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Paper has the multiple advantages of being breathable, sustainable, environmentally friendly, and non-toxic for medical care. However, the flammability stemming from the raw materials of paper has limited its use in medical heat therapy. In this paper, a composite flame-retardant coating is assembled layer by layer on a medical paper surface using medically safe natural biomaterials with starch and adenosine triphosphate as internal layers, and starch and phytic acid as external layers. With the layer-by-layer assembly using the ultrathin adsorption method, the microscopic morphology and elemental mapping reveal that all the biomaterials are deposited uniformly and have completely capsulated the paper surface fiber. The flame-retardant coating shows less impact on medical paper appearance morphology and mechanical properties in medical usability. The coated medical paper exhibits significant flame-retardant performance, such that the limiting oxygen index increases from 19.70% to 25.40% where both internal and external layers reached 100 layers (BL), and relevant residual charring in the thermogravimetric test increases 17.00 wt% in a nitrogen atmosphere and 18.00 wt% in an air atmosphere at 800 °C. The peak and total heat release rates of 100 BL medical paper reduced by approximately 91.10% and 53.10%, respectively, and the variations in both CO and CO2 production also suggest that flame-retardant coating could effectively inhibit combustion. Benefiting from the intumescent flame-retardant function of different biomaterial combinations and the multilayer design on different thermal response temperatures, the flame retardancy of medical paper significantly improved, and this advancement will make medical heat therapy safer and healthier for patients. [ABSTRACT FROM AUTHOR]

We have executed a cost-effective approach to produce a high-performance multifunctional human–machine interface (HMI) humidity sensor. The designed sensors were ecofriendly, flexible, and highly sensitive to variability in relative humidity (%RH) in the surroundings. In this study, we have introduced a humidity sensor by using carbon paper (as both a substrate and sensing material) and a silver (Ag) conductive ink pen. The carbon paper-based humidity sensor was developed by using a simple handwriting approach and the resulting devices exhibited excellent results including fast response/recovery times (12/24 s), a wide sensing range (30 to 85%), small hysteresis (1.1%), high stability (1 month), and repeatability. This high-performance humidity response could be attributed to the highly porous, hydrophilic, and permeable nature of carbon paper. Besides these features, the sensor offered high flexibility (100 bending cycles across different radii) and adaptability for uses like breath monitoring (through mouth and nose), proximity sensing (from multiple distances ranging from 1 to 10 cm), and depicting Morse code. This research work is a significant step forward in humidity sensing technology and the sustainable future of electronic devices by using a cost-effective, fast, and simple fabrication technique. [ABSTRACT FROM AUTHOR]

Paper is a thin nonwoven material made from cellulose fibers as the main raw material together with some additives. Paper is highly flammable, leading to the destruction of countless precious ancient books, documents, and art works in fire disasters. In recent years, researchers have made a lot of efforts in order to obtain more durable and fire-retardant paper. Owing to the successful synthesis of ultralong hydroxyapatite (HAP) nanowires as a new kind of inorganic nanofiber material, it becomes possible to develop a new kind of super-durable and fire-resistant paper. Recently, the authors' research group prepared a new kind of fire-resistant "Xuan paper" consisting of ultralong HAP nanowires. In this article, the super-durable fire-resistant "Xuan paper" based on ultralong HAP nanowires and the traditional Xuan paper based on cellulose fibers were evaluated by the accelerated aging method for 1200 days at 105 °C in air, which is the equivalent of 10,000 years of natural aging in the ambient environment. The aging mechanism of the traditional Xuan paper was further investigated by studying the fiber length/width and their distributions, morphology, infrared spectroscopy, thermogravimetric analysis, H–nuclear magnetic resonance spectra, and C–nuclear magnetic resonance spectra of cellulose fibers before and after the accelerated aging. The durability, properties, and mechanism of the fire-resistant "Xuan paper" based on ultralong HAP nanowires during the accelerated aging were studied. The experiments reveal the reasons for the deteriorated properties and reduced durability by aging of the traditional Xuan paper based on cellulose fibers, and the mechanism for the super-durability and excellent performances of the fire-resistant "Xuan paper" based on ultralong HAP nanowires during the accelerated aging process. [ABSTRACT FROM AUTHOR]

The document "Chemical Conservation of Paper-Based Cultural Heritage" discusses the importance of preserving paper-based artifacts, such as ancient books and manuscripts, to protect human civilization's development. Various studies highlighted in the document focus on the properties, degradation mechanisms, and conservation methods of paper artifacts, including the effects of hemicellulose on paper strength, the influence of environmental conditions on palm leaf manuscripts, and the use of innovative materials like soymilk and nanocellulose for paper sizing and reinforcement. The research aims to provide insights into more efficient and sustainable conservation practices for cultural heritage preservation. [Extracted from the article]

Paper-based cultural relics experience aging and deterioration during their long-term preservation, which poses a serious threat to their lifetime. The development of conservation materials with high compatibility and low intervention has been expected to extend the lifetime of paper artifacts. As a new type of biological macromolecule, nanocellulose has been extensively utilized in paper conservation, attributed to its excellent paper compatibility, high optical transparency, outstanding mechanical strength, and large specific surface area with abundant hydroxyl groups. This review systematically summarizes the latest development of three kinds of nanocellulose (cellulose nanofibril, cellulose nanocrystal, and bacterial nanocellulose) and their composites used for the multifunctional conservation of paper relics. Owing to the strong hydrogen bond interactions between hydroxyls of nanocellulose and paper fibers, nanocellulose can effectively consolidate paper without adding adhesives. The composite of nanocellulose with other functional materials greatly expands its application scope, and the superior performance has been emphasized in paper deacidification, consolidation, antimicrobial effect, antioxidation, UV resistance, self-cleaning, promotion of printing property, reduction in air permeability, and flame retardancy. The application characteristics and future prospects of nanocellulose composites are highlighted in the conservation of paper-based cultural relics. [ABSTRACT FROM AUTHOR]

The proper dosing and optimization of retention additives are necessary to ensure the desired benefits without compromising other aspects of the paper manufacturing process. In this study, the effects of a cationic polyelectrolyte based on acrylamide and a cationic derivative of acrylic acid on the different properties of paper containing recycled fibers were investigated. The structural and tensile properties were examined through various analyses to determine the optimal dosage of the retention additive. The results obtained indicate that while the retention agent can enhance papermaking efficiency by improving retention, drainage, and sheet formation, it also negatively impacts the tensile strength and surface smoothness of the recycled paper. This complexity highlights the importance of a balanced approach in optimizing retention aid dosages. Determining the optimum dosage of such an agent requires multiple trials and analyses with varying dosages. This review aims to offer a background for engineers seeking to enhance the competitiveness and reduce production costs of their paper products, as well as for researchers striving to surpass the existing standards and achieve innovative outcomes. [ABSTRACT FROM AUTHOR]

This article analyzes the prospects for the appearance of paper-based sensors on the sensor market. It is concluded that paper-based sensors are not a fantasy but a reality. It is shown that paper has properties that make it possible to develop a wide variety of paper-based sensors, such as SERS, colorimetric, fluorescent, conductometric, capacitive, fiber-optic, electrochemical, microfluidic, shape-deformation, microwave, and various physical sensors. The use of paper in the manufacturing of various sensors opens up new possibilities both in terms of new approaches to their manufacturing and in terms of new areas of their application. However, it must be recognized that for the widespread use of paper and the appearance of paper-based sensors on the sensor market, many obstacles must be overcome. [ABSTRACT FROM AUTHOR]

