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Copyright of Journal of Central South University is the property of Springer Nature and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Copyright of Gazi Üniversitesi Fen Bilimleri Dergisi Part C: Tasarım ve Teknoloji is the property of Gazi University and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Commercially pure titanium (CP-Ti) plates were friction stir welded (FSWed) using a welding tool with a tungsten carbide (WC) pin. The bead-on-plate technique was applied to reduce the effects of welding defects, such as incomplete penetration. Whereas many papers have reported on creep studies of CP-Ti as well as on FSW of CP-Ti, no paper has investigated the creep behavior of a CP-Ti FSW'ed joint. Consequently, the current study focuses on this topic. The current paper, which is part of a broader research project, focuses on the metallurgical processes occurring during the creep of a FSW'ed CP-Ti joint at the temperature range of 550-650 °C. Based on the current study and previous results obtained by the authors, it can be concluded that the weld is not the weakest link. In every case, necking and creep fracture occurred in the parent material (PM), rather than either the thermomechanically affected zone (TMAZ) or the stir zone (SZ), indicating that both zones are more creep-resistant than the parent material. Fractography showed that the fracture surface was typical of creep fracture and that the fracture mechanism was microvoid coalescence and also ruled out any preexisting defect. TEM study of broken crept specimens revealed randomly distributed dislocations but no evidence of grain refinement, hence leading to the conclusion that dislocation glide was the dominant creep mechanism. The technological implication of the current study is that the welding process is safe for use as far as its creep properties are concerned. [ABSTRACT FROM AUTHOR]

Friction stir processing (FSP), a severe plastic deformation process, was applied on commercially pure Ti to obtain an improved microstructure. The process yielded a refined microstructure and higher mechanical properties at room temperature (RT). Yet the microstructure was found to contain bright bands demonstrating high hardness values of about 500 HV. High-resolution scanning electron microscopy (HRSEM) as well as electron backscattering diffraction (EBSD) analysis indicated that these bands were composed of extra-fine equiaxed α-Ti grains with an average radius of 1–2 microns. In addition, a retained β phase was detected at the boundaries of these α-Ti grains, together with a small quantity of separate β grains. The results of a fractography study conducted on broken tensile specimens showed that the material that underwent FSP was free of defects and that the fracture started at these bands. It is proposed that these bright bands are due to excessive deformation occurring during the processing stage, leading to an accelerated dynamic recrystallization (DRX) process. In turn, these heavy deformation regions act as a strengthening constituent, making the material superior to the parent material as far as its mechanical RT properties are concerned. Consequently, this means that the FSP of CP-Ti has the potential to serve as an industrial means of improving the mechanical properties of the material. [ABSTRACT FROM AUTHOR]

In this work, the results of an investigation of electron-beam-welded samples of commercially pure titanium (CP-Ti) and the titanium alloy Ti6Al4V (Ti64) using fillers of various beta-stabilizing elements (Nb, V, Cu) are presented. The fillers were in the form of deposited layers on each of the two specimens via DC magnetron sputtering. The specimens were then subjected to electron-beam welding (EBW) under the same technological conditions. The structure of the obtained welded joints was investigated by scanning electron microscopy (SEM). X-ray diffraction (XRD) was used to investigate the phase composition of the fusion zone (FZ). The study of the mechanical properties of the samples was carried out via tensile tests and microhardness measurements. The results showed a different influence of the used fillers on the structure and properties of the obtained joints, and in all cases, the yield strength increased compared to the samples welded using the same technological conditions without the use of filler material. In the case of using Nb and V as a filler, the typical transformation of titanium welds into elongated αTi particles along with α'-Ti martensitic structures was observed. The addition of a Cu filler into the structure of the welds resulted in a unification and refining of the structure of the last, which resulted in the improvement of the mechanical properties of the weld, particularly its ductility, which is a known issue where electron-beam welding is concerned. [ABSTRACT FROM AUTHOR]

