1. Exploring Bismuth Oxide Supported Kaolinite for Photocatalytic Application.
- Author
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Thammaacheep, Punyanuch, Phetthai, Pornpraphatson, Suchai, Suthitra, Jannoey, Panatda, and Channei, Duangdao
- Subjects
BISMUTH trioxide ,WASTE products ,BAND gaps ,PHOTOCATALYSTS ,METALLIC oxides ,KAOLIN - Abstract
Bismuth oxide (Bi
2 O3 ) and Bi2 O3 –supported Kaolin were synthesized using household microwave–assisted methods (350 W, 5 min), with catalyst characteristics analyzed. XRD patterns confirmed the monoclinic structure of Bi2 O3 . Incorporating 20%w/w Kaolin increased the specific surface area of Bi2 O3 from 6.2879 to 16.1345 m2 /g, observed in FESEM images showing a hierarchical flower-like morphology resembling French fries alongside Kaolin plates. XRF analysis identified elements in Kaolin contributing to self–doping in band structure of Bi2 O3 , reducing its band gap and PL intensity. Kaolin/Bi2 O3 composites demonstrated enhanced photocatalytic degradation of tetracycline (TC) under visible light, attributed to Bi2 O3 -generated radicals and increased surface area. The composite photocatalyst can be recycled up to three times. This research not only enhances the photocatalytic activity of Bi2 O3 but also increases the value of a local waste material, Kaolin clay. Such enhancements could potentially extend to other metal oxides and abundant waste materials within the country. [ABSTRACT FROM AUTHOR]- Published
- 2024
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