1. A case study for the uranyl recovery over magnetically retrievable Cu-BTC@Fe3O4 nanocomposites.
- Author
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Sun, Zhong-Hua, Sheng, Pan-Pan, Li, Zi-Jie, Wang, Le-Yao, Bao, Wen-Li, Yuan, Li-Yong, Shi, Wei-Qun, and Zhang, Zhi-Hui
- Subjects
EXTENDED X-ray absorption fine structure ,NANOCOMPOSITE materials ,URANIUM ,METAL-organic frameworks - Abstract
A magnetic Metal–Organic Framework (MOF) nanocomposite, namely Cu-BTC@Fe
3 O4 (BTC = 1,3,5-benzenetricarboxylate) was used for magnetically retrievable separation of uranyl (UO2 2+ ) in the presence of competitive ions. A significant adsorption amount of 312 mg/g was achieved for uranium over Cu-BTC@Fe3 O4 at a pH value of 4.5. Extended X-ray Absorption Fine Structure (EXAFS) analysis indicated that the interaction of Cu-BTC@Fe3 O4 with UO2 2+ is the synergistic coordination of carboxylate groups of BTC ligand, Fe3 O4 -COOH, and hydrate H2 O for UO2 2+ ions. In addition to identifying a stable and retrievable adsorbent, the results generally elucidate UO2 2+ removal of MOFs composites. [ABSTRACT FROM AUTHOR]- Published
- 2023
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