Paper-based artworks are prone to natural aging processes driven by chemical and biological processes. Numerous treatments have been developed to mitigate deterioration and prevent irreversible damage. In this study, we investigated the use of poly(acrylic acid)/TiO2 composite hydrogels, combining their cleaning and protective functions in a minimally invasive treatment. Hydrogels allow for controlled water flow and photocatalytic TiO2 nanoparticles enhance the hydrogel's efficacy by enabling the removal of oxidation products and inactivating biological contaminants. Furthermore, this innovative material can act as a protective coating against UV-induced aging, preserving both color and stability of the paper. Raman spectroscopy and confocal laser scanning microscopy imaging techniques were employed to evaluate the treatments, allowing for us to differentiate between hydrolytic and oxidative aging processes. Our findings demonstrate that papers coated with poly(acrylic acid)/TiO2 composite hydrogels exhibit significant reductions in oxidative markers, an enhanced color stability, and an overall improved resistance to degradation compared to uncoated samples. [ABSTRACT FROM AUTHOR]

Succinic acid is applied in many chemical industries in which it can be produced through microbial fermentation using lignocellulosic biomasses. Mixed-waste office paper (MWOP) containing lignocellulosic fibers is enormously generated globally. MWOP is recycled into toilet paper and cardboard, but the recovery process is costly. The reuse of MWOP to alternatively produce succinic acid is highly attractive. In this study, pretreatment of MWOPs with 1% (v/v) H2SO4 at 121 °C for 20 min was found to be optimal. The optimal conditions for the enzymatic hydrolysis of H2SO4-pretreated MWOP (AP-MWOP) were at 50 °C, with cellulase loading at 80 PCU/g AP-MWOP. This resulted in the highest glucose (22.46 ± 0.15 g/L) and xylose (5.11 ± 0.32 g/L). Succinic acid production via separate hydrolysis and fermentation (SHF) by Escherichia coli KJ122 reached 28.19 ± 0.98 g/L (productivity of 1.17 ± 0.04 g/L/h). For simultaneous saccharification and fermentation (SSF), succinic acid was produced at 24.58 ± 2.32 g/L (productivity of 0.82 ± 0.07 g/L/h). Finally, succinic acid at 51.38 ± 4.05 g/L with yield and productivity of 0.75 ± 0.05 g/g and 1.07 ± 0.08 g/L/h was achieved via fed-batch pre-saccharified SSF. This study not only offers means to reuse MWOP for producing succinic acid but also provides insights for exploiting other wastes to high-value succinic acid, supporting environmental sustainability and zero-waste society. [ABSTRACT FROM AUTHOR]

Bacillus cereus is a widespread foodborne pathogen that can cause food poisoning when present in food at certain levels. Ingesting contaminated food may lead to symptoms such as abdominal pain, diarrhea, and, in severe cases, life-threatening conditions. In this study, a simple and super-fast method for detecting B. cereus was developed, which combines cellulose filter paper-based DNA extraction, multienzyme isothermal rapid amplification (MIRA), and lateral flow dipstick (LFD) technology. Initially, PCR was adopted to evaluate the DNA extraction efficiency of the filter paper, followed by the optimization of the lysis formula and extraction conditions. With the above optimization, DNA that can be used for subsequent nucleic acid amplification can be obtained within 3 min. Then, the isothermal amplification of MIRA–LFD was established and optimized to evaluate the detection specificity and sensitivity. Finally, the developed method was applied to detect B. cereus in cooked rice samples. The results indicated that the entire amplification procedure of MIRA-LFD only takes 15 min at 39 °C. The whole super-fast detection system could be completed in less than 20 min, from DNA extraction to result interpretation, which achieved a detection limit of 12 fg/μL of DNA concentration, corresponding to approximately 115 CFU/mL in actual samples. [ABSTRACT FROM AUTHOR]

Superhydrophobic paper-based functional materials have emerged as a sustainable solution with a wide range of applications due to their unique water-repelling properties. Inspired by natural examples like the lotus leaf, these materials combine low surface energy with micro/nanostructures to create air pockets that maintain a high contact angle. This review provides an in-depth analysis of recent advancements in the development of superhydrophobic paper-based materials, focusing on methodologies for modification, underlying mechanisms, and performance in various applications. The paper-based materials, leveraging their porous structure and flexibility, are modified to achieve superhydrophobicity, which broadens their application in oil–water separation, anti-corrosion, and self-cleaning. The review describes the use of these superhydrophobic paper-based materials in diagnostics, environmental management, energy generation, food testing, and smart packaging. It also discusses various superhydrophobic modification techniques, including surface chemical modification, coating technology, physical composite technology, laser etching, and other innovative methods. The applications and development prospects of these materials are explored, emphasizing their potential in self-cleaning materials, oil–water separation, droplet manipulation, and paper-based sensors for wearable electronics and environmental monitoring. [ABSTRACT FROM AUTHOR]

Invasive alien species pose significant ecological challenges, with Tradescantia fluminensis emerging as a major threat in Europe. This study investigates the potential of repurposing biomass from this invasive plant, collected in Galicia, for use in the pulp and paper industry. Following prior research on engineered paper made from Tradescantia fluminensis, this study examines its integration with commercially bleached eucalyptus pulp in varying proportions (90%, 70%, 50%, 30%, 10%). Key structural and physical properties, including pulp drainability, grammage, thickness, specific volume, density, and permeability, were analyzed to evaluate the viability of incorporating Tradescantia fluminensis biomass into paper production. The chemical composition and internal structures were observed using SEM visualization (JEOL 6100) to provide insights into the engineered paper's characteristics. The findings of this study suggest that blending Tradescantia fluminensis biomass with commercial pulp could provide a sustainable approach to paper manufacturing, leveraging residues from environmental cleanup efforts to reduce reliance on traditional raw materials. The best paper qualities were obtained with medium blends, ranging from 30 to 70% and 70 to 30% biomass to raw material. At these proportions, paper properties remained balanced, integrating both visual and physical characteristics. The most relevant data were observed for drainability (35–33° SR) and air resistance, which ranged from 5.57 to 7.33 s for 300 cm3 using the Gurley method. This study highlights the dual benefits of mitigating the ecological impact of invasive alien species waste while promoting sustainable practices in the paper industry. By challenging conventional norms and exploring new possibilities, it fosters the development of sustainable paper materials capable of promoting climate awareness and strengthening the connection between consumers, materials, and production processes. [ABSTRACT FROM AUTHOR]

In this work, four different experimental assessment approaches, namely, the Tissue Softness Analyzer (TSA), a Subjective Evaluation (SUB), the Kawabata Evaluation System (KES), and an Optical System (OPT), were used for the evaluation of softness on a set of 29 different tissue paper products. After processing and the interpretation of the results given by each one of the used methods, a procedure was implemented in the current work to make a comparison between them. The procedure consists in tracking the position of the tissue paper products on a ranking table, regardless of what values were obtained through each one of the four used methods independently. This comparison revealed to be very useful in determining the differences verified between methods allowing to conclude which ones were the least and the most concordant, and, at the same time, enabling us to identify interesting cases of tissue paper products on the set that caught our attention for their distinctive characteristics. [ABSTRACT FROM AUTHOR]