The porous hydroxyapatite coatings with a spherical structure were formed on commercially pure titanium (CP-Ti) by the micro-arc oxidation (MAO) in an alkaline electrolyte (hydroxyapatite + 1 M potassium hydroxide) at the applied voltage of 140, 160, 180 V and deposition time of 1 and 2 min. It was determined that by increasing voltage from 140 to 160 V the Ca/P ratio increases from 1.54 to 1.69, i.e., the composition of hydroxyapatite (HA) approaches to the biological one that accelerates formation of the interfacial bond between the implant and bone tissue. It was shown that increasing deposition time from 1 to 2 min at the voltage of 140 V promotes increasing Ca/P ratio. The corrosion resistance of CP-Ti with HA coatings was studied in Ringer's solution at a temperature of 37 °C. The best corrosion protection was observed for the coating deposited at 160 V, 1 min, when the thickness of the coating and HA formation is the highest. [ABSTRACT FROM AUTHOR]

Friction surface stirring (FSS) was employed to enhance the tribological properties of commercially pure Ti (CP-Ti). Applying FSS under the optimised process parameters (i.e. rotation and traverse speeds of 100 rpmand 8mm/min, respectively) was found to increase the surface hardness of as-received CP-Ti from about 200--630 HV. The sliding wear resistance was therefore increased by 76, 76, and 85% under applied loads of 5, 10, and 20 N, respectively. The average friction coefficient (AFC) of CP-Ti also reduced considerably by the FSS. For instance, the AFC was reduced from 0.67±0.07 and 1.04±0.14 to about 0.33±0.03 and 0.45±0.04 at the applied loads of 5 and 20 N, respectively. The wear and friction mechanisms were also discussed. [ABSTRACT FROM AUTHOR]

The joining of Ti to stainless steel would allow cost-effective and light weight designs for many applications. For friction stir spot welding of Ti to steel with lap configuration, dwell time is an important process parameter. The higher dwell time promotes higher heat generation, which helps material movement and mixing for joint creation. However, higher dwell time also leads to higher peak temperature and incubation time, which encourage undesirable IMC formation. This research focuses on the impact of dwell duration on the elemental diffusion and IMC growth during FSSW of CP-Ti and SS 304. This research numerically and experimentally analyzes the diffusion of elements, intermetallic compound formation, and shear strength of stainless steel 304 and titanium dissimilar friction stir spot welds. The temperature profiles from numerical thermal model show that the peak temperatures at the dissimilar joint interface increases as dwell time increases. The diffusion model and characterization results reveal that Ni, Fe, and Cr diffuse across the dissimilar joint interface from steel to titanium side. Since Ni, Fe, and Cr are β-Ti stabilizers, the β-Ti stabilizes next to the dissimilar interface. The α-β Ti needles are observed between the stabilized β-Ti and α-Ti region towards base material. The numerical predictions of β-Ti and Fe-Ti IMC compare well against the experimental results. From shear strength (tensile) tests, the maximum shear strength (tensile) of ~ 8 kN is achieved from the SS 304-CP-Ti joint performed with 10 s dwell time. At the joint interface, the presence of β-Ti strengthens the joint and the presence of Fe-Ti IMCs encourages abrupt brittle failure and reduces strength. With dwell times less than 10 s, the Fe-Ti IMC thickness is less than 1 μm, which leads to higher shear strength (tensile) with higher β-Ti thickness as dwell time increases. With 20 s dwell time, the Fe-Ti IMC thickness of about 1 μm leads to reduced shear strength (tensile). The EDS analysis of the fracture surfaces reveal that dissimilar SS 304-CP-Ti joints failed from the dissimilar interface containing Fe-Ti IMC. [ABSTRACT FROM AUTHOR]

Titanium alloys are characterised by poor tribological properties, and a ceramic TiO2 layer formed on the surface can greatly improve its performance. By pre-depositing a gold layer on the titanium surface, the gold particles promoted the outward diffusion of titanium in the ceramic conversion treatment to react with the inward-coming oxygen to form a compact titanium dioxide layer. The surface morphology, microstructure, and phase constituents were characterised by SEM/EDX and XRD. The adhesion of the oxide layers was assessed by a scratch test. The distribution of gold particles in the oxide layer enhanced the surface hardness and reduced the friction and wear against a WC (tungsten carbide) ball in the reciprocal tribological test. The ceramic conversion process was accelerated efficiently at 620–660 °C, and the more gold pre-deposited, the thicker the oxide layer. [ABSTRACT FROM AUTHOR]

