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Rationale: Compound‐specific stable isotope analysis of hydrogen (δD) and carbon (δ13C) in organic compounds is a valuable tool in biogeochemical research. A key limitation of this method is the relatively large amount of sample required to achieve desirable precision. Methods: We developed a large‐volume (20 μL) injection method that allows for high throughput analysis of less concentrated samples and tested it for δ13C and δD measurements of n‐alkanes. We also conducted a comparison of reference standards and assessed several methods to normalize and correct n‐alkane δD and δ13C measurements. Results: The mean precision of the δD method based on 233 environmental n‐alkane samples (two to three replications per sample) is 4.0‰ (1σ, estimated from the weighted mean of the pooled unbiased standard deviations) and 0.46‰ (1σ) for δ13C from 37 environmental samples (two to three replications per sample). The evaluation of reference standards shows that the use of n‐alkane standards with large offsets in δD values in adjacent n‐alkane chains can lead to biases in measurement correction. Conclusions: The large‐volume injection method shows good reproducibility of δ13C and δD measurements of n‐alkanes and reduces the required sample concentration by about 80%. We propose that for δD measurements, a reference standard set should be used in which each reference standard has a limited range of δD values and no adjacent n‐alkane chains, to minimize memory effects. [ABSTRACT FROM AUTHOR]

Paleoclimate data provide important information about the character of natural climate variability. However, records with sufficient length and resolution to resolve high‐frequency (decadal‐scale) variability across the Holocene are scarce. We present a 10,800‐year reconstruction of spring and summer temperature at three‐year resolution based on biochemical varves from Lake Żabińskie, Poland. The reconstruction is based on Ca/Ti ratio, which are significantly correlated with instrumental spring and summer temperature spanning 240 years. Major climate events of the Holocene period are represented in the reconstruction, including the Holocene Thermal Maximum, 8.2 ka Event, Medieval Climate Anomaly, and Little Ice Age. A low‐frequency 8,000‐year decreasing trend in warm‐season temperatures is driven by declining summer insolation. Temperature variability is highest during the early Holocene, likely related to warmer and drier conditions. The rate of warming during the past 90 years is extremely unusual, if not unprecedented for the Holocene, based on our reconstruction. Plain Language Summary: Studying past climate change helps us understand how the climate system works. One aspect of past climate that is not well understood is how much temperatures changed from year to year and over decades during warm periods of Earth's history. In this study, we measured chemical properties of lake sediments from Poland and found that chemical changes were related to spring and summer temperature changes. We used this data to estimate spring and summer temperatures during the past 10,800 years. Relatively warm summers occurred around 9,000–7,500 years ago, a period known from other studies to be relatively warm in the northern hemisphere. We also found greater variability in temperatures during this warm period. Our long record of spring and summer temperatures shows that the warming rate of the past 90 years is most likely faster than any time during the past 10,800 years, showing that human‐caused global warming is more extreme than natural climate variations. Key Points: 10,800‐year‐long, 3‐year‐resolution, warm‐season temperature reconstruction from biochemical varves from Lake Żabińskie, PolandPeak summer temperatures occurred during the early Holocene with declining summer insolation driving cooling during the past 8,000 yearsThe rate of modern warming is highly unusual, at least 4 standard deviations above the mean temperature trend of the past 10,800 years [ABSTRACT FROM AUTHOR]

Eutrophication and anoxia are increasing in lakes worldwide. However, our understanding of variations of primary productivity and anoxia in lakes over thousands of years is limited. Long-term records are needed to understand the natural variability of lake ecosystems and to improve our understanding of drivers of productivity and anoxia. In this study, we used the varved sediment record of Lake Żabińskie, Poland to answer the following research questions: 1) How have primary production and water column oxygen concentrations varied during the past 10,800 years?; 2) what role did natural and anthropogenic forces have in driving changes in primary production or lake mixing regime? Recently developed hyperspectral imaging (HSI) techniques were used to quantify sedimentary chloropigments- a and bacteriopheopigments- a (Bphe- a) at sub-annual resolution. These data, combined with elemental data from micro X-ray fluorescence (μ-XRF) and pigment assemblage data from high-performance liquid chromatography (HPLC) measurements, were used to reconstruct paleolimnological conditions. Bphe- a was used as an indicator of anoxia, and its presence suggests that an extensive anoxic zone was present nearly continuously from 10.8 to 2.8 ka BP. Anoxic conditions, driven by thermal stratification, were promoted by closed forest cover during that time, which limited wind-driven mixing of the water column. After 2.8 ka BP, water column oxygenation occurred more frequently, particularly during periods of increased human agricultural activity and forest opening. Pronounced anoxia was again present continuously from ~610 to 1470 CE, concurrent with a period of reforestation. After ~1610 CE, deforestation caused increases in erosion rates, algal production, and water column oxygenation. Pigment assemblages indicate that the algal community during the past 150 years was different from any other time during the Holocene. This study demonstrates a clear link between lake biogeochemical processes and forest cover and shows the potential of HSI to produce extremely high-resolution records of past productivity and redox conditions from varved lake sediments. Unlabelled Image • Aquatic productivity and anoxia were inferred from a 10,800-year sediment core. • Sedimentary pigments were quantified using hyperspectral imaging (HSI). • Anoxia was persistent during the Holocene prior to human-mediated deforestation. • HSI on varves enables sub-annual reconstruction of past productivity and anoxia. [ABSTRACT FROM AUTHOR]