In the papermaking industry, cellulose fibers often undergo a bleaching process which affects the surface of the fibers, or their overall morphology. The surface of the produced paper, which is most often used as a printing substrate, depends on the production method, the arrangement of the cellulose fibers, and the quantity and fineness of the filler. The micro-irregularities caused by the uneven distribution of fibers and surface particles of the filler make the paper's surface rough and affect the print quality and its stability when exposed to light from the moment of production to use. The unbleached cellulose fibers in the printing substrate contain natural pigments, lignin and hemicellulose that absorb UV radiation, as opposed to bleached fibers, which have higher whiteness and lightfastness. Therefore, the influence of UV radiation on the surface roughness of prints made on papers with natural unbleached and bleached hemp fibers was analyzed. This research confirmed that papers formed from unbleached fibers have rougher surface and that printed graphic products from bleached fibers have higher stability to UV radiation than those from natural, unbleached hemp fibers after 96 h of treatment in the Suntest chamber. [ABSTRACT FROM AUTHOR]

The process of pulping and papermaking is a complicated, resource-demanding operation that requires energy, water, and chemicals. When not managed properly, the process can also contribute significantly to pollution. The washing process is one critical operation that impacts the process's economics and environmental footprint. Most mills utilize rotary vacuum washers to separate black liquor from pulp, ensuring clean pulp for further processing downstream. Numerous factors influence the efficiency of a brown stock washer, and the washing operation itself is intricate. This study employs the system dynamics modeling approach to examine the critical role of brown stock washing in the pulp and paper industry, emphasizing optimizing process parameters for improved efficiency and sustainability. In the first part of the paper, a single stage of the washer system is modeled by establishing mass balance equations for key streams, including pulp, liquor, and dissolved solids. Within the system dynamics environment, separate models are developed for each stream, allowing for a detailed analysis of their behavior. To enhance modeling efficiency, the brown stock washing process is divided into four distinct operations: dilution, pulp formation, washing, and filtration. Breaking down the process into these operations makes it possible to focus on optimizing each step for improved overall performance. Furthermore, a control strategy is implemented to ensure stability in critical areas such as dilution vat level, discharged pulp consistency, and filtration tank level. In the final phase of the research, a multistage countercurrent brown stock washing line comprising three washers is modeled. Researchers can gain insights into how different components interact and influence overall performance by evaluating various parameters and analyzing the line's efficiency. This comprehensive analysis enables them to identify potential improvements and optimize the washing process for enhanced productivity and quality output. The conclusions drawn from this work offer valuable guidance for optimizing water management practices in the pulp and paper sector, contributing to the industry's sustainability goals and regulatory compliance. [ABSTRACT FROM AUTHOR]

Against the backdrop of carbon reduction and low-carbon economic development, this study takes the global paper industry chain as its research subject and employs the SBM-GML model and input–output model to measure the low-carbon TFP and value chain embedding levels of 42 major global economies from 2001 to 2021. Using fixed-effects and threshold effect models, the study examines both the overall and stage-specific impacts of value chain embedding on low-carbon TFP. The results reveal that between 2001 and 2021, while the low-carbon TFP of major countries in the global paper industry chain steadily increased, significant disparities persisted among them. Most countries experienced low-carbon TFP growth driven by technological progress, whereas only a few high low-carbon TFP nations also demonstrated upward trends in technical efficiency. The division of labour position in the value chain significantly promoted low-carbon TFP at a ratio of 1:0.26. In contrast, the low-carbon TFP effects of participation displayed a nonlinear impact with a threshold of 0.21: it exerted an insignificant inhibitory effect in the initial stage but, upon crossing the threshold, resulted in a significant positive effect with a ratio of 1:0.13. These findings highlight the importance of optimizing GVC strategies to achieve sustainable industrial transformation and growth. [ABSTRACT FROM AUTHOR]

A comparative adsorption study was carried out for methylene blue (MB) and its 3,7-bis(N,N-(2-hydroxyethyl)amino)-phenothiazinium dye analog (MBI). Batch experiments employed aqueous solutions and commercial filter paper. Out of seven kinetic models tested by means of four quality statistical indicators, the pseudo-second-order, the double-exponential, and the bi-linear Weber–Morris equations were best fits. For both dyes, the process was described as a succession of two diffusion-controlled steps. The Freundlich isotherm was chosen from 11 models describing a variety of mechanism assumptions. Physisorption was considered responsible for the dye removal from liquid. Adsorption of MB is thermodynamically favored, whereas that of MBI is sterically hindered. Both processes are exothermic and exhibit reduced randomness at the S-L interface. The paper was found suitable for retaining MB but served rather filtration/purification purposes for MBI. [ABSTRACT FROM AUTHOR]

Featured Application: A paper-based triboelectric nanogenerator using carbon nanotube composite papers, as developed in this study, has the potential to be used as an energy harvester in fields such as the Internet of Things (IoT). A unique triboelectric nanogenerator (TENG) using carbon nanotube (CNT) composite papers is proposed in this work. CNT composite papers can be fabricated easily using a method based on the production of Japanese washi paper. To obtain and evaluate the proposed TENGs, several types of CNT composite papers and aluminum plates were prepared. As the CNT composite paper contained many paper fibers, it was expected to be negatively charged, and the aluminum plate was expected to be positively charged across the triboelectric series. Through various experiments, it was confirmed that CNT composite papers could be used as TENGs. In addition, it was found that when a CNT composite paper was used, it contributed to triboelectricity generation, and the contained CNTs efficiently transferred the generated charge to the electrodes. Furthermore, output voltages approaching a maximum RMS value of 300 mV could be obtained. The results of this study will aid in the practical application of paper-based TENGs in the near future. [ABSTRACT FROM AUTHOR]

Electrocatalytic water splitting is a promising approach for obtaining clean hydrogen energy. In this work, novel molybdate@carbon paper composite electrocatalysts (CoxFe10-xMoO@CP), displaying outstanding electrocatalytic capabilities, were deriving from anchoring cobalt/iron molybdate materials onto the surface of carbon paper fibers. By adjusting the cobalt-to-iron ratio, the composite (Co5Fe5MoO@CP), with the optimal molar proportion (Co/Fe = 5/5), exhibited a distinctive nanoflower morphology (50–100 nm), which provided a significant number of active sites for electrocatalytic reactions, and showed the strongest electrocatalytic potency for both the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). Specifically, the overpotentials for HER and OER were 123.6 and 245 mV at 10 mA·cm−2, with a Tafel slope of 78.3 and 92.2 mV·dec−1, respectively. The hydrogen and oxygen evolution reactions remained favorable and stable over 35 days and 2 weeks of cyclic voltammetry cycles. In a two-electrode system, efficient overall water splitting was achieved at a cell voltage of 1.60 V. Under high alkaline concentration and temperature conditions, the Co5Fe5MoO@CP composite still maintained excellent HER and OER catalytic activity and stability, indicating its satisfactory potential for industrial applications. Density functional theory (DFT) analysis revealed that the promoted hydrogen evolution capability derived from the synergistic catalytic effect of iron and cobalt atoms within the molecule, while cobalt atoms functioned as the catalytic core for the oxygen evolution process. This work provides a novel strategy towards high-efficiency electrocatalysts to significantly accelerate the overall water splitting. [ABSTRACT FROM AUTHOR]

