within the target range, resulting in normal delivery. This critical real‐world data may facilitate physicians and patients to make informed treatment decisions about using sapropterin in pregnant women with PKU and in women of childbearing age with PKU who are responsive to sapropterin. [ABSTRACT FROM AUTHOR]

The first magnetic field in a star other than the Sun was detected in 1947 in the star 78 Vir. Today, we know that about 10% of these intermediate-mass and high-mass stars have strong, large-scale surface magnetic fields whose origin has remained a mystery till today. It has been suggested that merging of main-sequence and pre-main-sequence stars could produce such strong fields. The massive star τ Sco is a well-known member of the group of magnetic stars and is a blue straggler given its apparently young age compared to that of other members of the Upper Scorpius association. Here, we present 3D magnetohydrodynamic simulations of the coalescence of two massive main-sequence stars and 1D stellar evolution computations of the subsequent evolution of the merger product that can explain τ Sco's magnetic field, apparent youth and other observed characteristics. We argue that field amplification in stellar mergers is a general mechanism to form strongly-magnetised massive stars. Such stars are promising progenitors of magnetars, which may give rise to some of the enigmatic fast radio bursts, and their supernova explosions may be affected by the strong magnetic fields. [ABSTRACT FROM AUTHOR]

A solid-state polymer electrolyte (SPE) could be a viable alternative in order to reduce polysulfide mobility and to mitigate the shuttle effect in lithium–sulfur batteries. In this work, single lithium-ion conducting solid polymer electrolytes (SLIC-SPEs) based on a lithiated Nafion membrane have been prepared and characterized for such a purpose. In the search for organic aprotic swelling solvents that do not cause instability or phase separation problems in the membrane and are suitable for use in lithium–sulfur batteries, only a few were found. They included a mixture of ethylene carbonate (EC) and propylene carbonate (PC), and glyme molecules that did not cause undesirable leaching of the solvent during thermal cycling. A thorough and systematic study of lithium-ion transport was conducted on the swollen membranes by pulsed-field gradient nuclear magnetic resonance (PFG-NMR) and electrochemical impedance spectroscopy (EIS), while the mechanical properties have been tested by dynamic mechanical analysis (DMA). A combination with gas phase infiltrated sulfur–carbon composite cathodes did not only enable the use of carbonate-based solvents in a quasi-solid-state lithium sulfur full cell, but also allow almost complete utilization of the active material without the need for liquid electrolyte additions. Carbonate plasticized Nafion electrolyte improves safety as it is non-toxic, high-boiling and non-flammable. The material combination of a sulfur embedded cathode and ionomer/EC/PC thus opens the way to applications in the field of thin, mechanically flexible and safe high-energy batteries for smart textiles. [ABSTRACT FROM AUTHOR]

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Copyright of Revue d'Orthopédie Dento-Faciale is the property of Parresia and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Drinking water contaminated by pathogenic micro-organisms increases the risk of infectious gastrointestinal disease which could potentially lead to acute kidney injury and even death, particularly amongst the young and the elderly. Earlier studies have shown a substantial reduction in the incidence of diarrheal disease over a period of one year using a polysulfone membrane water gravity-powered water filtration device. The current report is a continuation of these studies to assess the long-term effects of the innovative method on diarrheal incidence rates over a 4-year follow-up period. This follow-up study monitored the trend of self-reported diarrheal events in all households in the previously studied villages for 5 months, in the last half of each study year, using the same questionnaire utilized in the earlier study. Three villages that had no device yet installed served as controls. We computed monthly diarrheal incidence rates for all study years (standardized to per 100 person-months) and compared these to the pre-device incidence rate in 2018 and in the control group, using the Wilcoxon rank sum exact test. The average diarrheal incidence rates of 1.5 p100pm in 2019, 2.19 p100pm in 2021, and 0.54p100pm in 2022 were significantly different from an earlier study that reported 17.8 p100pm rates before the devices were installed in 2018, (all p-values < 0.05). Concomitantly, self-reported diarrheal infections were substantially higher in the “control villages” not yet having the filtration device installed (80.9, 77.6, and 21.5 per 100 pm). The consistent and large reduction in diarrhea incidence documents the long-term efficacy of the use of the membrane filtration device. This simple water purification method using gravity flow improves public health in remote regions with limited resources. [ABSTRACT FROM AUTHOR]

Fe‐N‐C catalysts are a promising alternative to replace cost‐intensive Pt‐based catalysts in high temperature polymer electrolyte membrane fuel cell (HT‐PEMFC) electrodes. However, the electrode fabrication needs to be adapted for this new class of catalysts. In this study, gas diffusion electrodes (GDEs) are fabricated using a commercial Fe‐N‐C catalyst and different polytetrafluorethylene (PTFE) binder ratios, varying from 10 to 50 wt % in the catalyst layer (CL). The oxygen reduction reaction performance is investigated under HT‐PEMFC conditions (160 °C, conc. H3PO4 electrolyte) in a half‐cell setup. The acidophilic character of the Fe‐N‐C catalyst leads to intrusion of phosphoric acid electrolyte into the CL. The strength of the acid penetration depends on the PTFE content, which is visible via the contact angles. The 10 wt % PTFE GDE is less capable to withdraw product water and electrolyte and results into the lowest half‐cell performance. Higher PTFE contents counterbalance the acid drag into the CL and impede flooding. The power density at around 130 mA mgCatalyst−2 increases by 34 % from 10 to 50 wt % PTFE. [ABSTRACT FROM AUTHOR]

