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The world-renowned Miocene Clarkia paleolake in northern Idaho (USA) is closely associated with Columbia River Basalt Group volcanism. The flood basalt dammed a local drainage system to form the paleolake, which preserved a plant fossil Lagerstätte in its deposits. However, the precise age and temporal duration of the lake remain unsettled. We present the first unequivocal U-Pb zircon ages from interbedded volcanic ashes at the P-33 type location, constraining the deposition to 15.78 ± 0.039 Ma. Using micro-X-ray fluorescence and petrographic and spectral analyses, we establish the annual characteristics of laminations throughout the stratigraphic profile using the distribution of elemental ratios, mineral assemblages, and grain-size structures, as well as organic and fossil contents. Consequently, the ~7.5-m-thick varved deposit at the type location P-33 represents ~840 yr of deposition, coincident with the end of the main phase of Columbia River Basalt Group eruptions during the Miocene Climate Optimum. The timing and temporal resolution of the deposit offer a unique opportunity to study climate change in unprecedented detail during global warming associated with carbon-cycle perturbations. [ABSTRACT FROM AUTHOR]

Pedogenic carbonate is an invaluable archive for reconstructing continental paleoclimate and paleoecology. The δ13C of pedogenic carbonate (δ13Cc) has been widely used to document the rise and expansion of C4 plants over the Cenozoic. This application requires a fundamental presumption that in soil pores, soil-respired CO2 dominates over atmospheric CO2 during the formation of pedogenic carbonates. However, the decoupling between δ13Cc and δ13C of soil organic matter (δ13CSOM) have been observed, particularly in arid regions, suggesting that this presumption is not always valid. To evaluate the influence of atmospheric CO2 on soil δ13Cc, here we performed systematic δ13C analyses of paleosols across the Chinese Loess Plateau, with the sample ages spanning three intervals: the Holocene, the Late Pleistocene, and the mid-Pliocene warm period. Our paired δ13Cc and δ13CSOM data reveal broadly divergent trending patterns. Using a two-component CO2-mixing model, we show substantial incorporations of atmospheric CO2 (up to 60%) into soil pore space during carbonate precipitation. This result readily explains the enrichment of δ13Cc and its divergence from δ13CSOM. As a consequence, δ13C of pedogenic carbonates formed under semiarid and/ or arid conditions are largely driven by regional aridity through its control on soil CO2 composition, and thus cannot be used to evaluate the relative abundance of C3 versus C4 plants. Nonetheless, these carbonates can be applied for atmospheric CO2 reconstructions, even for periods with low CO2 levels. [ABSTRACT FROM AUTHOR]

The appearance of permanent El Niño--like conditions prior to 3 million years ago is founded on sea-surface temperature (SST) reconstructions that show invariant Pacific warm pool temperatures and negligible equatorial zonal temperature gradients. However, only a few SST records are available, and these are potentially compromised by changes in seawater chemistry, diagenesis, and calibration limitations. For this study, we establish new biomarker-SST records and show that the Pacific warm pool was ~4°C warmer 12 million years ago. Both the warm pool and cold tongue slowly cooled toward modern conditions while maintaining a zonal temperature gradient of ~3°C in the late Miocene, which increased during the Plio-Pleistocene. Our results contrast with previous temperature reconstructions that support the supposition of a permanent El Niño--like state. [ABSTRACT FROM AUTHOR]

The late Pliocene onset of major Northern Hemisphere glaciation (NHG) is one of the most important steps in the Cenozoic global cooling. Although most attempts have been focused on high-latitude climate feedbacks, no consensus has been reached in explaining the forcing mechanism of this dramatic climate change. Here we present a key low-latitude climate record, the high-resolution Asian monsoon precipitation variability for the past five million years, reconstructed from South China Sea sediments. Our results, with supporting evidence from other records, indicate signifi cant mid-Pliocene Asian monsoon intensification, preceding the initiation of NHG at ca. 2.7 Ma ago. This 1.4-million-year-long monsoon intensification probably enhanced monsoon-induced Asian continental erosion and chemical weathering and in the process left fingerprints in marine calcium isotopes. Furthermore, increased rock weathering and/or organic carbon burial probably lowered the contemporary atmospheric CO2 and may have triggered the NHG onset. [ABSTRACT FROM AUTHOR]

Contrary to our conclusions, Ravelo et al. argue that our TEX86-based sea surface temperature (SST) records do not conflict with the supposition of "permanent El Niño-like" conditions during the early Pliocene. We show that the way Ravelo et al. treat the existing temperature data perpetuates an inaccurate impression of cooler Pacific warm-pool SSTs and low [ABSTRACT FROM AUTHOR]