This study aims to provide evidence that when testing cellulose paper modified with copper particles (CuPs), the particle size and the analysis method influence the antimicrobial activity observed by this material. Commercial CuPs of nanometric size (2.7 nm, CuNPs) and micrometric size (2.5 µm, CuMPs) were used to modify cellulose paper sheets. CuPs were incorporated during the pulp disintegration phase (stage 1) of the sheet formation process, according to the ISO 5269-1:2005 standard. Modified paper sheets retained 16% and 14% of CuNPs and CuMPs, respectively. Additionally, CuPs were distributed randomly on the fiber surfaces, often forming aggregates. Finally, the antimicrobial activity of the modified paper sheets was evaluated using ISO 20645:2004 and ISO 20743:2013. The results showed that the antimicrobial activity assessed using each standard method is conditioned by the mechanism of action of the CuPs and, therefore, by their size. It was concluded that ISO 20645:2004 is suitable for evaluating the antibacterial effect of paper/CuNPs, as nanoparticles diffuse from the paper and are released into the culture medium. In contrast, ISO 20743:2013 can be used for both CuNP- and CuMP-based paper, as it evaluates the antibacterial effect based on the direct interaction between the copper particle and the bacteria. [ABSTRACT FROM AUTHOR]

With the advent of artificial intelligence digitization, intangible cultural heritage faces challenges in preservation and transmission. Utilizing modern technology to achieve digital protection and dissemination has become a crucial issue today. This study enhances the digital inheritance and development of Chinese intangible cultural heritage paper-cutting art through generative AI technologies, specifically Diffusion and LoRA models. The Analytic Hierarchy Process (AHP) was employed to categorize the cultural value of paper-cutting, selecting four core elements: "Spring Festival", "Chinese Zodiac", "Women", and "Birds and Flowers". Based on these, eight LoRA models were developed to generate paper-cutting-style patterns (using the FLUX.1-dev and Stable Diffusion 1.5 models). In the user satisfaction assessment, the Importance–Performance Analysis (IPA) method was used to analyze four dimensions of the model experience. The results indicate that the LoRA model excels in generating detailed paper-cutting patterns and accurately reproducing cultural elements, particularly in the generation of complex Chinese character designs. User feedback suggests that the LoRA model effectively enhances the digital representation and dissemination of paper-cutting art, though there is room for improvement in terms of generation speed and ease of operation. This study provides a new technological pathway for the digital preservation of intangible cultural heritage and promotes the modernization of paper-cutting art transmission. [ABSTRACT FROM AUTHOR]

This paper reports studies on the thermal chemistry of the flash pyrolysis (heating rate of 20,000 °C/s up to 800 °C) of non-fossil fuel carbon (NFF-C) waste (or refuse-derived fuel, RDF) in the context of using this as an alternative reductant for blast furnace ironmaking. Gas chromatography–mass spectrometry (GCMS) analysis linked to the pyrolyser was used to simulate the thermal processes that take place during injection in the blast furnace raceway, where material experiences extreme temperature (ca. 1000 °C) over very short residence times (<300 ms). Species identification and qualitative analysis of evolved species generated are reported. Whilst the pyrolyser uses flash heating of a static sample, a drop tube furnace was also employed to study a sample moving rapidly through a pre-heated furnace held at 1000 °C to enable reductant burnout rates to be measured. The overarching aim of this piece of work is to study the suitability of replacing fossil fuel with non-recyclable plastic and paper as blast furnace reductants. [ABSTRACT FROM AUTHOR]

A recyclability perspective is essential in the sustainable development of energy storage devices, such as lithium-ion batteries (LIBs), but the development of LIBs prioritizes battery capacity and energy density over recyclability, and hence, the recycling methods are complex and the recycling rate is low compared to other technologies. To improve this situation, the underlying battery design must be changed and the material choices need to be made with a sustainable mindset. A suitable and effective approach is to utilize bio-materials, such as paper and electrode composites made from graphite and cellulose, and adopt already existing recycling methods connected to the paper industry. To address this, we have developed a concept for fabricating fully disposable and resource-efficient paper-based electrodes with a large-scale roll-to-roll coating operation in which the conductive material is a nanographite and microcrystalline cellulose mixture coated on a paper separator. The overall best result was achieved with coated roll 08 with a coat weight of 12.83(22) g/m2 and after calendering, the highest density of 1.117(97) g/cm3, as well as the highest electrical conductivity with a resistivity of 0.1293(17) m Ω · m. We also verified the use of this concept as an anode in LIB half-cell coin cells, showing a specific capacity of 147 mAh/g, i.e., 40% of graphite's theoretical performance, and a good long-term stability of battery capacity over extended cycling. This concept highlights the potential of using paper as a separator and strengthens the outlook of a new design concept wherein paper can both act as a separator and a substrate for coating the anode material. [ABSTRACT FROM AUTHOR]

The processing of paper sludge is currently an important environmental topic due to its high global production. The aim of this study is to monitor the biodegradation of paper sludge when the initial conditions change. Biodegradability tests 301F and OECD 311 were used to determine biodegradation. The data obtained from the tests were subsequently obtained for the simulation in MATLAB R2023b. The highest aerobic decomposition was approximately 80% after 28 days at an initial concentration of paper sludge leachate of 76 g/L. By simulating 3D modelling, we can predict that with a retention time of 1 day with degradation under aerobic conditions at the level of 70%, the ideal initial concentration of organic substances will be 157.55 g/L. Based on this model, it is possible to estimate that with a biogas production of 554 m3/tVS and a decomposition time of 20 days, it is necessary to set a concentration of approximately 128 g/L. Based on biodegradability tests, paper sludge was evaluated as suitable for aerobic or anaerobic biological decomposition. [ABSTRACT FROM AUTHOR]

We propose a new type of soft actuator based on carbon nanotube (CNT) composite paper (CNTCP), i.e., a paper actuator. In our previous study, we demonstrated that actuator operation was possible when using CNTCPs as electrodes with ordinary paper containing ionic liquid between the electrodes; however, their bending motion was not sufficient. Therefore, we here attempt to modify the paper actuator. For this, we tried to soften CNTCPs by first reducing the ratio of contained CNTs. In addition, as a new strategy, we took advantage of the fact that the proposed actuator was made of paper and introduced the Kirigami (introducing periodical slits to papers) technique into the structure of our paper actuator. As a result, the performance of the actuator was improved, and its bending motion became visibly larger. The response of the improved actuator to the input voltage was investigated in detail, and the detailed operating conditions could be clarified. Moreover, it was found that not only a bending motion but also a twisting motion could be realized in specific slit patterns. It is thought that the fact that the variation in movement can be increased simply by adding incisions is unique to the proposed paper actuator. [ABSTRACT FROM AUTHOR]