We implement general relativistic hydrodynamics in the moving-mesh code arepo. We also couple a solver for the Einstein field equations employing the conformal flatness approximation. The implementation is validated by evolving isolated static neutron stars using a fixed metric or a dynamical space–time. In both tests, the frequencies of the radial oscillation mode match those of independent calculations. We run the first moving-mesh simulation of a neutron star merger. The simulation includes a scheme to adaptively refine or derefine cells and thereby adjusting the local resolution dynamically. The general dynamics are in agreement with independent smoothed particle hydrodynamics and static-mesh simulations of neutron star mergers. Coarsely comparing, we find that dynamical features like the post-merger double-core structure or the quasi-radial oscillation mode persist on longer time scales, possibly reflecting a low numerical diffusivity of our method. Similarly, the post-merger gravitational wave emission shows the same features as observed in simulations with other codes. In particular, the main frequency of the post-merger phase is found to be in good agreement with independent results for the same binary system, while, in comparison, the amplitude of the post-merger gravitational wave signal falls off slower, i.e. the post-merger oscillations are less damped. The successful implementation of general relativistic hydrodynamics in the moving-mesh arepo code, including a dynamical space–time evolution, provides a fundamentally new tool to simulate general relativistic problems in astrophysics. [ABSTRACT FROM AUTHOR]

For renewable hydrogen production, polymer electrolyte membrane water electrolysis is the most promising technology. However, the technology is not yet competitive with conventional hydrogen production in terms of cost. The impact of cost reduction options on CAPEX and OPEX is investigated. Depending on the hours of operation, the main cost factor is the production and manufacturing of components or the price of electricity. Clearly a tremendous need to implement low‐cost electrolysis cells on a large scale to bring green hydrogen production costs to a level 1–3 € kg−1 hydrogen. [ABSTRACT FROM AUTHOR]

Platinum on graphitized low surface area carbon (Pt/C) is coated with a silicon oxide thin film and is employed as anode catalyst to manipulate the tolerance of proton exchange membrane fuel cells toward carbon monoxide and hydrogen sulfide contamination. The SiO2 coating, prepared by successive hydrolysis of 3‐aminopropyl‐triethoxisilane and tetraethoxysilane, forms clusters in proximity to Pt in sizes comparable to the catalyst particles, leaving most of the carbon surfaces free. The performance with and without CO is investigated in situ at relative humidities (RH) of 100%, 70%, and 40%. When operated with neat hydrogen, SiO2‐Pt/C shows marginally better performance owing to an improved protonic conduction due to the water retaining hydrophilic SiO2. Upon operation with CO‐contaminated fuel, the SiO2‐Pt/C performs worse than that of Pt/C particularly at high RH. CO stripping measurements reveal an increase in CO oxidation potential for the SiO2‐Pt/C, suggesting an increased CO coverage and consequently higher anode overpotentials during operation with CO‐contaminated fuel. Upon operation with H2S in the fuel, the SiO2 coating extends the lifetime until the cell voltage broke down, which is attributed to the enhanced water retention due to SiO2 and the solubility of sulfuric species. [ABSTRACT FROM AUTHOR]

The double detonation is a widely discussed mechanism to explain Type Ia supernovae from explosions of sub-Chandrasekhar mass white dwarfs. In this scenario, a helium detonation is ignited in a surface helium shell on a carbon/oxygen white dwarf, which leads to a secondary carbon detonation. Explosion simulations predict high abundances of unburnt helium in the ejecta, however, radiative transfer simulations have not been able to fully address whether helium spectral features would form. This is because helium can not be sufficiently excited to form spectral features by thermal processes, but can be excited by collisions with non-thermal electrons, which most studies have neglected. We carry out a full non-local thermodynamic equilibrium radiative transfer simulation for an instance of a double detonation explosion model, and include a non-thermal treatment of fast electrons. We find a clear He  i λ10830 feature which is strongest in the first few days after explosion and becomes weaker with time. Initially this feature is blended with the Mg  ii λ10927 feature but over time separates to form a secondary feature to the blue wing of the Mg  ii λ10927 feature. We compare our simulation to observations of iPTF13ebh, which showed a similar feature to the blue wing of the Mg  ii λ10927 feature, previously identified as C  i. Our simulation shows a good match to the evolution of this feature and we identify it as high velocity He  i λ10830. This suggests that He  i λ10830 could be a signature of the double detonation scenario. [ABSTRACT FROM AUTHOR]