Commercially pure titanium (CP-Ti) plates were friction-stir welded (FSWed) using a welding tool with a tungsten carbide (WC) pin. The bead-on-plate technique was applied to reduce the effects of welding defects, such as incomplete penetration. An X-ray inspection and fractography showed that the FSWed material was free of defects and of WC particles, which may have originated from the welding tool. The appearance of refined equiaxed grains in the thermo-mechanically affected zone (TMAZ) may have been related to dynamic recrystallization (DRX) occurring during the FSW due to the high temperature and intensive plastic deformation involved in the process. Grain refinement, mechanical twinning, and increased dislocation density were detected within the TMAZ, and these microstructural changes were considered to be responsible for the improved mechanical properties of the TMAZ. The TEM study reported in the current paper revealed the presence of nano-sized grains in the FSWed material due to dynamic recrystallization (DRX) occurring during the processing stage. The microstructure obtained during FSW of Ti has been reported in a several publications, yet many discrepancies can be found in these publications. Among these discrepancies are the size and the shape of the grains at the various zones, as well as the presence or non-presence of various zones at the vicinity of the weld. The current study contradicts the argument for correlations between the conditions prevailing at different points across the TMAZ and microstructural changes, which were previously proposed by several researchers. [ABSTRACT FROM AUTHOR]

The possibility of increasing the hardness to 1420 HV and the corrosion resistance of the CP-Ti surface using a combined plasma electrolytic treatment consisting in anodic plasma electrolytic nitrocarburising in a solution of ammonia, acetone and ammonium chloride at 900 °C and subsequent plasma electrolytic polishing is shown. The morphology, surface roughness, phase composition, structure and microhardness of the modified layer were studied. The corrosion characteristics of the treated surface were studied through potentiodynamic tests and electrochemical impedance spectroscopy. It has been shown that an increase in the surface roughness has a negative effect on the corrosion resistance. The proposed plasma electrolytic polishing makes it possible to remove the outer porous oxide layer, providing increased corrosion resistance. The highest reduction in the corrosion current density, by 13 times compared to CP-Ti and by two orders compared to a plasma electrolytic nitrocarburising sample, is achieved after plasma electrolytic polishing in a solution of ammonium fluoride (4%) at 300 V for 3 min. [ABSTRACT FROM AUTHOR]

A coupled heat source model that combined a Gauss surface heat source with a Gauss cylindrical volumetric heat source was introduced to simulate temperature field distribution and melt pool characteristics using a finite element simulation (FEM) method for the deep and narrow melt pools formed in laser powder bed fusion (L-PBF) aiming at commercial pure titanium (CP-Ti). For comparison, the same simulations using the Gauss surface heat source model and the double ellipsoid heat source model were also performed. The simulated melt pool geometries using the coupled heat source model match well with the measurements, with an average error of 1% for the melt pool depth and 7% for the width. Based on the single-track experimental results, it was found by comparing the simulated results from the three heat source models that the coupled heat source model had better accuracy than the other two. Then, the temperature field and the melt pool geometries of CP-Ti fabricated at different laser power levels from 300 W to 500 W and scanning speeds from 600 mm/s to 4000 mm/s were simulated. According to the simulated maximum temperature and geometries of the melt pool, a suitable process parameters map for CP-Ti was obtained. The reported experimental results agree well with the simulated map. The coupled heat source model is more accurate and applicable for the deep and narrow melt pools formed during L-PBF. [ABSTRACT FROM AUTHOR]

