Search

In response to the issue of young truck drivers' weaker perception of potential risks, which makes them more prone to engaging in risky driving behaviors, the direct influence of risk perception on behavior was innovatively considered. An improved theory of planned behavior (TPB) model was developed and a study on risky driving behavior among young truck drivers was conducted. Valid questionnaire data from 330 young truck drivers in China were collected, and the improved TPB model was validated and analyzed through structural equation modeling. The results indicate that the improved TPB model can effectively explain the risky driving behavior among young truck drivers. Specifically, attitudes toward behavior, subjective norms, and perceived behavioral control have significant positive effects on behavioral intention, while behavioral intention and perceived behavioral control have significant positive effects on behavior. In addition, risk perception has a significant negative effect on behavioral intention and behavior. Furthermore, a comparison with the traditional TPB model reveals that the improved TPB model performs better in terms of fit and explanatory power. Fit indices CMIN/DF, RMSEA, and AGFI were optimized by 16%, 18%, and 1.5%, respectively, and there was a 5% increase in explanatory power for behavior variance, validating the rationality and effectiveness of the improved TPB model. This provides decision support for the development of intervention measures for risky driving behavior among young truck drivers in the future. [ABSTRACT FROM AUTHOR]

Based on the change trends of traffic flow in different controlled directions at an intersection, the space-time resource integrated optimization method for TOD (time-of-day) division based on multidimensional traffic-flow data is proposed in this paper. By analyzing the traffic-flow data of 8, 4, 2, and 1 dimensions commonly used at the intersection, the dynamic Fisher algorithm is used to complete the time segment division of the traffic-flow sequence of different dimensions. On this basis, the preliminary TOD division is completed, and the phase timing and lane-use assignment corresponding to the preliminary time periods are optimized. Then, the adjacent time periods are merged and tested to complete the final result of the TOD division. In order to verify the effectiveness of the proposed method, the schemes based on traffic-flow data of different dimensions are carried out by using the data at an actual intersection in Wuhu City, and the total and average vehicle delays of different schemes throughout the day are evaluated by VISSIM. The results show that the more dimensions of traffic flow data are adopted, the more refined the TOD division scheme is, and the less the total delay and average delay at intersections throughout the day are. In particular, the TOD division scheme after further optimizing the lane-use assignment can further reduce the total and average vehicle delay throughout the day. It shows that the method using multidimensional traffic-flow data at an intersection to carry out the integrated optimization of TOD division, lane-use assignment, and phase timing has good applicability. [ABSTRACT FROM AUTHOR]

• Lignin-based surfactants LC and LCQ with various isoelectric points were synthesized. • The effect and mechanism of the pI of LCQ on the enzymatic hydrolysis were studied. • The SED of Eu-SPORL increased from 35.2% to 95.3% by adding LCQ-40. • LCQ could be efficiently recovered for the excellent pH-response performance. The isoelectric point (pI) of lignin-based surfactant is an important factor in the enhancement on the enzymatic hydrolysis of lignocellulose. In this work, lignin carboxylate (LC) and quaternary ammonium lignin carboxylates (LCQ-x, x%: the mass ratio of quaternizing agent to enzymatic hydrolysis lignin) with different isoelectric points were synthesized. LC or LCQ-x with pI significantly lower or higher than 4.8 reduced the non-productive adsorption of cellulase on lignin, but for the significant inhibitory effect on cellulase activity, their enhancements on the enzymatic hydrolysis of lignocellulose were not remarkable. However, LCQ-x with pI around 4.8 preserved the cellulase activity, and significantly reduced the non-productive adsorption of cellulase, therefore remarkably enhanced the enzymatic hydrolysis. 2 g/L LC, LCQ-40 (pI = 5.0) and LCQ-100 (pI = 9.2) increased the enzymatic digestibility of pretreated eucalyptus from 35.2% to 53.4%, 95.3% and 60.4% respectively. In addition, for the excellent pH-response performance, LCQ could be efficiently recovered after enzymatic saccharification. [ABSTRACT FROM AUTHOR]

In order to enhance the enzymatic hydrolysis of lignocelluloses and recycle surfactants after enzymatic hydrolysis, a pH-responsive lignin amphoteric surfactant (SLQA) was prepared by the quaternization of sulfonated lignin (SL). Compared with SL, SLQA could much more effectively enhance the enzymatic hydrolysis of lignocelluloses. With an increase in the quaternization degree, enhancement of the enzymatic hydrolysis of lignocelluloses by the SLQA gradually increased. Adding 2 g L−1 SLQA-80 (mass radio of quaternizing agent to SL was 80%) could increase the enzymatic digestibility of pretreated eucalyptus and corncob residues (CCR) from 36.7% and 37.8% to 84.3% and 90.5%, respectively. The adsorption of SLQA on lignin film was larger than that of SL, and the lignin film became more hydrophilic after adsorbing SLQA. Thus, SLQA could cause more effective steric hindrance and form a hydration layer to reduce the non-productive adsorption of cellulase on lignin. The purified SLQA-80 exhibited sensitive pH-responsive property, and 90.8% of SLQA-80 could be recycled by adjusting the pH of hydrolysate after enzymatic hydrolysis. Adding recyclable SLQA could not only obviously enhance the enzymatic hydrolysis of lignocelluloses, but could also enable the comprehensive utilization of lignocelluloses. This method is of great significance to reducing the cost of cellulosic ethanol. [ABSTRACT FROM AUTHOR]