Assessing novel electrocatalysts for the electrochemical ammonia synthesis (EAS) requires reliable quantitative trace analysis of electrochemically produced ammonia to infer activity and selectivity. This study concerns the development of an ion chromatography (IC) method for quantitative trace analysis of ammonium in 0.1 M sulfuric acid electrolyte, which is applied to EAS gas‐diffusion electrode (GDE) experiments with commercial chromium nitride as electrocatalyst. The developed IC method is highly sensitive, versatile, and reliable, achieving a limit of quantification (LOQ) of 6 μg l−1 (6 ppbmol) ammonium. The impacts of the sample matrix, dilution, and neutralization, as well as contamination, on the quantitative analysis by IC are analyzed. Experimental constraints result in an effective LOQ including dilution of 60 μg l−1 for the determination of ammonium in 0.1 M sulfuric acid electrolyte, owing to necessary sample dilution. The practical guide presented herein is intended to be very relevant for the field of EAS as a guideline and applicable to a broad range of catalyst systems and ion chromatography devices. [ABSTRACT FROM AUTHOR]

When the primary star in a close binary system evolves into a giant and engulfs its companion, its core and the companion temporarily orbit each other inside a common envelope. Drag forces transfer orbital energy and angular momentum to the envelope material. Depending on the efficiency of this process, the envelope may be ejected leaving behind a tight remnant binary system of two stellar cores, or the cores merge retaining part of the envelope material. The exact outcome of common-envelope evolution is critical for in the formation of X-ray binaries, supernova progenitors, the progenitors of compact-object mergers that emit detectable gravitational waves, and many other objects of fundamental astrophysical relevance. The wide ranges of spatial and temporal timescales that characterize common-envelope interactions and the lack of spatial symmetries present a substantial challenge to generating consistent models. Therefore, these critical phases are one of the largest sources for uncertainty in classical treatments of binary stellar evolution. Three-dimensional hydrodynamic simulations of at least part of the common-envelope interaction are the key to gain predictive power in modeling common-envelope evolution. We review the development of theoretical concepts and numerical approaches for such three-dimensional hydrodynamic simulations. The inherent multi-physics, multi-scale challenges have resulted in a wide variety of approximations and numerical techniques to be exercised on the problem. We summarize the simulations published to date and their main results. Given the recent rapid progress, a sound understanding of the physics of common-envelope interactions is within reach and thus there is hope that one of the remaining fundamental problems of stellar astrophysics may be solved before long. [ABSTRACT FROM AUTHOR]

We are witnessing the dawn of gravitational wave (GW) astronomy. With currently available detectors, observations are restricted to GW frequencies in the range between ~10 Hz and 10 kHz, which covers the signals from mergers of compact objects. The launch of the space observatory LISA will open up a new frequency band for the detection of stellar interactions at lower frequencies. In this work, we predict the shape and strength of the GW signals associated with common-envelope interaction and merger events in binary stars, and we discuss their detectability. Previous studies estimated these characteristics based on semi-analytical models. In contrast, we used detailed three-dimensional magnetohydrodynamic simulations to compute the GW signals. We show that for the studied models, the dynamical phase of common-envelope events and mergers between main-sequence stars lies outside of the detectability band of the LISA mission. We find, however, that the final stages of common-envelope interactions leading to mergers of the stellar cores fall into the frequency band in which the sensitivity of LISA peaks, making them promising candidates for detection. These detections can constrain the enigmatic common-envelope dynamics. Furthermore, future decihertz observatories such as DECIGO or BBO would also be able to observe this final stage and the post-merger signal, through which we might be able to detect the formation of Thorne- Zytkow objects. [ABSTRACT FROM AUTHOR]

Porous gas‐diffusion electrodes (GDEs) are widely used in electrochemical applications where a gaseous reactant is converted to a target product. Important applications for silver‐based GDEs are the chlor‐alkali and the CO2 electrolysis processes in which silver catalyzes the oxygen‐ or carbon dioxide reduction reaction. The wetting of the porous GDEs is of utmost importance for the achieved performance of the electrode: a completely dry electrode will result in low current densities due to the reduced active surface area while on the other hand, a completely flooded electrode will deteriorate the access of the gaseous reactant. Therefore, we investigated silver‐based GDEs for the oxygen reduction reaction with different amounts of the hydrophobic agent polytetrafluoroethylene (PTFE) and analyzed the potential‐induced wetting behavior (electrowetting). The electrolyte breakthrough was recorded by a digital microscope and subsequently evaluated via imaging analysis of the observed breached electrolyte droplets. In order to characterize the wetting state during transition to the steady‐state, we applied electrochemical impedance spectroscopy measurements and retrieved the double‐layer capacitance. Our results indicate that a higher overvoltage facilitates the breakthrough of electrolytes through the gas‐diffusion electrode. Surprisingly, a faster breakthrough of electrolyte was observed for electrodes with higher PTFE content. Porometry measurements revealed that the GDE with low PTFE content has a monomodal pore size distribution, whereas electrodes with higher PTFE amount exhibit a bimodal pore size distribution. In GDEs with monomodal pore size distribution the time in which the double layer capacitance is leveling off correlates with the breakthrough time of the electrolyte. In summary, we emphasize that the wetting of GDEs is a complex interplay of the applied potential, electrode composition, and resulting porous structure which requires further advanced measurements and analysis considering the parameters affecting the wetting behavior as a whole. [ABSTRACT FROM AUTHOR]