Titanium has been one of the traditional metals used in the medical industry since 1940. This work modeled and simulated a hip-joint replacement implant using Creo 5.0 and DEFORM 3D (v11.0), respectively. Four titanium-based billets were modeled; out of four billets, three billets were coated with a specified thickness, and one was uncoated. Among the three coated billets, one billet was coated with a 500-micron and two billets coated with a 1000-micron thickness. At the end of the simulation, the coating materials formed patches on the surface of the forged parts. The coating material Ti-6Al-4V (high O2) produced excellent mechanical properties in contrast to the CP-Ti material, which displayed low mechanical properties and did not match the core property. Hence, it was suggested to provide a bulk coating of Ti-6Al-4V (high O2) on the billet to improve the physio-mechanical properties and biocompatibility. Four points were selected on the surface of the forged parts at different locations for identifying the property variations concerning forging time. Results found that coating thickness required more on the side surface of the billet material than on the upper and lower surfaces to enhance its properties. [ABSTRACT FROM AUTHOR]

The TA1 welded joints with different heat inputs were obtained by a fiber laser and their microstructure, mechanical properties and corrosion resistance in simulated saliva solution were studied. The results show that the microstructure in fusion zone (FZ) is needle-like α′ martensite and lath-shape α′ martensite, and that of the heat-affected zone (HAZ) is zigzag α phase. With the increase of heat input, the volume fraction of needle-like α′ martensite decrease and the microstructure is coarsened in FZ, but there is almost no change in the microstructure of the HAZ. The order of the corrosion resistance of welded joints with different heat inputs is the same as FZ > HAZ > base material (BM), and the heat input has a more influence on the corrosion resistance of FZ. The binary multiple linear regression relationship between the corrosion current density/charge transfer resistance and the length/width of α′ martensite was established, indicating that the width of α′ martensite is the main factor affecting the corrosion resistance. [ABSTRACT FROM AUTHOR]

The present work is aimed at developing corrosion-resistant biocompatible coatings on Cp-Ti by anodisation. The coatings were developed by anodising Cp-Ti at a voltage of 60 V over a period of 60 minutes. The coatings were developed by using two different electrolytes, namely ethylene glycol solution of NH4F and an aqueous solution of H3PO4. The developed coatings were annealed at 400 °C. The wettability, surface morphology and phase composition of the samples were evaluated by contact angle goniometry, field emission-scanning electron microscopy (FE-SEM) and X-ray diffractometry (XRD), respectively. The corrosion characteristics of th samples were analysed by potentiodynamic polarisation (PDP) and electrochemical impedance spectroscopy (EIS) in Kokubo's simulated body fluid (SBF) environment to resemble the human blood plasma. Anodisation of the Cp-Ti resulted in the formation of nanoporous structure, which on annealing, resulted in the dwindling of the nanopores. The anodised (A and B) and annealed samples (AH and BH) exhibited better hydrophilic surfaces with enhanced corrosion resistance as indicated by the decrease in current densities of A, AH, B and BH samples by 70.6%, 84.2%, 87.4% and 94.2%, respectively, compared to the substrate, which qualifies them to be corrosion resistant and biocompatible. [ABSTRACT FROM AUTHOR]

During vacuum annealing of C-103 (Nb-10Hf-1Ti) sheets, local melting was noticed at the locations they were in contact with commercially pure titanium (CP-Ti) base sheet. On metallurgical analysis, it was noted that initially CP-Ti sheet reacted with the Inconel 600 tray, forming a series of low melting eutectics, below the annealing temperature of 1175 °C. The weight of C-103 charge experienced at the contact region between the bottom-most C-103 sheet with Inconel 600 gridded tray, where the eutectic reaction between CP-Ti and Inconel 600 occurred initially along with long annealing time, enabled interdiffusion of Ni, Cr, Ti, Nb and Hf, forming a eutectic mixture. Based on detailed metallurgical analysis, the reactions were established and the cause of melting was attributed to improper selection of base tray/sheet combination. Finally, it was recommended to use a Mo tray between Inconel 600 tray and CP-Ti sheet to overcome the problem. [ABSTRACT FROM AUTHOR]