The Asian monsoon has long been argued to be a product of the Himalaya-Tibetan Plateau, and simulation experiments have confirmed the key role of the Himalaya-Tibetan Plateau in transforming regional atmospheric and oceanic circulations. However, temporal constraints on the strengthening of the Asian monsoon inferred from foraminifer isotopic and faunal data and terrestrial climatic and ecological records are inconsistent with each other, which has obscured the tectonic-climatic linkage. In particular, discriminating the post-middle Miocene global cooling from the monsoon upwelling cooling is critical, but poorly understood due to the lack of adequate constraints for monsoonal upwelling. Here we present new middle to late Miocene biomarker-based reconstructions of sea-surface temperature (SST) for the western Arabian Sea. Our new SSTs capture a long-term ocean cooling since ca. 14.8 Ma and a major drop in SST in the period 11-10 Ma after which the SSTs reached similar values as the Holocene. The new SST record is consistent with planktonic foraminifer, siliceous biota, and geochemical tracer studies, suggestive of ocean cooling and high productivity associated with monsoonal upwelling. The 11-10 Ma ocean cooling is not clearly expressed in other tropical oceans, indicating that the ocean cooling in the western Arabian Sea is not a simple reflection of global cooling. We interpret the 11-10 Ma ocean cooling as representing the establishment of monsoonal upwelling in the western Arabian Sea, triggered by strong cyclonic activities as a result of the Neogene outward expansion of the Himalaya-Tibetan Plateau. [ABSTRACT FROM AUTHOR]

The alkenone-pCO2 methodology has been used to reconstruct the partial pressure of ancient atmospheric carbon dioxide (pCO2) for the past 45 million years of Earth's history (Middle Eocene to Pleistocene epochs). The present long-term CO2 record is a composite of data from multiple ocean localities that express a wide range of oceanographic and algal growth conditions that potentially bias CO2 results. In this study, we present a pCO2 record spanning the past 40 million years from a single marine locality, Ocean Drilling Program Site 925 located in the western equatorial Atlantic Ocean. The trends and absolute values of our new CO2 record site are broadly consistent with previously published multi-site alkenone-CO2 results. However, new pCO2 estimates for the Middle Miocene are notably higher than published records, with average pCO2 concentrations in the range of 400-500 ppm. Our results are generally consistent with recent pCO2 estimates based on boron isotope-pH data and stomatal index records, and suggest that CO2 levels were highest during a period of global warmth associated with the Middle Miocene Climatic Optimum (17-14 million years ago, Ma), followed by a decline in CO2 during the Middle Miocene Climate Transition (approx. 14 Ma). Several relationships remain contrary to expectations. For example, benthic foraminiferal δ18O records suggest a period of deglaciation and/or high-latitude warming during the latest Oligocene (27-23 Ma) that, based on our results, occurred concurrently with a long-term decrease in CO2 levels. Additionally, a large positive δ18O excursion near the Oligocene-Miocene boundary (the Mi-1 event, approx. 23 Ma), assumed to represent a period of glacial advance and retreat on Antarctica, is difficult to explain by our CO2 record alone given what is known of Antarctic ice sheet history and the strong hysteresis of the East Antarctic Ice Sheet once it has grown to continental dimensions. We also demonstrate that in the Neogene with low CO2 levels, algal carbon concentrating mechanisms and spontaneous biocarbonate-CO2 conversions are likely to play a more important role in algal carbon fixation, which provides a potential bias to the alkenone-pCO2 method. [ABSTRACT FROM AUTHOR]

The modern Pacific Ocean hosts the largest oxygen-deficient zones (ODZs), where oxygen concentrations are so low that nitrate is used to respire organic matter. The history of the ODZs may offer key insights into ocean deoxygenation under future global warming. In a 12-My record from the southeastern Pacific, we observe a >10‰ increase in foraminifera-bound nitrogen isotopes (15N/14N) since the late Miocene (8 to 9 Mya), indicating large ODZs expansion. Coinciding with this change, we find a major increase in the nutrient content of the ocean, reconstructed from phosphorus and iron measurements of hydrothermal sediments at the same site. Whereas global warming studies cast seawater oxygen concentrations as mainly dependent on climate and ocean circulation, our findings indicate that modern ODZs are underpinned by historically high concentrations of seawater phosphate. [ABSTRACT FROM AUTHOR]

Cyclization in glycerol dibiphytanyl glycerol tetraethers (GDGTs) results in internal cyclopentane moieties which are believed to confer thermal stability to crenarchaeal membranes. While the average number of rings per GDGT lipid (ring index) is positively correlated with temperature in many temperate environments, poor correlations are often observed in geothermal environments, suggesting that additional parameters may influence GDGT core lipid composition in these systems. However, the physical and chemical parameters likely to influence GDGT cyclization which are often difficult to decouple in geothermal systems, making it challenging to assess their influence on lipid composition. In the present study, the influence of temperature (range 65-81°C), pH (range 3.0-5.0), and ionic strength (range 10.1-55.7 mM) on GDGT core lipid composition was examined in the hyperthermoacidophile Acidilobus sulfurireducens, a crenarchaeon originally isolated from a geothermal spring in Yellowstone National Park, Wyoming. When cultivated under defined laboratory conditions, the composition of individual and total GDGTs varied significantly with temperature and to a lesser extent with the pH of the growth medium. Ionic strength over the range of values tested did not influence GDGT composition. The GDGT core lipid ring index was positively correlated with temperature and negatively correlated with pH, suggesting that A. sulfurireducens responds to increasing temperature and acidity by increasing the number of cyclopentyl rings in GDGT core membrane lipids. [ABSTRACT FROM AUTHOR]