Double detonations of sub-Chandrasekhar mass white dwarfs are a promising explosion scenario for Type Ia supernovae, whereby a detonation in a surface helium shell triggers a secondary detonation in a carbon-oxygen core. Recent work has shown that low-mass helium shell models reproduce observations of normal SNe Ia. We present 3D radiative transfer simulations for a suite of 3D simulations of the double detonation explosion scenario for a range of shell and core masses. We find light curves broadly able to reproduce the faint end of the width–luminosity relation shown by SNe Ia, however, we find that all of our models show extremely red colours, not observed in normal SNe Ia. This includes our lowest mass helium shell model. We find clear Ti  ii absorption features in the model spectra, which would lead to classification as peculiar SNe Ia, as well as line blanketing in some lines of sight by singly ionized Cr and Fe-peak elements. Our radiative transfer simulations show that these explosion models remain promising to explain peculiar SNe Ia. Future full non-LTE simulations may improve the agreement of these explosion models with observations of normal SNe Ia. [ABSTRACT FROM AUTHOR]

However, and from hearsay, it became public opinion among physicians that a patient has to shiver during dialysis treatment, otherwise he/she would not have received a good dialysis. Jürgen had a great interest in researching quality of life issues for hemodialysis patients [[26]] and particularly among elderly patients [[28]]. During his clinical practice, Jürgen was continuously worried about the low hematocrit of dialysis patients followed by their reduced physical abilities. [[10]], Bommer advanced the need for a filtered dialysis fluid in 2001 in order to reduce patient risks. [Extracted from the article]

The chemical industry must become carbon neutral by 2050, meaning that process‐, energy‐, and product‐related CO2 emissions from fossil sources are completely suppressed. This goal can only be reached by using renewable energy, secondary raw materials, or CO2 as a carbon source. The latter can be done indirectly through the bioeconomy or directly by utilizing CO2 from air or biogenic sources (integrated biorefinery). Until 2030, CO2 waste from fossil‐based processes can be utilized to curb fossil CO2 emissions and reach the turning point of global fossil CO2 emissions. A technology mix consisting of recycling technologies, white biotechnology, and carbon capture and utilization (CCU) technologies is needed to achieve the goal of carbon neutrality. In this context, CHEMampere contributes to the goal of carbon neutrality with electricity‐based CCU technologies producing green chemicals from CO2, N2, O2, and H2O in a decentralized manner. This is an alternative to the e‐Refinery concept, which needs huge capacities of water electrolysis for a centralized CO2 conversion with green hydrogen, whose demand is expected to rise dramatically due to the decarbonization of the energy sector, which would cause a conflict of use between chemistry and energy. Here, CHEMampere's core reactor technologies, that is, electrolyzers, plasma reactors, and ohmic resistance heating of catalysts, are described, and their technical maturity is evaluated for the CHEMampere platform chemicals NH3, NOx, O3, H2O2, H2, CO, and CxHyOz products such as formic acid or methanol. Downstream processing of these chemicals is also addressed by CHEMampere, but it is not discussed here. [ABSTRACT FROM AUTHOR]

Mergers of neutron stars and black holes are nowadays observed routinely thanks to gravitational-wave astronomy. In the isolated, binary-evolution channel, a common-envelope phase of a red supergiant and a compact object is crucial to sufficiently shrink the orbit and thereby enable a merger via gravitational-wave emission. Here, we use the outcome of three-dimensional hydrodynamic common-envelope simulations of a 9.4 solar mass red supergiant and a 5 solar mass black-hole to explore the further evolution and final fate of the remnant binary. The binary system undergoes another phase of mass transfer during which it is visible as an X-ray binary. We find that the donor star does not explode as an ultra-stripped supernova because of the large remaining envelope mass, but as a Type Ib/c supernova. Supernova kicks are actually required to sufficiently perturb the orbit and thus facilitate a merger within a Hubble time via gravitational-wave emission. [ABSTRACT FROM AUTHOR]

Supernovae of Type Iax (SNe Iax) are an accepted faint subclass of hydrogen-free supernovae. Their origin, the nature of the progenitor systems, however, is an open question. Recent studies suggest that the weak deflagration explosion of a near-Chandrasekhar-mass white dwarf in a binary system with a helium-star donor could be the origin of SNe Iax. In this scenario, the helium-star donor is expected to survive the explosion. We use the one-dimensional stellar evolution codes MESA and Kepler to follow the postimpact evolution of the surviving helium companion stars. The stellar models are based on our previous hydrodynamical simulations of ejectaâ€"donor interaction, and we explore the observational characteristics of these surviving helium companions. We find that the luminosities of the surviving helium companions increase significantly after the impact: they could vary from 2500 L ⊙ to 16,000 L ⊙ for a Kelvinâ€"Helmholtz timescale of about 104 yr. After the star reaches thermal equilibrium, it evolves as an O-type hot subdwarf (sdO) star and continues its evolution along the evolutionary track of a normal sdO star with the same mass. Our results will help to identify the surviving helium companions of SNe Iax in future observations and to place new constraints on their progenitor models. [ABSTRACT FROM AUTHOR]