Handmade papers, as carriers of paper-based cultural relics, have played a crucial role in the development of human culture, knowledge, and civilization. Understanding the intricate relationship between the structural properties and degradation mechanisms of handmade papers is essential for the conservation of historical documents. In this work, an artificial dry-heat-accelerated aging method was used to investigate the interplay among the mechanical properties of paper, the degree of polymerization (DP) of cellulose, the chemical composition, the hydrogen bond strength, the crystallinity, and the degree of hornification for paper fibers. The results demonstrated for the first time that the mechanical properties of handmade bamboo paper exhibited an initial plateau region, a rapid decline region, and sometimes a second plateau region as it undergoes a dry-heat aging process. The changes in cellulose, hemicellulose, and lignin content were tracked throughout these three stages. The lignin content was relatively stable, while the cellulose and hemicellulose content decreased, which was consistent with the observed decline in mechanical properties. When the DP of cellulose decreased to the range of 600–400, there was a critical point in the mechanical properties of the paper, marking a transition from the initial stable region to a rapid decline region. The fiber embrittlement caused by cellulose chain breakage resulting from the decrease in DP was counteracted by the enhancement of intermolecular hydrogen bonds and the hornification process. A second stable region appeared when the DP was less than 400, marking a transition from a balanced or slightly decreasing trend in the initial plateau region to a sharp decline. This study also discussed for the first time that the formation of the second plateau region may be due to the presence of hemicellulose and lignin, which hinder the further aggregation of cellulose and maintain the structural stability of the fiber cell. The findings of this study can provide guidance for improving ancient book preservation strategies. On the one hand, understanding how these components affect the durability of paper can help us better predict and slow down the aging of ancient books. On the other hand, specific chemical treatment methods can be designed to stabilize these components and reduce their degradation rate under adverse environmental conditions. [ABSTRACT FROM AUTHOR]

This study introduces a novel paper coating approach using modified zinc oxide (ZnO), providing a comparison with conventional materials used in the paper industry. The research focused on determining the concentration for effective microbial growth inhibition and evaluates the impact of different ZnO types on coated-paper properties, including antimicrobial activity, surface morphology, tensile strength, and water absorption. Specifically, ZnO microparticles (ZnOws), ZnO nanoparticles (ZnOnp), and modified ZnOnp (ZnOnp-CaCO3, with a core–shell structure composed of calcium carbonate [CaCO3] and nano-zinc oxide) were incorporated into coating formulations at varying concentrations (0 × MIC, 1 × MIC, 2 × MIC, and 3 × MIC, based on minimum inhibitory concentrations [MICs]). The results demonstrated that among all tested microorganisms, ZnOnp-CaCO3 showed the lowest MIC values. ZnOnp-CaCO3-coated paper exhibited superior antimicrobial activity against both Gram-positive and Gram-negative bacteria, as well as fungi, outperforming ZnOws and ZnOnp. At 1 × MIC, %inhibition for E. coli, S. aureus, and A. niger were 98.3%, 99.1%, and 90.8%, respectively. Additionally, ZnOnp-CaCO3 coatings caused minimal color change in the paper compared to the other ZnO variants. The coating did not negatively impact the mechanical properties of the paper across all ZnO types and concentrations. Water absorption tests showed increased hydrophobicity with higher ZnO content, with ZnOnp and ZnOnp-CaCO3 exhibiting greater reductions in water absorption than ZnOws. Overall, ZnOnp-CaCO3 showed strong potential as an antimicrobial agent for paper surfaces, making it ideal for packaging and hygiene products. By partially replacing ZnOnp with inexpensive CaCO3 core particles, ZnOnp-CaCO3 delivers enhanced performance, reduced costs, and greater sustainability for large-scale applications. [ABSTRACT FROM AUTHOR]

This study explores the use of cellulose nanofiber (CNF)-stabilized Pickering emulsions for paper coatings, focusing on their rheological properties and effects on hydrophilicity and water vapor transmission rate (WVTR). Two types of Pickering emulsions, oil-in-water (O/W), were stabilized with 1 wt% CNF extracted from fique by-products. The oily phases of the emulsions were composed of poly(lactic acid) (PLA) and cocoa butter (CB). The physical stability, viscosity, and viscoelasticity of the emulsions were characterized. The emulsions were applied to the surfaces of Bond and Kraft papers using the rod-coating method. The coating process involved first applying a layer of the PLA emulsion followed by a layer of the CB emulsion. The coated papers were then evaluated by FE-SEM, contact angle, adhesion work, and water vapor transmission rate (WVTR). The results indicated that the coatings effectively produced a slightly hydrophobic surface on the papers, with contact angles approaching 90°. Initially, Kraft paper exhibited a WVTR value of 29.20 ± 1.13 g/m2·h, which significantly decreased to 7.06 ± 2.80 g/m2·h after coating, representing a reduction of 75.82%. Similarly, natural Bond paper showed a WVTR value of 30.56 ± 0.34 g/m2·h, which decreased to 14.37 ± 5.91 g/m2·h after coating, indicating a reduction of 47.02%. These findings demonstrate the potential of CNF-stabilized Pickering emulsions for enhancing the performance of paper coatings in terms of hydrophobicity and moisture barrier properties. The approach of this study aligns with global sustainability goals in packaging materials combining the use of PLA and CB to develop a waterborne coating to enhance the moisture barrier properties, demonstrated by a substantial reduction in water vapor transmission rates, and an improved hydrophobicity of coated papers. [ABSTRACT FROM AUTHOR]

Excessive copper (Cu2+) causes adverse effects on human health and the ecological environment. Traditional methods for detecting Cu2+ have drawbacks such as high detection costs, complex operating conditions, and being time consuming. Therefore, there is an urgent need to develop simple detection methods to better meet specific health and environment quality needs. In this work, a paper-based fluorescence sensor was prepared (herein referred to as the as-prepared method) by immersing filter paper in aqueous polyethyleneimine (PEI) solution, and its potential use in Cu2+ detection was investigated. The results showed that the as-prepared paper samples, with fluorescence properties obtained by aggregation-induced luminescence of PEI, have selective recognition of Cu2+ based on the internal filtration effect, and the lowest detection limit is 0.03 μM. In addition, the relative error of this method is in the range of 1.80~2.23%, which is relatively comparable to the national standard method (0.63~630 μM), demonstrating high accuracy. Therefore, paper-based sensors with a simple preparation method have potential applications in the detection of Cu2+ in water. [ABSTRACT FROM AUTHOR]

Herein, we developed a colorimetric method for the determination of Cu2+ and Zn2+ using NBD-G as a novel selective metal sensor. NBD-G was easily synthesized by a nucleophilic substitution reaction between 4-chloro-7-nitro-2,1,3-benzoxadiazole (NBD-Cl) and Girard's Reagent P. The NBD-G solution is yellow, but when it reacts with Cu2+ and Zn2+, its color changes selectively to red (510 nm) and orange (480 nm), respectively. NBD-G was used as a sensor for Cu2+ and Zn2+, showing a high sensitivity down to 0.77 µM for Cu2+ and 1.66 µM for Zn2+. NBD-G could determine both metals simultaneously; thus, it was applied to determine them in multimineral supplements, which showed excellent recoveries. Next, a filter paper impregnated with NBD-G was prepared as a test paper, and a simple, selective, and rapid onsite method for quantifying Cu2+ was developed as, interestingly, the paper showed no change upon the addition of Zn2+. Next, Cu2+ could be quantified with high selectivity and accuracy by photographing the color change with a smartphone camera and processing the image with Image J. The detection limit for Cu2+ using this method was 3.9 µM. Finally, the NBD-G test paper method was able to satisfactorily quantify Cu2+ spiked into the rainwater. [ABSTRACT FROM AUTHOR]

