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The thermal durability of thermal barrier coating systems (TBCs) obtained using feedstock powders with different purity and phase content was investigated by thermal shock testing with different cycle times, including the effects on the sintering and phase transformation behaviors. Four 8 wt.% yttria-stabilized zirconia powders, with regular purity (TC1), high purity (TC2 and TC3), and without monoclinic phase (TC4), were employed to prepare the topcoat of TBC by atmospheric plasma spray on a NiCoCrAlY bondcoat deposited by high velocity oxy-fuel. The microstructure and phase stability of the topcoats affected the TBCs' lifetime in the short-term (1 h) and long-term (24 h) furnace cyclic test (FCT) at 1100 °C and jet engine thermal shock (JETS) test. In the short-term FCT and JETS tests, in which coatings are severely subjected to thermal stress, the TBCs' lifetime is most affected by the microstructure of the topcoat. The coating layer with the lowest monoclinic phase in the as-sprayed state showed the lowest phase-transformation characteristics in the isothermal oxidation test (1400 °C). These properties resulted in the best lifetime in the long-term FCT. Therefore, the coating material and evaluating methods of TBCs' life should be selected depending on the usage environment. [ABSTRACT FROM AUTHOR]

In this study, a high-entropy approach was employed to design a new single-phase A 2 B 2 O 7 oxide for thermal insulation applications. Multicomponent high-entropy oxides, containing up to seven different cations, were successfully synthesized in a single defective fluorite structure. We observed that the incorporation of the functional cation, Zn2+, effectively blocked the heat radiation phenomenon by reducing the photon mean free path, and further reduced the high-temperature thermal conductivity owing to the larger free carrier concentration originated from the large number of oxygen vacancies. Although a large concentration of Zn2+ caused a slight reduction in thermal expansion, this study suggests that functional cations can be easily incorporated; thus, expanding the material diversity beyond the typical doping levels to develop new thermal barrier materials. [ABSTRACT FROM AUTHOR]

The thermal durability of thermal barrier coatings (TBCs) obtained using feedstock powders with different purity and phase content was investigated by cyclic thermal testing, including the effects on the sintering and phase transformation behaviors. Three kinds of 8 wt.% yttria-stabilized zirconia, namely regular purity (8YSZ), high purity (HP), and no monoclinic phase (nMP), were employed to prepare top coats by atmospheric plasma spraying on a NiCoCrAlY bond coat using a high-velocity oxy-fuel system. Use of 8YSZ, HP, and nMP for plasma spraying affected the microstructure and lifetime of the TBC in furnace cyclic testing (FCT) at 1100 °C and the sintering rate during annealing at 1400 °C for 50, 100, 200, and 400 h. In FCT, the TBC formed from nMP showed the longest durability, while that formed from HP showed lifetime performance similar to that obtained with regular-purity 8YSZ. The TBC obtained with nMP also exhibited the lowest monoclinic phase transition rate, followed by those obtained using HP and 8YSZ. [ABSTRACT FROM AUTHOR]

In this study, we designed a thermal barrier coating (TBC) system—Yb 2 O 3 –Gd 2 O 3 –Y 2 O 3 co-stabilized ZrO 2 (YGYZ) coating—with a Lewis neutral B–SiO 2 layer applied on its surface via a sol–gel-based glassification process and investigated its long-term corrosion resistance under corrosive environments. The corrosion behavior of the B–SiO 2 -covered YGYZ coating was assessed after 20, 40, 80, 160, and 320 h exposure to a hot corrosive environment of Na 2 SO 4 + V 2 O 5 at 1100 °C. Results indicated that the B–SiO 2 layer effectively prevented the penetration of corrosive salts and formation of m -ZrO 2 phase in the coating layer as well as generated vertical cracks that could release the residual stress. Therefore, it is concluded that depositing a Lewis neutral B-SiO 2 layer on YGYZ coatings is highly beneficial for extending the lifetime of the TBCs. • Lewis neutral B–SiO 2 layer was coated on Yb 2 O 3 –Gd 2 O 3 –Y 2 O 3 co-stabilized ZrO 2. • B–SiO 2 -covered YGYZ coatings effectively blocked the penetration of corrosive salts. • With increasing exposure time, B–SiO 2 -covered YGYZ coating generate vertical cracks. • B–SiO 2 -covered YGYZ coatings have better thermal durability than existing systems. [ABSTRACT FROM AUTHOR]

Hot corrosion and CaO–MgO–Al 2 O 3 –SiO 2 (CMAS) resistance of thermal barrier coatings (TBCs) are required in an industrial gas turbine employed with impure fuels and high turbine inlet temperatures. Therefore, various TBC systems with different structural combinations were investigated in thermochemical aspects of hot corrosion and CMAS causing the degradation of TBCs. Four types of 8 wt% yttria-stabilized zirconia (8YSZ), namely dense microstructure (8YSZ), porous microstructure (C–8YSZ), no monoclinic phase (NoM–8YSZ), and low thermal conductivity (low-k), were employed to prepare topcoats using an atmospheric plasma spray on the two bondcoats coated by a vacuum plasma spray with feedstocks of NiCoCrAlY and NiCoCrAlY+Hf + Si. Hot corrosion components penetrated through the whole topcoat layer at 1000 °C however did not infiltrate to the bondcoat layers because of the thermally grown oxide layer formed between the topcoat and the bondcoat. In addition, the elements Hf and Si contained in the bondcoat composition suppressed diffusion of β phase aluminum. In the visual inspection after the hot corrosion at 1000 °C and CMAS test at 1250 °C, the TBC system with the NoM–YSZ topcoat layer showed a sound condition without failure unlike other TBCs, and no monoclinic phase after hot corrosion and the CMAS test, indicating that the phase stability plays a critical role in TBCs' lifetime in the hot corrosion and CMAS environments. • Superiority of Hf and Si elements in MCrAlY bondcoat was observed through hot corrosion test. • Conventional and advanced TBCs failed with a similar trend independent of chemicals and porosity. • low-k TBCs showed a negative dependency on both hot corrosion and CMAS • Phase stability of topcoat layer can also be proposed to have more life time under the environment of hot corrosion and CMAS. [ABSTRACT FROM AUTHOR]