Although rare, temporally and taxonomically highly-resolved palaeoecological studies with high chronological precision are essential to perform detailed comparisons with precisely dated independent evidence such as archaeological findings, historical events, or palaeoclimatic data. Using a new highly-resolved and chronologically precise sedimentary record from Lago di Mezzano (central Italy), we reconstruct decadal-scale vegetation, species diversity, and fire dynamics, aiming to better understand the linkages between climate, land use, fire, and plant communities from the Neolithic to the Copper Age (c. 5100–3100 cal. BC). Closed, mixed beech-oak forests, including evergreen Quercus ilex, dominated the landscape around Lago di Mezzano during the Neolithic and were disturbed by repeated opening phases, with important implications for lake biogeochemistry and mixing regimes. This was in conjunction with increasing fire activity to promote agro-pastoral practices, as inferred from increasing charcoal, Cerealia type, Triticum type, Hordeum type, Plantago lanceolata type, and Urtica pollen. Fires, on their turn, augmented species diversity (richness and evenness). The comparison of the Mediterranean record from Lago di Mezzano with available continuous and high-precision submediterranean and cool-temperate palynological sequences suggests comparable land use pulses across Southern and Central European regions, most likely in connection with climate change. The outcomes of this study are not only of palaeoecological and archaeological interest; they may also help to improve projections of ecosystem dynamics under future global change. [ABSTRACT FROM AUTHOR]

Around 200,000 yr ago, Homo sapiens emerged in Africa. By 40 ka, Homo sapiens had spread throughout Eurasia, and a major competing species, the Neanderthals, became extinct. The factors that drove our species "out of Africa" remain a topic of vigorous debate. Existing research invokes climate change as either providing opportunities or imposing limits on human migration. Yet the paleoclimate history of northeast Africa, the gateway to migration, is unknown. Here, we reconstruct temperature and aridity in the Horn of Africa region spanning the past 200,000 yr. Our data suggest that warm and wet conditions from 120,000 to 90,000 yr ago could have facilitated early waves of human migration toward the Levant and Arabia, as supported by fossil and lithic evidence. However, the primary out-of-Africa event, as constrained by genetic studies (ca. 65-55 ka), occurred during a cold and dry time. This complicates the climatemigration relationship, suggesting that both "push" and "pull" factors may have prompted Homo sapiens to colonize Eurasia. [ABSTRACT FROM AUTHOR]

Mesomediterranean vegetation with abundant evergreen broadleaved trees and shrubs is dominant along the coast of northern Greece. Well-dated palynological records are available from the inland submediterranean zone, where evergreen broadleaved trees and shrubs are absent or rare, but less is known about the vegetation history of the coastal area. For instance, it is unclear when and why evergreen broadleaved vegetation expanded during the Holocene. Here we present a new record from a mesomediterranean site, Limni Volvi, near the coast of the Aegean Sea. To understand Holocene vegetation history, we combined palynology, microscopic charcoal analysis and biogeochemical proxies (Ti, Ca, RABD655–680max). At the start of the Holocene, open steppe vegetation and high fire activity prevailed around Limni Volvi. Afforestation by deciduous trees was likely delayed compared to sites further inland, due to the lack of moisture at the start of the Holocene, but vegetation composition was generally similar (i.e. submediterranean), with barely any evergreen broadleaved element. Around 8150 cal. BP (6200 cal. BC) trees and shrubs declined in the open woodlands or parklands, and the landscape returned to steppe conditions at 8000 cal. BP (6050 cal. BC), likely because of drier and colder conditions during the “8.2 ka event.” Around the same time, cultural indicators suggest the start of Neolithic agriculture in the region. The present-day mesomediterranean vegetation with evergreen oaks only began to develop after 6000–5000 cal. BP (4050–3050 cal. BC), likely in response to increasing winter temperatures and reduced frost occurrence, further advantaged by human impact during the past 3600 years. [ABSTRACT FROM AUTHOR]