Copper ions (Cu2+) are the third most essential transition metal ions critical to human health. Rapid detection of Cu2+ in water and biological fluids is of significant importance. In this study, we develop a sensitive multi-channel paper microfluidic device integrated with a 3D-printed smartphone-based colorimetric reader for the rapid detection of Cu2+. A novel rhodamine derivative, 1-(N,N-dichloromethine) amino-4-rhodamine B hydrazine-benzimide (RBCl), exhibiting high selectivity and sensitivity to Cu2+, was synthesized and applied as the detection reagent. The interaction mechanism between RBCl and Cu2+ was investigated, revealing a structural transition from a colorless spirolactam (closed-ring) to an open-ring amide structure, resulting in a pink color upon Cu2+ binding. A multi-channel paper microfluidic device with eight detection zones was fabricated, enabling the simultaneous analysis of eight samples. To enhance portability and quantification, a 3D-printed smartphone colorimetric reader was integrated, providing a rapid and efficient detection platform. The system achieved highly specific Cu2+ detection within 2 min, with a detection limit as low as 1.51 ng/mL, meeting water monitoring standards in most countries. Excellent recoveries were demonstrated in real samples, including tap water, river water, blood serum, and urine diluent. This integrated paper microfluidic system is highly sensitive and specific, offering a promising solution for water quality monitoring and health assessment through its rapid sample-to-answer capability. [ABSTRACT FROM AUTHOR]

Archival materials are increasingly vulnerable to damage from chemical, physical, biological, and environmental factors, including climate change-related extreme weather events such as torrential rains and flash floods. These conditions pose significant risks to paper-based cultural heritage, leading to degradation from both water and salt exposure. This study investigates the effects of direct immersion in saline solutions on different types of paper, simulating the impact of flooding events. We focused on how varying levels of salinity affect the crystalline structure of paper, which is crucial for understanding its degradation. This study employed non-invasive, portable optical techniques such as luminescence, reflectivity, and Raman spectroscopy to monitor the changes in the paper structure. Our results showed that salt exposure leads to significant alterations in the paper's crystalline composition. The study concludes that washing treatments are essential for mitigating further degradation, highlighting the importance of timely intervention in preserving cultural heritage. The non-destructive nature of the methods used also demonstrates their potential for in situ applications in cultural heritage conservation. [ABSTRACT FROM AUTHOR]

Background: The Beck Depression Inventory-II (BDI-II) is a widely used patient-reported outcome (PRO) tool designed to screen for depressive symptoms and assess their severity. In recent years, with advancements in digital technology, the BDI-II has been adapted for use as an electronic PRO (ePRO) tool. However, to the best of our knowledge, the reliability of the smartphone version of the BDI-II has not been thoroughly investigated. This study aimed to assess the equivalence of the traditional paper and smartphone versions of the BDI-II. Methods: This study employed a randomized crossover design with adults (n = 100) from the Gunma Prefecture, Japan. Participants completed both the paper and smartphone versions of the BDI-II at 1-week intervals. The equivalence between the two versions was evaluated using the intraclass correlation coefficient (ICCagreement). Additionally, Cronbach's alpha and McDonald's omega were calculated for both versions. Results: The mean age of the participants was 19.78 years (SD = 0.94, 10% male). The ICCagreement between the paper and smartphone versions of the BDI-II was 0.81 (95% CI 0.74–0.87). Cronbach's alpha was 0.88 (95% CI 0.84–0.91) for the paper version and 0.88 (95% CI 0.84–0.91) for the smartphone version. McDonald's omega was 0.88 (95% CI 0.81–0.95) for the paper version and 0.89 (95% CI 0.85–0.93) for the smartphone version. Conclusions: The BDI-II is suitable for use in its smartphone version, and the smartphone version of the BDI-II is a valuable addition to the mental healthcare professional's toolkit. [ABSTRACT FROM AUTHOR]

The development and standardization of an effective inoculation technique are essential for reliable screening of crop genotypes. In this study, three inoculation methods—in vitro paper towel, in vitro agar, and soil inoculation in pots—were tested to evaluate the pathogenic potential of Macrophomina phaseolina, the causative agent of dry root rot (DRR). Since the pathogenicity of M. phaseolina is influenced by environmental factors, identifying a robust inoculation method is critical. Among the three techniques, the paper towel inoculation method resulted in the highest seedling mortality of 66.66% in cluster beans and 86.67% in cowpeas within just ten days, demonstrating its effectiveness. The agar inoculation technique, while successful, required 15 days to confirm pathogenicity, with seedling mortality rates of 63.33% for cowpeas and 53.33% for cluster beans. In contrast, the soil inoculation method showed comparatively lower mortality rates, with 36.66% for cluster beans and 26.67% for cowpeas. Based on these findings, the paper towel method emerged as the most efficient technique for inducing rapid pathogenicity in M. phaseolina in both cowpeas and cluster beans. Its suitability was further validated through the screening of released varieties of these crops compared against the soil inoculation method. Notably, genotypes that appeared moderately resistant under the soil inoculation method were found to range from susceptible to highly susceptible when evaluated using the paper towel technique. These results underscore the reliability of the paper towel method as a rapid and robust screening tool for identifying resistant genotypes of cowpea and cluster bean on a larger scale. [ABSTRACT FROM AUTHOR]

The catalytic performance of mixed metal oxides in the combustion of paper industrial waste (bark, paper sludge, and waste paper reject) was investigated. The mixed metal oxide catalyst with, SiO2, Al2O3, Fe2O3, and CaO percentages of 78.57, 9.28, 4.28, and 7.85, respectively, was prepared by mixing iron mill scale, clinker, used cement, and bentonite clay, which were employed as metal oxide precursors. An analysis of the combustion behavior of bark, paper sludge, and waste paper reject with and without a mixed metal oxide catalyst, using the thermogravimetric analysis technique, showed that the ignition temperature remained unchanged after the addition of the catalyst. In contrast, the burnout temperature was reduced from 616.9 to 482.6 °C, 682.0 to 672.5 °C, and 678.1 to 669.9 °C for bark, paper sludge, and waste paper reject, respectively. These results indicated that adding a mixed metal oxide catalyst enhanced the combustion reactivity via the accelerated char combustion of biomass. Furthermore, the products formed during the combustion process with and without a catalyst were investigated in a packed-bed reactor. The gaseous products (H2, CO, CH4, C2H4, C2H6, and CO2) were observed during the combustion process of bark, paper sludge, and waste paper reject at 700 °C, both with and without a mixed metal oxide catalyst. However, higher H2 and CO2 compositions, which are attributed to the catalyst addition, were found in the presence of a catalyst, which improved the tar decomposition and the water–gas shift reaction. [ABSTRACT FROM AUTHOR]

This study investigates the triboelectric performance of nanogenerators based on copy paper (CP) and barium titanate (BTO) with varying concentrations (0%, 5%, 10%, 15%, and 20%). BTO was coated onto the paper surface via screen-printing, significantly enhancing the triboelectric properties. Results showed that as the BTO concentration increased, the output performance improved, with optimal performance observed at 15% BTO. At this concentration, the nanogenerator produced an output of 103 V and 3.6 µA. The CP/BTO nanogenerator demonstrated stable performance over 57,600 cycles at 4 Hz frequency and 40 N applied force, indicating excellent durability. The device attained a maximum power density of 32.4 µWcm2, highlighting the efficiency improvement through BTO integration. Various parameters including BTO concentration, applied force, and frequency were studied to optimize device performance. The CP/BTO device successfully powered 60 LEDs and a calculator, demonstrating its potential for practical energy harvesting applications. This research presents a promising approach for developing low-cost, environmentally friendly power-generating systems for wearable and portable devices. [ABSTRACT FROM AUTHOR]