The nebular spectra of Type Ia supernovae (⪆100 d after explosion) consist mainly of emission lines from singly and doubly ionized Fe-group nuclei. However, theoretical models for many scenarios predict that non-thermal ionization leads to multiply ionized species whose recombination photons ionize and deplete Fe+, resulting in negligible [Fe  ii ] emission. We investigate a method to determine the collisional excitation conditions from [Fe  ii ] line ratios independently from the ionization state and find that it cannot be applied to highly ionized models due to the influence of recombination cascades on Fe+ level populations. When the ionization state is artificially lowered, the line ratios (and excitation conditions) are too similar to distinguish between explosion scenarios. We investigate changes to the treatment of non-thermal energy deposition as a way to reconcile overionized theoretical models with observations and find that a simple work function approximation provides closer agreement with the data for sub- M ch models than a detailed Spencer–Fano treatment with widely used cross-section data. To quantify the magnitude of additional heating processes that would be required to sufficiently reduce ionization from fast leptons, we artificially boost the rate of energy loss to free electrons. We find that the equivalent of as much as an eight times increase to the plasma loss rate would be needed to reconcile the sub- M ch model with observed spectra. Future studies could distinguish between reductions in the non-thermal ionization rates and increased recombination rates, such as by clumping. [ABSTRACT FROM AUTHOR]

The first magnetic field in a star other than the Sun was detected in 1947 in the star 78 Vir. Today, we know that about 10% of these intermediate-mass and high-mass stars have strong, large-scale surface magnetic fields whose origin has remained a mystery till today. It has been suggested that merging of main-sequence and pre-main-sequence stars could produce such strong fields. The massive star τ Sco is a well-known member of the group of magnetic stars and is a blue straggler given its apparently young age compared to that of other members of the Upper Scorpius association. Here, we present 3D magnetohydrodynamic simulations of the coalescence of two massive main-sequence stars and 1D stellar evolution computations of the subsequent evolution of the merger product that can explain τ Sco's magnetic field, apparent youth and other observed characteristics. We argue that field amplification in stellar mergers is a general mechanism to form strongly-magnetised massive stars. Such stars are promising progenitors of magnetars, which may give rise to some of the enigmatic fast radio bursts, and their supernova explosions may be affected by the strong magnetic fields. [ABSTRACT FROM AUTHOR]

Single-degenerate (SD) binary systems composed of a white dwarf and a nondegenerate helium (He)-star companion have been proposed as the potential progenitors of Type Ia supernovae (SNe Ia). The He-star companions are expected to survive the SN Ia explosion in this SD progenitor model. In the present work, we map the surviving He-star companion models computed from our previous three-dimensional hydrodynamical simulations of ejectaâ€"companion interaction into the one-dimensional stellar evolution code Modules for Experiments in Stellar Astrophysics to follow their long-term evolution to make predictions of their post-impact observational properties, which can be helpful in searches for such surviving He-star companions in future observations. By comparing with the very-late-epoch light curve of the best observed SN Ia, SN 2011fe, we find that our surviving He-star companions become significantly more luminous than SN 2011fe about 1000 days after maximum light. This suggests that an He star is very unlikely to be a companion to the progenitor of SN 2011fe. [ABSTRACT FROM AUTHOR]

Kelvin–Helmholtz instability (KH) waves have been broadly shown to affect the growth of hydrometeors within a region of falling precipitation, but formation and growth from KH waves at cloud top needs further attention. Here, we present detailed observations of cloud-top KH waves that produced a snow plume that extended to the surface. Airborne transects of cloud radar aligned with range height indicator scans from ground-based precipitation radar track the progression and intensity of the KH wave kinetics and precipitation. In situ cloud probes and surface disdrometer measurements are used to quantify the impact of the snow plume on the composition of an underlying supercooled liquid water (SLW) cloud and the snowfall observed at the surface. KH wavelengths of 1.5 km consisted of ∼750-m-wide up- and downdrafts. A distinct fluctus region appeared as a wave-breaking cloud top where the fastest updraft was observed to exceed 5 m s−1. Relatively weaker updrafts of 0.5–1.5 m s−1 beneath the fluctus and partially overlapping the dendritic growth zone were associated with steep gradients in reflectivity of −5 to 20 dBZe in as little as 500-m depths due to rapid growth of pristine planar ice crystals. The falling snow removed ∼80% of the SLW content from the underlying cloud and led to a twofold increase in surface liquid equivalent snowfall rate from 0.6 to 1.3 mm h−1. This paper presents the first known study of cloud-top KH waves producing snowfall with observations of increased snowfall rates at the surface. [ABSTRACT FROM AUTHOR]

Knowing the phase evolution behavior of battery materials is important for optimizing the operating conditions and understanding the aging behavior of the material. Phase changes of state‐of‐the‐art battery materials at room temperature are well understood, but the influence of temperature on the phase evolution is barely investigated. In this study, operando X‐ray diffraction (XRD) is applied for the observation of phase changes of graphite during cycling at different temperatures. The phase evolution is altered at lower temperatures (0 °C) compared to room temperature due to slower kinetics and diffusion rates even at low current rates of C/20. Differences in phase evolution between charge and discharge are more pronounced at 0 °C compared to higher temperatures. During delithiation at 43 °C, the formation of stage 2L is more distinct than at 25 °C whereas at 0 °C, no stage 2L formation is observed. However, at 0 °C, several phases co‐exist, supporting the theory of the shrinking annuli mechanism for phase evolution during (de‐)lithiation of graphite. [ABSTRACT FROM AUTHOR]