Commercial purity titanium (CP-Ti) and a Ti-6Al-4V alloy (Ti64) were processed by high-pressure torsion (HPT) for 10 and 20 turns. The HPT processing produced a nanostructured microstructure and a significant strength enhancement in the CP-Ti and Ti64 samples. After 20 turns, the samples of HPT-processed CP-Ti and Ti64 were subjected to laser surface treatments in an air atmosphere using different scanning speeds and laser powers. The surface roughness of the laser-modified samples increased with increasing laser power and this produced hydrophilicity due to a lower contact angle. After a holding time of 27 days, these samples underwent a hydrophilic-to-hydrophobic transformation as the contact angle increased from 13° to as much as 120° for the CP-Ti sample, and for the Ti64 sample the contact angle increased from 10° to 126°. In addition, the laser surface modification process was carried out with different atmospheres (air, vacuum and O2) on heat-treated but unstrained CP-Ti and Ti64 samples and the contact angle changed due to the surface element content. Thus, as the carbon content increased from 28% to 47% in CP-Ti in a vacuum environment, the surface contact angle increased from 22° to 140°. When a laser surface modification process is conducted under oxygen-less conditions, it is concluded that the contact angle increases rapidly in order to control the hydrophobic properties of Ti and the Ti alloy. [ABSTRACT FROM AUTHOR]

Anodic oxidation of CP-Ti, for production of TiO2 nanotubes, has been extensively described in terms of the electrochemical mechanism of tubular growth or the effect of the parameters on the final tube morphology. Recently, a kinetic growth model was proposed to describe the distinct morphologies of the anodic oxide layer as phases of the nanotubular development process, offering a new perspective for the tuning of nanotube production. In this work, the anodizing behavior of a CP-Ti alloy in an ethylene glycol electrolyte was investigated in light of this new model. The final morphology of the nanotubes was characterized by SEM, considering the effects of electrolyte aging, the microstructure, the applied potential difference and time on the morphological development of nanotubes. Electrolyte aging was shown to lead to a decreased dissolution effect on the oxide. The applied potential difference was shown to lead to an increased dissolution effect and more rapid nanotube growth kinetics, while time resulted in extended dissolution. Moreover, the obtained results were analyzed considering a previous study focused on the anodizing behavior of the α- and β-phases of Ti6Al4V alloy. Overall, the tube morphology resembled that obtained for the Al-containing α-phase of the Ti6Al4V alloy, but the growth kinetics were considerably slower on CP-Ti. [ABSTRACT FROM AUTHOR]

In‐plane biaxial fatigue tests of commercial pure titanium (CP‐Ti) were performed to investigate the effects of load ratio and phase shift on fatigue and ratcheting behavior. The results show that with the decrease of load ratio or the increase of phase shift, biaxial ratcheting strain effect is more significant, leading to the deterioration of fatigue resistance. Analysis of the crack morphology and fracture characteristic reveals that the crack propagation path becomes complex and the fracture morphology changes due to the enhanced non‐proportional hardening effect. Finally, current multiaxial life prediction models are evaluated to compare the applicability in the biaxial fatigue life prediction. Highlights: Effects of load ratio and phase shift on biaxial ratcheting behavior are discussed.Biaxial fatigue life is more sensitive to the variation of the phase shift.The crack morphology and fracture characteristics are analyzed.The applicability of different multiaxial life prediction models is evaluated. [ABSTRACT FROM AUTHOR]

In the present work, pack carburization with rubberwood charcoal and rubberwood ash at 925 °C for 6, 12, and 24 h was carried out to improve the surface hardness of commercially pure titanium (CP-Ti). X-ray diffraction and energy dispersive spectrometer analyses revealed the formation of titanium carbide (TiC) and the existence of oxygen diffusion in the carburized surface. The surface hardness of most optimized conditions has remarkably increased by 481 % as compared to untreated CP-Ti (from 175 HV to 1016 HV) due to the TiC surface layer, while the hardened oxygen diffusion layer a bout 300 um in depth, as clearly seen in the microhardness profiles is useful for increased load-bearing capacity. Consequently, pack carburization with rubberwood charcoal and rubberwood ash is a promising surface modification technique, which can significantly enhance the surface hardness and increase the loadbearing capacity of CP-Ti for biomedical and tribological applications. [ABSTRACT FROM AUTHOR]