The paper industry is undergoing a critical phase of digital transformation, driven by the need for increased efficiency and sustainability. This study offers an initial insight into the industry's digitalisation status based on a survey conducted at the ZELLCHEMING Expo 2024 by ZELLCHEMING's technical committee DATA. The survey assessed the digital maturity of various companies and the industry, uncovering data management practices and key challenges. The findings reveal a discrepancy between the companies' self-assessed digital maturity and their views on the industry's overall digitalisation, with the companies generally rating the industry as being on a rather low maturity whilst rating their own maturity more favourably. Challenges, such as legacy systems, data quality issues, and inconsistent digitalisation efforts, persist, although there is a notable awareness of the importance of data. The study highlights the potential of frameworks, like the Industrie 4.0 Maturity Index and the VDI Guideline for Industrie 4.0, in guiding digital transformation. To enhance digital maturity, companies must advance through the stages of digital integration, address key obstacles, and align digital initiatives with strategic goals. This paper offers practical recommendations for advancing digital capabilities and achieving long-term sustainability and competitiveness not only in the paper industry but also generally for manufacturing enterprises. Ultimately, this research emphasises the need for a cohesive approach to digitalisation, which involves all stakeholders—from management to operational staff—in fostering resilience and adaptability in an ever-evolving industrial landscape. [ABSTRACT FROM AUTHOR]

The subject of this study is the optimization of the paper production process in one of Poland's leading paper mills. In addition to its primary objective of paper production, the company generates heat and electricity for internal consumption and external clients, including the local municipality. Surplus energy may be sold on the power exchange; however, this requires forecasting the quantity of energy to be sold 24 h in advance, which introduces an element of uncertainty. Production stoppages, often caused by random events such as paper breakage, force a power decrease in the CHP system, further complicating energy forecasting. To minimize the occurrence of such events, numerical taxonomy methods were employed to determine the optimal screen speed (Vs) and winding speed (Vn) for two paper machines, based on the type and weight of the paper produced. This analysis utilized detailed daily data collected by the company over the period 2015–2020. The findings contribute to minimizing the occurrence of paper roll tearing, thereby reducing the risk of inaccurate forecasts of the energy and heat produced by the CHP system. Furthermore, the methodology employed in this study may be effectively applied to other optimization problems in industrial processes. [ABSTRACT FROM AUTHOR]

Paper-based cultural relics inevitably face a variety of diseases such as acidification, yellowing, and strength loss during long-term preservation, where weakly alkaline inorganic materials play an important role in their deacidification treatments. In this work, by simply adjusting the supersaturation of crystal growing solution without the use of any organic additives, one-dimensional (1D) and two-dimensional (2D) weakly alkaline materials—magnesium carbonate hydrates (MCHs)—were controllably synthesized. It is worth noting that the coatings of 1D/2D MCHs not only cause little change in chromatic aberration and water wettability, but also ensure their safety for alkali-sensitive pigments. Meanwhile, the deacidification, anti-aging, strength-enhancing, and flame-retardant effects of these materials have been tested on ancient book papers, all of which achieved good protective effects. In contrast, 1D MCH materials brought about significant enhancement in both mechanical strengths and flame-retardant effects, and the related effects were investigated. Based on this facile micromorphology control strategy, more low-dimensional nanomaterials are expected to be synthesized by design for the protection of paper-based relics, which will expand our knowledge on functional deacidification and protection mechanisms. [ABSTRACT FROM AUTHOR]

This text describes a study that investigates the mechanics, environmental benefits, and potential challenges of paper recycling machines. It highlights the importance of these machines in promoting a more sustainable future, and how they align with the United Nations' Sustainable Development Goals (SDGs). The SDGs aim to address issues such as climate change, land use, responsible consumption and production, and poverty alleviation by promoting sustainable economies. This study explores the transformative potential of the recycling industry and its impact on the economy of Papua New Guinea (PNG). [ABSTRACT FROM AUTHOR]

The influence of scientific papers is measured by their citations. Although predicting the papers' citation impact based on non-content factors has garnered extensive attention, the influence of such factors is rarely compared. In this article, we compare the influence of non-content factors on the citation counts of academic publications across three fields, i.e., math, computer science, and management. We consider different methods in this study, including three machine learning approaches, namely, XGBoost, Gradient Boosting Decision Tree, and Random Forest, along with statistical techniques such as linear regression and quantile analysis. Our findings reveal that no matter the field or analytical method applied, author prestige and the number of references consistently stand out as the most influential factors, while the breadth of categories covered by the paper has minimal impact. In mathematics, the first citation date and article length are almost equally important as author prestige, while the number of authors and the journal impact factor are crucial for computer science papers. In management, the number of collaborating countries is relatively influential with respect to the paper's citations. The results of the quantile regression indicate that at higher quantile levels, the impact of author prestige and the number of authors on the papers' citation impact are more pronounced across all three disciplines, while the journal impact factor and paper length have the greatest influence at low and medium quantile levels. Our findings indicate that the reliance of academic citations on author prestige and journal impact factors not only highlights the unequal distribution of resources within the current academic system but also further exacerbates citation inequality. [ABSTRACT FROM AUTHOR]

Although paper packages are biodegradable, their applications in food packaging are limited due to high affinity for absorbing moisture and the high permeability of gases and liquids with surroundings. Therefore, exploring the use biodegradable coatings such as nanocellulose to improve barrier is a relevant strategy. This study assessed the efficacy of unbleached nanofibrillated cellulose (NFC) as an additive to paper and coatings. Using NFC derived from unbleached eucalyptus pulp, a 5% mass addition to the paper pulp and a 2 mm wet nanocellulose coating to kraft paper handsheets made from pine pulp were investigated. In addition, nanocellulose films of similar thicknesses were appraised. The physical, morphological, mechanical, and thermal characteristics of the resulting papers were assessed. Incorporating NFC notably enhanced the morphology area of the paper by padding its pores, thus increasing its density by up to 48% and improving its water barrier properties by up to 50%. The mechanical strength showed significant enhancements, particularly in bursting and tensile strength with increases of up to 134% and 50%, respectively. Anyhow, the films exhibited lower bursting indices and no improvement in the tearing index. Nonetheless, the thermal stability of the handsheets with NFC coating meets the minimum requirements for food packaging. [ABSTRACT FROM AUTHOR]

This study aimed to investigate the effect of aminating waste newsprint paper with different aminating agents (ammonia/ammonia water, ethylenediamine, and diethylenetriamine) for the sorption efficiency of Reactive Black 5 (RB5) and Reactive Yellow 84 (RY84) dyes. To increase the amination efficiency, the paper material was pre-activated with epichlorohydrin. The scope of this study included the characterization of the sorbents tested (FTIR, elemental analysis, BET surface area, porosity, and pHPZC), determination of the influence of pH on dye sorption efficiency, sorption kinetics, and the maximum sorption capacity of the dyes. The study results showed that amination with ethylenediamine and diethylenetriamine introduced 87% and 194% more amine groups into the sorbent's structure compared to the treatment with ammonia. The sorption efficiency of RB5 and RY84 on the sorbents tested was the highest in the pH range of 2–3. The sorption equilibrium time ranged from 90 to 150 min and was longer in the case of the unmodified sorbents. The experimental data from the study were best described by the pseudo-second-order model and the Langmuir 1 and 2 models. Amination had a very strong effect on the sorption capacity of newsprint. For example, the sorption capacity of newsprint paper towards RB5 (Qmax = 7.12 mg/g) increased after amination with ammonia, ethylenediamine, and diethylenetriamine to the value of Qmax = 182.78 mg/g, Qmax = 202.7 mg/g, and Qmax = 231.5 mg/g, respectively. [ABSTRACT FROM AUTHOR]