The performance of rechargeable magnesium batteries is strongly dependent on the choice of electrolyte. The desolvation of multivalent cations usually goes along with high energy barriers, which can have a crucial impact on the plating reaction. This can lead to significantly higher overpotentials for magnesium deposition compared to magnesium dissolution. In this work we combine experimental measurements with DFT calculations and continuum modelling to analyze Mg deposition in various solvents. Jointly, these methods provide a better understanding of the electrode reactions and especially the magnesium deposition mechanism. Thereby, a kinetic model for electrochemical reactions at metal electrodes is developed, which explicitly couples desolvation to electron transfer and, furthermore, qualitatively takes into account effects of the electrochemical double layer. The influence of different solvents on the battery performance is studied for the state‐of‐the‐art magnesium tetrakis(hexafluoroisopropyloxy)borate electrolyte salt. It becomes apparent that not necessarily a whole solvent molecule must be stripped from the solvated magnesium cation before the first reduction step can take place. For Mg reduction it seems to be sufficient to have one coordination site available, so that the magnesium cation is able to get closer to the electrode surface. Thereby, the initial desolvation of the magnesium cation determines the deposition reaction for mono‐, tri‐ and tetraglyme, whereas the influence of the desolvation on the plating reaction is minor for diglyme and tetrahydrofuran. Overall, we can give a clear recommendation for diglyme to be applied as solvent in magnesium electrolytes. [ABSTRACT FROM AUTHOR]

Background: 5q spinal muscular atrophy (SMA) is a disabling and life-limiting neuromuscular disease. In recent years, novel therapies have shown to improve clinical outcomes. Yet, the absence of reliable biomarkers renders clinical assessment and prognosis of possibly already affected newborns with a positive newborn screening result for SMA imprecise and difficult. Therapeutic decisions and stratification of individualized therapies remain challenging, especially in symptomatic children. The aim of this proof-of-concept and feasibility study was to explore the value of 1H-nuclear magnetic resonance (NMR)-based metabolic profiling in identifying non-invasive diagnostic and prognostic urinary fingerprints in children and adolescents with SMA.Results: Urine samples were collected from 29 treatment-naïve SMA patients (5 pre-symptomatic, 9 SMA 1, 8 SMA 2, 7 SMA 3), 18 patients with Duchenne muscular dystrophy (DMD) and 444 healthy controls. Using machine-learning algorithms, we propose a set of prediction models built on urinary fingerprints that showed potential diagnostic value in discriminating SMA patients from controls and DMD, as well as predictive properties in separating between SMA types, allowing predictions about phenotypic severity. Interestingly, preliminary results of the prediction models suggest additional value in determining biochemical onset of disease in pre-symptomatic infants with SMA identified by genetic newborn screening and furthermore as potential therapeutic monitoring tool.Conclusions: This study provides preliminary evidence for the use of 1H-NMR-based urinary metabolic profiling as diagnostic and prognostic biomarker in spinal muscular atrophy. [ABSTRACT FROM AUTHOR]

Background Hemodialysis (HD) patients are commonly prescribed phosphate binders (PBs) to manage serum phosphorus levels, as hyperphosphatemia is strongly associated with poorer survival. Nonadherence with the PB prescription is associated with elevated serum phosphorus levels. We studied associations between patient satisfaction with their PB and serum phosphorus levels and mortality rates. Methods Adult HD patients in Germany, Italy, Spain and the UK in the Dialysis Outcomes and Practice Patterns Study were administered a survey instrument in late 2017. Patients were asked about their satisfaction with their PBs, as measured through three questions (difficulty, inconvenience and dissatisfaction) on a 5-point Likert scale, with each dichotomized into average worst versus good responses. These were used as predictors in linear regression models of continuous serum phosphorus levels and in Cox proportional hazards models of mortality, with adjustments for demographics, comorbidities and laboratory values. Results Patients having greater difficulty, inconvenience and dissatisfaction with their PB had higher serum phosphorus levels in adjusted models {+0.21 mg/dL [95% confidence interval (CI) ±0.23], +0.30 (±0.21) and 0.36 (±0.22), respectively}, and higher odds of having serum phosphorus levels ≥6.0 mg/dL. Measures of dissatisfaction were also associated with an elevated risk of mortality, with adjusted hazard ratios of 2.2 (95% CI 1.3–3.6), 1.6 (1.0–2.6) and 1.7 (1.1–2.7), respectively; this association was not strongly affected by adjustment for baseline serum phosphorous level. Conclusions Self-reported difficulty, inconvenience and dissatisfaction in taking one's prescribed PBs were associated with elevated serum phosphorus levels and serum phosphorus levels above clinically meaningful thresholds. While the mechanism for the association with mortality is unclear, patient-reported satisfaction should be considered when attempting to manage patient serum phosphorus levels. [ABSTRACT FROM AUTHOR]

Three different woods (lignum vitae; black fiber palm; spruce) were investigated regarding their friction and wear properties under abrasion and sliding. For the abrasive wear against silicon carbide paper, the palm wood gave the lowest removal of material, especially under an orientation of the black fibers normal to the contact region (on R–T-plane in R-direction). At the same time, this material had the highest anisotropy. Slightly less abrasion resistant was lignum vitae, whereas spruce was most easily abraded. This can be considered as an indication that spruce can easily be machined. Under sliding conditions against smooth steel, a similar tendency, but at much lower wear rates compared to abrasion, was found. The relatively high coefficient of friction under dry sliding allows the use of these woods as friction materials, for example in brakes. Additional lubrication of the two best woods, lignum vitae and black fiber palm, by soaked sunflower oil brought the coefficient of friction to a much lower level, so that the use of these woods as bearing materials in various applications is promising. [ABSTRACT FROM AUTHOR]