Commercially pure Ti (CP‐Ti) was heat treated at 1273 K (1000°C), which was higher than β‐transus temperature, followed by water quenching. The dwell time at 1000°C was changed from 1 to 240 h. The heat treatment at 1000°C resulted in α grain coarsening, whereas martensitic transformation occurred due to the rapid cooling from β phase. The hardness increased by the martensitic transformation, where higher hardness was achieved by longer dwell time at 1000°C. However, the fatigue strengths of the heat‐treated CP‐Ti were lower than that of the as‐received one. The fatigue strength of the specimen with the shortest dwell time of 1 h was the lowest among the heat‐treated samples with different dwell times. Untransformed coarse α grains were seen in the heat‐treated specimens, which resulted in the lower fatigue crack initiation resistance and fatigue strength than the as‐received specimen. [ABSTRACT FROM AUTHOR]

Purpose: This paper aims to investigate the structural, tribological and electrochemical properties of Ag2O, ZnO, NiO coatings and Ag2O/ZnO/NiO nanocomposite films deposited on commercially pure titanium. Design/methodology/approach: Ceramic thin films (Ag2O, ZnO, NiO coatings and Ag2O/ZnO/NiO nanocomposite film) were deposited on commercially pure titanium (CP-Ti) substrate. Surface characterization of the uncoated and coated samples was made by structural surveys (scanning electron microscopic examinations and X-ray diffraction analyses), hardness measurements, tribological and corrosion experiments. Findings: Results were indicated that sol-gel coatings improved the wear and corrosion resistance of CP-Ti, and the best results were seen at the nanocomposite coating. It may be attributed to its small grain size, high surface hardness and high film thickness. Originality/value: This study can be a practical reference and offers insight into the influence of nanocomposite ceramic films on the increase of hardness, tribological and corrosion performance. Also, the paper displayed a promising approach to produce Ag2O/ZnO/NiO nanocomposite coating on commercially pure titanium implants for biomedical applications. [ABSTRACT FROM AUTHOR]

This paper presents the study of microstructure and properties of 8 mol% yttrium stabilized zirconia coating fabricated by Plasma Spray Physical Vapor Deposition technique on commercial pure titanium. The coating was characterized by X-ray diffraction, high resolution scanning electron microscope, profilometer, nanoindentation and nanomachining tests. The X-ray phase analysis exhibit the tetragonal Zr0.935Y0.065O1.968, TiO and a-Ti phases. The Rietveld refinement technique were indicated the changes of crystal structure of the produced coatings. The characteristic structure of columns were observed in High Resolutions Scanning Electron Microscopy. Moreover, the obtained coating had various development of surfaces, thickness was equal to 3.1(1) µm and roughness 0.40(7) µm. Furthermore, the production coatings did not show microcracks, delamination and crumbing. The performed experiment encourages carried out us to tests for osseointegration. [ABSTRACT FROM AUTHOR]

In the present paper, the influences of different double layer on wear and scratch performances of commercially pure Titanium (CP-Ti) were investigated. TiO2/SiO2 and SiO2/TiO2 double layer coatings were deposited on CP-Ti by sol-gel dip coating process and calcined at 750C. The phase structure, cross-sectional morphology, composition, wear track morphologies, adhesion properties, hardness and roughness of uncoated and coated samples were characterized with X-ray diffraction, scanning electron microscopy (SEM), nano-indentation technique, scratch tester and 3D profilometer. Also, the tribological performances of all samples were investigated by a pin-on-disc tribo-tester against Al2O3 ball. Results showed that hardness, elastic modulus and adhesion resistance of double layer coated samples were higher than untreated CP-Ti. It was found that these properties of TiO2/SiO2 double layer coatings have higher than SiO2/TiO2 double layer coating. Additionally, the lowest friction coefficient and wear rates were obtained from TiO2/SiO2 double layer coatings. Therefore, it was seen that phase structure, hardness and film adhesion are important factors on the tribological properties of double layer coatings. [ABSTRACT FROM AUTHOR]