Human activity has fundamentally altered the global phosphorus (P) cycle. Yet our understanding of when and how humans influenced the P cycle has been limited by the scarcity of long-term P sequestration records, particularly outside Europe and North America. Lake sediments provide a unique archive of past P burial rates and allow the human-mediated disruption of the global P cycle to be examined. We compiled the first global-scale and continentally resolved reconstruction of lake-wide Holocene P burial rates using 108 lakes from around the world. In Europe, lake P burial rates started to increase noticeably after ∼4000 calendar years before 1950 CE (cal BP), whereas the increase occurred later in China (∼2000 cal BP) and in North America (∼550 cal BP), which is most likely related to different histories of population growth, land-use and associated soil erosion intensities. Anthropogenic soil erosion explains ∼86% of the observed changes in global lake P burial rates in pre-industrial times. We also provide the first long-term estimates of the global lake P sink over the Holocene (∼2686 Tg P). We estimate that the global mean lake sediment P sequestration since 1850 CE (100 cal BP) is ∼1.54 Tg P yr−1, representing approximately a six-fold increase above the mean pre-industrial value (∼0.24 Tg P yr−1; 11,500 to 100 cal BP) and around a ten-fold increase above the Early-Middle Holocene low-disturbance baseline of 0.16 Tg P yr−1. This study suggests that human activities have been affecting the global P cycle for millennia, with substantial alteration after industrial times (1850 CE). • We estimated Holocene phosphorus (P) burial rates in sediments of 108 global lakes. • Global lake P burial rates increased notably in the Late Holocene. • Human-induced soil erosion caused early increases in lake sediment P burial rates. • We observed different patterns of lake P burial rates among continents since the Late Holocene. • We provide the first estimates of long-term, global P sequestration in lake sediments throughout the Holocene. [ABSTRACT FROM AUTHOR]

New records of paleoenvironmental change from two lakes near Cordova, south central Alaska, combined with analysis of previously reported sediment sequences from the adjacent Copper River Delta, provide quantitative constraints on a range of Earth system processes through their expression in relative sea-level change. Basal sediment ages from Upper Whitshed Lake indicate ice-free conditions by at least 14,140-15,040 cal yr BP. While Upper and Lower Whitshed Lakes provide only upper limits to relative sea-level change, interbedded layers of freshwater peat and intertidal silt extending more than 11 m below present sea level in Copper River Delta indicate net submergence over the last 6000 years and multiple earthquake deformation cycles. In contrast, Lower Whitshed Lake, situated just above present high tide level, records only one episode of marine sedimentation, commencing AD 1120-1500, that we interpret as the result of isostatic subsidence due to Little Ice Age mass accumulation of the Chugach Mountain glaciers. Lower Whitshed Lake also records isostatic uplift at the end of the Little Ice Age before the end of marine sedimentation caused by ~1.5 m coseismic uplift in the great Alaska earthquake of AD 1964. We successfully explain the records of relative sea-level change from both Copper River Delta and the Whitshed Lakes by integrating the effects of eustatic sea-level rise, glacial isostasy, earthquake deformation cycles, sediment loading, sediment compaction and Late Holocene changes in glacier mass into a single model. This approach provides initial quantitative constraints on the individual contributions of these processes. Taking reasonable estimates of eustasy, post-Last Glacial Maximum and Neoglacial glacial isostatic adjustment and a simple earthquake deformation cycle, we demonstrate that sediment loading and sediment compaction are both contributors to relative sea-level rise at Copper River Delta, together producing subsidence averaging approximately 1.2 mm yr-1 over the mid to Late Holocene. Further isolation basin studies have the potential to greatly improve our understanding of the individual contributions of these processes in this highly dynamic region. [ABSTRACT FROM AUTHOR]

The middle to late Holocene (8,200 years ago to present) in the Arctic is characterized by cooling temperatures and the regrowth and advance of glaciers. Whether this Neoglaciation was a threshold response to linear cooling, or was driven by a regional or Arctic‐wide acceleration of cooling, is unknown. Here we examine the largest‐yet‐compiled multiproxy database of Arctic Holocene temperature change, along with model simulations, to investigate regional and Arctic‐wide increases in cooling rate, the synchronicity of Neoglacial onset, and the observed and simulated rates of temperature change. We find little support for an Arctic‐wide onset of Neoglacial cooling but do find intervals when regions experienced rapid increases in long‐term cooling rate, both in the observations and in climate model simulations. In the model experiments, Neoglacial cooling is associated with indirectly forced millennial‐scale variability in meridional heat transport superposed on the long‐term decline of summer insolation. Plain Language Summary: Arctic summer temperatures have decreased for the past 8,000 years, before rapidly warming over the past century. As temperatures cooled, glaciers that had melted began to regrow throughout the Arctic, a phenomenon and a time interval known as Neoglaciation. This study seeks to understand the nature of this cooling and whether or not this indicates a tipping point in the climate system. Specifically, we use a large database of records from ice cores, lakes, ocean sediment, and more paleoclimate archives to detect patterns of cooling. We investigate these patterns, and climate model simulations, to determine what parts of the Arctic experienced Neoglaciation at the same time, how rapidly it cooled, and what climate models indicate about the causes of cooling. We find that the Arctic did not cool simultaneously, but different regions cooled at different times and that the climate models perform well when simulating both the timing and amount of Arctic cooling. Key Points: The onset of Neoglaciation is regional and driven by nonlinear increases in regional coolingModel simulations suggest that cooling onsets are linked to Atlantic Meridional Overturning CirculationObserved and simulated rates of late Holocene cooling in the Arctic are remarkably similar [ABSTRACT FROM AUTHOR]