Ni‐doped chromite anodes were integrated into electrolyte‐supported cells (ESC) with 5×5 cm2 size and investigated in fuel cell mode with H2/H2O fuel gas. Both a stoichiometric and a nominally A‐site deficient chromite anode material showed promising performance at 860 °C approaching the ones of state‐of‐the‐art Ni/Gd‐doped ceria (CGO) anodes. While the difference in polarization resistance was small, an increased ohmic resistance of the perovskite anodes was observed, which is related to their limited electronic conductivity. Increasing the chromite electrode thickness was shown to enhance performance and stability considerably. Degradation increased with current density, suggesting its dependency on the electrode potential, and could be reversed by redox cycling. Sulfur poisoning with 20 ppm hydrogen sulfide led to rapid voltage drops for the chromite anodes. It is discussed that Ni nanoparticle exsolution facilitates hydrogen dissociation to the extent that it is not rate‐limiting at the investigated temperature unless an insufficiently thick electrode thickness is employed or sulfur impurities are present in the feed gas. [ABSTRACT FROM AUTHOR]

Tin foil and SnOx/C gas‐diffusions electrodes (GDEs) were investigated via electrochemical impedance spectroscopy (EIS) to extract the differential double‐layer capacitance (Cdl) as a measure of the wetted surface area. Time‐dependent Cdl values revealed an immediate stationary wetting for tin foil electrodes while a distinct increase of Cdl – which becomes stationary with time – was observed for GDEs. The time‐dependent wetting behavior of the GDEs was substantiated by physical post‐mortem characterization. Since the wetted surface area determines the number of reachable active sites the performance of GDEs should be normalized to the wetted surface area for evaluation of reactivity. [ABSTRACT FROM AUTHOR]

Background Beta-2 microglobulin (β2M) accumulates in hemodialysis (HD) patients, but its consequences are controversial, particularly in the current era of high-flux dialyzers. High-flux HD treatment improves β2M removal, yet β2M and other middle molecules may still contribute to adverse events. We investigated patient factors associated with serum β2M, evaluated trends in β2M levels and in hospitalizations due to dialysis-related amyloidosis (DRA), and estimated the effect of β2M on mortality. Methods We studied European and Japanese participants in the Dialysis Outcomes and Practice Patterns Study. Analysis of DRA-related hospitalizations spanned 1998–2018 (n  = 23 976), and analysis of β2M and mortality in centers routinely measuring β2M spanned 2011–18 (n  = 5332). We evaluated time trends with linear and Poisson regression and mortality with Cox regression. Results Median β2M changed nonsignificantly from 2.71 to 2.65 mg/dL during 2011–18 (P = 0.87). Highest β2M tertile patients (>2.9 mg/dL) had longer dialysis vintage, higher C-reactive protein and lower urine volume than lowest tertile patients (≤2.3 mg/dL). DRA-related hospitalization rates [95% confidence interval (CI)] decreased from 1998 to 2018 from 3.10 (2.55–3.76) to 0.23 (0.13–0.42) per 100 patient-years. Compared with the lowest β2M tertile, adjusted mortality hazard ratios (95% CI) were 1.16 (0.94–1.43) and 1.38 (1.13–1.69) for the middle and highest tertiles. Mortality risk increased monotonically with β2M modeled continuously, with no indication of a threshold. Conclusions DRA-related hospitalizations decreased over 10-fold from 1998 to 2018. Serum β2M remains positively associated with mortality, even in the current high-flux HD era. [ABSTRACT FROM AUTHOR]

Sub-Chandrasekhar mass carbon-oxygen white dwarfs with a surface helium shell have been proposed as progenitors of Type Ia supernovae (SNe Ia). If true, the resulting thermonuclear explosions should be able to account for at least some of the range of SNe Ia observables. To study this, we conducted a parameter study based on three-dimensional simulations of double detonations in carbon-oxygen white dwarfs with a helium shell, assuming different core and shell masses. An admixture of carbon to the shell and solar metallicity are included in the models. The hydrodynamic simulations were carried out using the AREPO code. This allowed us to follow the helium shell detonation with high numerical resolution, and this improves the reliability of predicted nucleosynthetic shell detonation yields. The addition of carbon to the shell leads to a lower production of 56Ni, while including solar metallicity increases the production of intermediate mass elements. The production of higher mass elements is further shifted to stable isotopes at solar metallicity. Moreover, we find different core detonation ignition mechanisms depending on the core and shell mass configuration. This has an influence on the ejecta structure. We present the bolometric light curves predicted from our explosion simulations using the Monte Carlo radiative transfer code ARTIS and make comparisons with bolometric SNe Ia data. The bolometric light curves of our models show a range of brightnesses, which is able to account for subluminous to normal brightness SNe Ia. We show the model bolometric width-luminosity relation compared to data for a range of model viewing angles. We find that, on average, our brighter models lie within the observed data. The ejecta asymmetries produce a wide distribution of observables, which might account for outliers in the data. However, the models overestimate the extent of this compared to data. We also find that the bolometric decline rate over 40 days, Δm40(bol), appears systematically faster than data. [ABSTRACT FROM AUTHOR]