Enhanced cell adherence to the surface of nanocrystallized commercially pure titanium (CP-Ti) was observed by several authors. However, the understanding of the surface modification of Ti in a physiological solution due to nanocrystallized grain size has not been reached. In this work, equal channel angular pressing (ECAP) was applied to manufacturing ultrafine grained CP-Ti. Martensite and Widmanstatten microstructures were also obtained for comparison. The CP-Ti pieces with different microstructures were subjected to soaking tests in a simulated body fluid. Electrochemical impedance spectroscopy (EIS) measurements, X-ray photoelectron spectroscopy (XPS) and scanning electron microscope (SEM), energy dispersive spectrometer (EDS) were used to characterize the surfaces. The results show the surface precipitates mainly contain Ti, O, Ca and P. The quantity of precipitates on ECAPed CP-Ti is the largest among different specimens corresponded to the observation of the thickest layer formation on ECAPed CP-Ti found by EIS. EDS results show more CaPO and less Ti are included on ECAPed Ti comparing to the deposits on other two types of specimens. Smaller numbers of precipitates and denser film are produced on the surface of the water-quenched CP-Ti. The regeneration kinetics of the CaP precipitates evaluated by Gibbs free energy is introduced to interpret the precipitating behaviors on different CP-Ti specimens. [ABSTRACT FROM AUTHOR]

Strength and ductility of fusion zone of metastable β titanium alloy welds can be improved by choosing suitable fillers. This paper reports the effects of using CP-Ti filler on the microstructural and mechanical properties of Ti-15-3 weldments. Full penetration autogenous and CP-Ti filler welds were produced by pulsed gas tungsten arc welding. X-ray diffraction analysis revealed small amounts of α-Ti phase in the diffraction pattern obtained for welds prepared using CP-Ti filler. Transmission electron microscopy analysis showed presence of grain boundary and intragranular α in the fusion zone of the welds prepared using CP-Ti filler. The welds prepared with CP-Ti filler showed higher hardness, higher UTS and lower % strain compared to autogenous welds. [ABSTRACT FROM AUTHOR]

The aim of the present work is to investigate the effects of prestrain and subsequent annealing on tensile properties of commercial pure titanium (CP-Ti). According to tensile test results, yield strength and ultimate tensile strength increase with the increase of prestrain. Elongation and uniform strain decrease linearly with prestrain. In the case of prestrain that is higher than 3.5%, the macro-yield of specimens changes from gradual yielding to discontinuous yielding. It is supposed that considerable numbers of dislocations introduced into the material lead to the appearance of yield plateau. The quantitative analysis of the contribution of dislocation hardening to the strain hardening shows that dislocation-associated mechanisms play an important role in strain hardening. Moreover, a modified Fields-Backofen model is proposed to predict the flow stress of prestrained CP-Ti at different strain rates. Both strain rate sensitivity and strain hardening exponent decrease with prestrain. Fracture surfaces of the specimens show that fracture mechanism of all tested specimens is dimple fracture. The more ductile deformation in prestrained CP-Ti after annealing indicates that its ductility is improved by annealing. [ABSTRACT FROM AUTHOR]

Titanium (Ti) and its alloys may be processed via advanced powder manufacturing routes such as additive layer manufacturing (or 3D printing) or metal injection moulding. This field is receiving increased attention from various manufacturing sectors including the medical devices sector. It is possible that advanced manufacturing techniques could replace the machining or casting of metal alloys in the manufacture of devices because of associated advantages that include design flexibility, reduced processing costs, reduced waste, and the opportunity to more easily manufacture complex or custom-shaped implants. The emerging advanced manufacturing approaches of metal injection moulding and additive layer manufacturing are receiving particular attention from the implant fabrication industry because they could overcome some of the difficulties associated with traditional implant fabrication techniques such as titanium casting. Using advanced manufacturing, it is also possible to produce more complex porous structures with improved mechanical performance, potentially matching the modulus of elasticity of local bone. While the economic and engineering potential of advanced manufacturing for the manufacture of musculo-skeletal implants is therefore clear, the impact on the biocompatibility of the materials has been less investigated. In this review, the capabilities of advanced powder manufacturing routes in producing components that are suitable for biomedical implant applications are assessed with emphasis placed on surface finishes and porous structures. Given that biocompatibility and host bone response are critical determinants of clinical performance, published studies of in vitro and in vivo research have been considered carefully. The review concludes with a future outlook on advanced Ti production for biomedical implants using powder metallurgy. [ABSTRACT FROM AUTHOR]