1. High-performance K-ion half/full batteries with superb rate capability and cycle stability.
- Author
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Xianlu Lu, Xinfeng Zhang, Yapeng Zheng, Dongdong Zhang, Lan Jiang, Fengmei Gao, Qiao Liu, Dingfa Fu, Jie Teng, and Weiyou Yang
- Subjects
BATTERY storage plants ,ENERGY storage - Abstract
Currently, a big problem for exploring K-ion half/full batteries is how to bring them with both high specific capacity and long cycling stability simultaneously, in terms of their intrinsically sluggish kinetics of K+ with larger radius than that of Li
+ , which often causes huge volume change over the electrochemical reaction. Herein, we report the exploration of high-performance K-ion half/full batteries with superb rate capability and cycle stability based on B-doped porous carbons with increased active sites and improved conductivity. The as-assembled K-ion half cell exhibits an excellent rate capability of 428 mA h g-1 at 100 mA g-1 and a high reversible specific capacity of 330 mA h g-1 with 120% specific capacity retention after 2,000 cycles at 2,000 mA g-1 , which is state of the art among those based on carbon materials. Moreover, the as-constructed full cell delivers 98% specific capacity retention over 750 cycles at 500 mA g-1 , which is superior to most of the analogs based on carbon materials that have been reported thus far, underscoring their potential applications in advanced energy storage. [ABSTRACT FROM AUTHOR]- Published
- 2022
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