Highly porous carbon materials employed in sulfur cathodes are of utmost importance to the charge transport, conductivity and stability of the cathode in metal–sulfur batteries. Herein, ultramicroporous carbon aerogels as conductive matrices embedding sulfur for cathode application in lithium–sulfur batteries are synthesized and investigated. Resulting from organic resorcinol–formaldehyde aerogels, the synthesized carbon aerogels feature a highly porous structure with a surface area of 500–2000 m2 g−1 and large micropore volume up to 0.6 cm3 g−1. The effective gas-phase sulfur infiltration of the carbon aerogels and the resulting confinement of sulfur in the micropores are demonstrated. It is indicated that sulfur-infiltrated microporous carbon aerogel cathodes are able to suppress the polysulfide shuttle effect, maintaining 80% (≥1000 mA h g(S)−1) and 70% (≥800 mA h g(S)−1) of the initial discharge capacity after 200 cycles at a rate of 0.3C in carbonate and ether-based electrolytes, respectively. Remarkably, the herein prepared composite cathode can still deliver a discharge capacity of at least 700 mA h g(S)−1 at a faster rate of 2C in both electrolyte systems. The cyclability and compatibility of the ether and carbonate-based electrolytes with such a composite cathode are discussed elaborately. [ABSTRACT FROM AUTHOR]

Water electrolysis is the key to a decarbonized energy system, as it enables the conversion and storage of renewably generated intermittent electricity in the form of hydrogen. However, reliability challenges arising from titanium‐based porous transport layers (PTLs) have hitherto restricted the deployment of next‐generation water‐splitting devices. Here, it is shown for the first time how PTLs can be adapted so that their interface remains well protected and resistant to corrosion across ≈4000 h under real electrolysis conditions. It is also demonstrated that the malfunctioning of unprotected PTLs is a result triggered by additional fatal degradation mechanisms over the anodic catalyst layer beyond the impacts expected from iridium oxide stability. Now, superior durability and efficiency in water electrolyzers can be achieved over extended periods of operation with less‐expensive PTLs with proper protection, which can be explained by the detailed reconstruction of the interface between the different elements, materials, layers, and components presented in this work. [ABSTRACT FROM AUTHOR]

An artifact appearing during the cathodic transient of cyclic voltammograms (CVs) of low-loaded platinum on carbon (Pt/C) electrodes in proton exchange membrane fuel cells (PEMFCs) was examined. The artifact appears as an oxidation peak overlapping the reduction peak associated to the reduction of platinum oxide (PtOx). By varying the nitrogen (N2) purge in the working electrode (WE), gas pressures in working and counter electrode, upper potential limits and scan rates of the CVs, the artifact magnitude and potential window could be manipulated. From the results, the artifact is assigned to crossover hydrogen (H2X) accumulating in the WE, once the electrode is passivated towards hydrogen oxidation reaction (HOR) due to PtOx coverage. During the cathodic CV transient, PtOx is reduced and HOR spontaneously occurs with the accumulated H2X, resulting in the overlap of the PtOx reduction with the oxidation peak. This feature is expected to occur predominantly in CV analysis of low-loaded electrodes made of catalyst material, whose oxide is inactive towards HOR. Further, it is only measurable while the N2 purge of the WE is switched off during the CV measurement. For higher loaded electrodes, the artifact is not observed as the electrocatalysts are not fully inactivated towards HOR due to incomplete oxide coverage, and/or the currents associated with the oxide reduction are much larger than the spontaneous HOR of accumulated H2X. However, owing to the forecasted reduction in noble metal loadings of catalyst in PEMFCs, this artifact is expected to be observed more often in the future. [ABSTRACT FROM AUTHOR]

Progress in the three-dimensional modeling of supernovae (SNe) prompts us to revisit the supernova remnant (SNR) phase. We continue our study of the imprint of a thermonuclear explosion on the SNR it produces, which we started with a delayed detonation model of a Chandrasekhar-mass white dwarf. Here we compare two different types of explosion models, each with two variants: two delayed detonation models (N100ddt, N5ddt) and two pure deflagration models (N100def, N5def), where the N number parameterizes the ignition. The output of each SN simulation is used as input to an SNR simulation carried on until 500 yr after the explosion. While all SNR models become more spherical over time and overall display the theoretical structure expected for a young SNR, clear differences are visible among the models, depending on the geometry of the ignition and on the presence or not of detonation fronts. Compared to N100 models, N5 models have a strong dipole component and produce asymmetric remnants. N5def produces a regular-looking, but offset remnant, while N5ddt produces a two-sided remnant. Pure deflagration models exhibit specific traits: a central overdensity, because of the incomplete explosion, and a network of seam lines across the surface, boundaries between burning cells. Signatures from the SN dominate the morphology of the SNR up to 100–300 yr after the explosion, depending on the model, and are still measurable at 500 yr, which may provide a way of testing explosion models. [ABSTRACT FROM AUTHOR]