This study investigates the fabrication and characterization of flexible PN diode devices using phosphorus- and boron-doped carbon nanotube (CNT) paper, also known as Buckypaper (BP). The BP substrate is fabricated from multi-walled carbon nanotubes (MWCNTs) and doped with phosphorus and boron to form N-type and P-type semiconductors, respectively. Various experimental techniques, including Raman spectroscopy, Hall effect measurements, and scanning electron microscopy (SEM), are employed to analyze the properties of the doped BP. The results reveal that the current-voltage (I-V) and capacitance-voltage (C-V) characteristics preliminarily exhibit the basic electrical properties of a diode after doping with P-type and N-type carriers. Subsequently, optimized vertical stacking combined with parallel electrode configurations for the BP diode devices demonstrates that vertical series stacking gradually enhances the thermoelectric voltage, while horizontal parallel connections approximately scale up the thermoelectric and photovoltaic voltages proportionally. The findings underscore the critical role of creating heterogeneously doped CNT-paper PN junction electric fields in improving the performance of carbon-based semiconductor devices. Furthermore, we demonstrate that these directionally oriented energy devices, when stacked, can form modular systems with enhanced efficiency. This work highlights the potential of flexible carbon material-based devices for advanced thermoelectric and photovoltaic applications. [ABSTRACT FROM AUTHOR]

The need for biodegradable and environmentally friendly materials is increasing due to resource shortages and rising levels of environmental pollution. Agro-food waste, which includes coffee grounds, is of great interest in the production of composite materials due to its low cost, low density, easy availability, non-abrasive nature, specific properties such as reduced wear on the machinery used, the absence of residues and toxic products, and biodegradable characteristics. The composite materials developed that include coffee grounds exhibit good characteristics. This field is evolving and requires further improvements, but, at this moment, it can be stated that coffee grounds are not just waste but can be transformed into a highly efficient material applicable in various domains. In this study, composite materials were prepared using paper pulp as a matrix, coffee grounds as a filler material, and water as a binding agent. The obtained composite materials were evaluated through thermal analysis, SEM, EDX, ATR-FTIR, and rheological behavior analysis. The composite materials created from paper pulp and coffee grounds proved to be effective for use in the production of seedling pots. The seedling pots created in this study are produced at a low cost, are environmentally friendly, exhibit thermal stability, have good stability over time, and have good resistance to deformation. [ABSTRACT FROM AUTHOR]

The automotive industry is under growing pressure from regulatory agencies to improve the recyclability of its plastic components. Simultaneously, manufacturers are adopting natural fiber composites in vehicles to reduce their carbon footprint and decrease reliance on petroleum-based materials. This presents a challenge at vehicle end-of-life, however, as natural fiber-reinforced polymers are substantially more difficult to recycle than their unreinforced counterparts. This study investigated the development of a mechanical recycling process for paper fiber-reinforced polypropylene composites, focusing on the impact of injection molding parameters—specifically, injection temperature and rate—on the thermal, mechanical, and water uptake properties of the composites. The results showed that processing temperature had a greater influence on composite performance than injection rate, with some limited interaction effects between the two. Higher processing intensity damaged the paper fibers, increasing the number of nucleation sites and resulting in greater polypropylene crystallinity. These structural changes reduced tensile properties at higher intensities, while flexural properties improved. Objective function analysis was applied to identify optimal processing conditions, balancing these competing trends. Overall, the findings demonstrate that paper fiber-reinforced polypropylene composites can be recycled into automotive-relevant injection molding compounds using conventional plastic manufacturing techniques, though careful tuning of processing parameters is essential to achieve optimal performance. [ABSTRACT FROM AUTHOR]

Cellulose nanomaterials have been demonstrated to be excellent barriers against grease, oxygen, and other vapors, but their implementation in packaging materials is challenging because of numerous technical and practical challenges. In this work, the oxygen, air, grease, and heptane barrier performance of copy papers coated with cellulose nanocrystals (CNCs), oxidized cellulose nanofibrils (TOCNs), and carboxymethyl cellulose (CMC) weas examined. The effects of different materials and processing conditions were evaluated for their impacts on the resulting barrier properties. TOCN coatings demonstrated significantly better barrier properties than CNC and CMC coatings due to the long-range networked structure of TOCN suspensions eliciting enhanced film formation at the paper surface. Neat coatings of nanocellulose did not readily result in strong oxygen barriers, but the addition of CMC and/or an additional waterborne water barrier coating was found to result in oxygen barriers suitable for packaging applications (1 cm3/m2·day transmission at low humidity with a 10 g/m2 coating). Cast films and thick coatings of CMC were good barriers to oxygen, grease, and air, and its addition to cellulose nanomaterial suspensions aided the coating process and reduced coating defects. In all cases, the incorporation of additional processing aids or coatings was necessary to achieve suitable barrier properties. However, maintaining the strong barrier properties of nanocellulose coatings after creasing remains challenging. [ABSTRACT FROM AUTHOR]

This paper evaluates the modification of fiber morphology and the strength property development of paper from Enset fiber as a function of soda pulping conditions and refining energy. Soda pulping was conducted at pulping temperatures between 160 and 180 °C. The NaOH charge was 16, 20, and 24% based on the initial raw material. The beating of pulp was conducted using a Jokro mill. The refining of pulp was conducted in a laboratory refiner at different refining intensities. The mild Jokro mill beating was not effective on Enset fiber pulp. On the other hand, the laboratory refiner effectively refined the pulp. The fiber morphology was altered in the way of improving the paper formation and strength. The beating degree of the pulp was increased to about 49 °SR. The tensile index was enhanced to around 80 Nm/g using a refining energy input of 250 kwh/t. From the results, it can be concluded that Enset fiber pulp is suitable for packaging papers due to its high strength level. On the other hand, Enset fiber can be a potential raw material for specialty papers like filter paper and tea bags because of its high porosity. [ABSTRACT FROM AUTHOR]

Polyethylene-, polyvinylidene chloride-, and per- and polyfluoroalkyl substance-coated paper generate microplastics or fluorochemicals in the environment. Here, we report an approach for the development of oil-resistant papers using an environmentally friendly, fluorine-free, water-dispersible poly(dimethylsiloxane) (PDMS) coating on kraft paper. Carboxylic-functionalized PDMS (PDMS-COOH) was synthesized and subsequently neutralized with ammonium bicarbonate to obtain a waterborne emulsion, which was then coated onto kraft paper. The water resistance of the coated paper was determined via Cobb60 measurements. The Cobb60 value was reduced to 2.70 ± 0.14 g/m2 as compared to 87.6 ± 5.1 g/m2 for uncoated paper, suggesting a remarkable improvement in water resistance. Similarly, oil resistance was found to be 12/12 on the kit test scale versus 0/12 for uncoated paper. In addition, the coated paper retained 70–90% of its inherent mechanical properties, and more importantly, the coated paper was recycled via pulp recovery using a standard protocol with a 91.1% yield. [ABSTRACT FROM AUTHOR]