The growth of ride-hailing services has made people's daily commutes more convenient but has increased traffic on the road. However, the data needed to verify the impact of ride-hailing services on the urban road traffic network are lacking. This study matches data on the trajectories of different kinds of vehicles in Xuancheng city in the urban road network by using vehicle information data, ride-hailing information data, and license plate data recorded by the traffic bayonet system from December 26, 2018, to January 25, 2019. We used two indices, the detecting intensity and the detecting rate, to analyze the characteristics of travel based on ride-hailing services in Xuancheng. The results show that the ride-hailing vehicles have obvious travel characteristics of morning peak and evening peak, and in central urban areas and through the proposed indices of the travel time occupation rate and the travel space occupation rate to further quantitatively analyze the spatial and temporal characteristics of travel of different kinds of vehicles. Following this, we calculated the average ratios of different kinds of vehicles on congested sections of the road network and used simple regression to analyze the relationship between this and the average speed on these sections to quantitatively analyze the impact of ride-hailing on traffic congestion. The work here can provide effective decision-making support to the government for managing travel based on ride-hailing services. [ABSTRACT FROM AUTHOR]

The conversion of lignocelluloses into fermentable sugars by enzymatic hydrolysis is a key step in biorefining. However, there are still some bottleneck problems such as low hydrolysis efficiency, high cost of cellulase and low utilization of lignin. In this work, the nonionic surfactant monomethoxy polyethylene glycol (MPEG) was grafted on enzymatic hydrolysis lignin (EHL) to obtain a pH-responsive polymer (EHL-MPEG). EHL-MPEG could achieve rapid dissolution–precipitation conversion by the ionization and protonation of carboxyl groups. By adjusting the grafting amount of MPEG, EHL-MPEG could not only enhance the enzymatic hydrolysis of lignocelluloses, but also efficiently recover cellulase after hydrolysis. Adding 3 g L−1 EHL-MPEG40 (the mass ratio of MPEG to EHL was 40%) could increase the glucose yield of corncob residue (CCR) and pretreated eucalyptus from 79.4% and 48.3% to 92.5% and 89.5%, respectively, which was comparable to the effect of the nonionic surfactant PEG4600. By simply adjusting the pH of solutions, more than 85% of cellulase proteins could be recovered by EHL-MPEG40 with almost complete recovery of β-glycosidase, exoglucanase V and xylanase. Compared with a pH-responsive lignin amphoteric surfactant (pH-LAS) obtained by grafting ionic groups on lignin, EHL-MPEG40 had a more sensitive pH response and a stronger cellulase recovery ability. In the enzymatic hydrolysis of CCR, a pH-LAS could save about 50% of cellulase, while EHL-MPEG40 could save more than 60% of cellulase. Furthermore, approximately 96% of EHL-MPEG40 could be reused. This new method can not only evade the process of immobilization, but also avoid the activity loss and component change of cellulase through immobilization. Using recyclable EHL-MPEG to improve glucose yield and recover cellulase during lignocellulosic hydrolysis is of great significance for improving the enzymatic saccharification process, reducing the cost of cellulase and realizing comprehensive utilization of lignocelluloses. [ABSTRACT FROM AUTHOR]

Some zwitterionic surfactants exhibit upper critical solution temperature (UCST) in aqueous solutions. For the zwitterionic surfactant solution mixed with cellulase, when its temperature is below UCST, the cellulase can be recovered by coprecipitation with zwitterionic surfactant. In this work, 3-(Hexadecyldimethylammonio) propanesulfonate (SB3-16) was selected to enhance the enzymatic hydrolysis of lignocelluloses and recover the cellulase. After adding 2 mmol/L of SB3-16, the enzymatic digestibility of eucalyptus pretreated by dilute acid (Eu-DA) and by sulfite (Eu-SPORL) increased from 27.9% and 35.1% to 72.6% and 89.7%, respectively. The results showed that SB3-16 could reduce the non-productive adsorption of cellulase on hydrophobic interface, while it did not significantly inhibit the activity of cellulase. For the solution contained 1 wt% SB3-16 and 200 mg protein/L CTec2 cellulase, 55.2% of protein could be recovered by cooling. The filter paper activity of the recovered cellulase was 1.93 FPU/mg protein, which was 95.8% of its initial activity. [ABSTRACT FROM AUTHOR]

In order to evaluate the homogeneity of asphalt mixture quantitatively, the distribution characteristic of internal phases of asphalt mixture were identified based on digital image processing technique and stereology theory, and the homogeneity coefficient (i.e., K) was proposed. At the same time, the trend of variation and reliability of homogeneity of asphalt mixture were analyzed by changing the nominal maximum aggregate size, aggregate gradation and asphalt content. The results suggest that the homogeneity of asphalt mixture could be comprehensively described using DIP technique combined with stereology theory. The smaller the K, the better the distribution homogeneity of the asphalt mixture. An improvement in the homogeneity of an asphalt mixture is achieved with the decrease of the nominal maximum aggregate size and a finer aggregate gradation. The asphalt content corresponding to the optimal homogeneity of the internal structure of asphalt mixture specimen is the optimum asphalt content. According to the experimental study, the suggested values of the homogeneity coefficient were given, which provides theoretical support to control the construction quality of the hot mixture asphalt. [ABSTRACT FROM AUTHOR]

Polyvinylpyrrolidone (PVP) is an antifouling polymer to resist the adsorption of protein on solid surface. Effects of PVP on the enzymatic hydrolysis of pretreated lignocelluloses and its mechanism were studied. Adding 1 g/L of PVP8000, the enzymatic digestibility of eucalyptus pretreated by dilute acid (Eu-DA) was increased from 28.9% to 73.4%, which is stronger than the classic additives, such as PEG, Tween and bovine serum albumin. Compared with PEG4600, the adsorption of PVP8000 on lignin was larger, and the adsorption layer was more stable and hydrophilic. Therefore, PVP8000 reduced 73.1% of the cellulase non-productive adsorption on lignin and enhanced the enzymatic hydrolysis of lignocelluloses greatly. [ABSTRACT FROM AUTHOR]