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Today, the most effective and suitable method to obtain molecular H2 is the extraction from mixtures where it is present, using gas‐sieving membranes. To this aim, the preparation and characterization of layered nano‐composites are described, made of alternated layers of positively charged Poly(Diallyl Dimethyl Ammonium chloride) (PDDA) and negatively charged graphene oxide (GO) nanosheets with high and tunable selectivity for H2 purification. The composites are assembled exploiting electrostatic interactions and the layer‐by‐layer technique; this study correlates permeance tests with changes in chemical composition and structure of the material using X‐rays Photoelectron Spectroscopy, X‐rays diffraction water contact angle, and surface zeta‐potential measurements. Thanks to its layered nature, the GO‐PDDA composite shows an excellent selectivity, allowing faster permeation of H2 as compared to CO2 and Argon. By transforming the GO to reduced GO, the porosity of the nanosheets can be further increased, in this way increasing the permeance of the material and its selectivity at the same time, thus allowing to overcome the Robeson limit, the technological upper boundary to the performance of actual membranes. [ABSTRACT FROM AUTHOR]

This methodological, policy-focused paper firstly defines the concept of "sustainable territorial innovation" and its operationalisation according to the strategic objectives of Europe 2020. Statistical processing was based on 26 indicators, which helped to perform a multivariate analysis and allowed to identify ten groups of municipalities characterised in terms of the territorial sustainable innovation idea. Their GIS spatial distribution has led authors to combine them with the set of indicators proposed by the Italian Government in the UE Cohesion Policy 2014-2020 perspective. The paper also addresses the constraints and opportunities for urban and peri-urban policies within new scenarios. [ABSTRACT FROM AUTHOR]