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1. Regioselective Iodoazidation of Alkynes: Synthesis of a,a-Diazidoketones.

Author

Noriko Okamoto, Takuya Sueda, Hideki Minami, Yoshihisa Miwa, and Reiko Yanada

Subjects
*REGIOSELECTIVITY (Chemistry), *ALKYNES, *CHEMICAL processes, *CHEMICAL reactions, *RING formation (Chemistry)
Abstract

Aryl alkyl alkynes reacted with N-iodosuccinimide (NIS) and trimethylsilyl azide (TMSN3), leading to a,a-diazidoketones via the regioselective addition of IN3 to alkynes. Huisgen cyclization of a,a-diazidoketones generated bis-triazole compounds. [ABSTRACT FROM AUTHOR]

Published
2015
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