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Pillow-plate heat exchangers (PPHEs) represent a suitable alternative to conventional shell-and-tube and plate heat exchangers. The inherent waviness of their channels promotes fluid mixing in the boundary layers and facilitates heat transfer. The overall thermo-hydraulic performance of PPHEs can further be enhanced by applying secondary surface structuring, thus increasing their competitiveness against conventional heat exchangers. In this work, various secondary structures applied on the PPHE surface were studied numerically to explore their potential to enhance near-wall mixing. Computational fluid dynamics (CFD) simulations of single-phase turbulent flow in the outer PPHE channel were performed and pressure drop, heat transfer coefficients, and overall thermo-hydraulic efficiency were determined. The simulation results clearly demonstrate a positive impact of secondary structuring on heat transfer in PPHEs. [ABSTRACT FROM AUTHOR]