Search

AbstractHerein, a high-sensitive electrochemical sensor based upon a multi-walled carbon nanotubes modified screen-printed carbon electrode (MWCNTs-SPCE) was constructed for the determination of isoliquiritigenin (ISL). The electrochemical properties of ISL on the MWCNTs-SPCE were investigated systematically and a fast and cost-effective method for the determination of ISL was successfully established. A clear irreversible oxidation peak of the ISL was observed at 0.3 V (versus Ag/AgCl) on the MWCNTs-SPCE. The oxidation of ISL on MWCNTs-SPCE was an adsorption reaction accompanied by diffusion. Using differential pulse voltammetry (DPV), we observed that the oxidation peak current of the ISL in phosphate buffer (pH 7) showed a linear relationship from 0.50 to 100 µg/mL and a detection limit of 0.10 µg/mL. This method displayed good repeatability and stability, as well as exhibited excellent selectivity for ISL. Also, we successfully applied the method to determine ISL in Chinese herbal medicine licorice. Validation of the analyses via spike assays showed a recovery rate ranging from 95.39 to 101.00%, which was consistent with high performance liquid chromatography (HPLC). [ABSTRACT FROM AUTHOR]

Defect engineering is extensively utilized in 2D memory devices due to its effectiveness in enhancing charge‐trapping ability. However, conventional defect modulation techniques usually introduce only single types of carrier traps and cannot reconfigure trap types and densities after device fabrication. Here, for the first time, electrical stimulation‐driven long‐range migration of Cu ions within CuInP2S6 (CIPS) films is demonstrated to simultaneously introduce both electron and hole traps and enable reconfigurable modulation of interfacial defect trapping. This process is referred to as “electrical stimulation‐induced defect engineering”. By integrating these defect traps and the dual‐gate coupling effect, the memory window‐to‐scan range (MW/S.R) ratio, which reflects the device's charge trapping ability, doubled and peaked at 78.1% at Vbg = ± 80 V. Additionally, the dual‐gate memory device based on the graphene/CIPS/h‐BN/WSe2 heterostructure exhibits a maximum on/off ratio reaching 107 for multi‐level storage states, integrating neuromorphic computing and logic operations within a single platform. With 81 storage states and paired‐pulse facilitation (PPF), it achieves ≈90% accuracy in reservoir computing (RC) simulations. These results highlight the potential of electrical stimulation‐induced defect engineering for next‐generation electronics. [ABSTRACT FROM AUTHOR]

O3-type NaTMO 2 (TM = transition metal) is highly anticipated as a cathode for sodium-ion batteries due to its high theoretical specific capacity and low cost. However, the irreversible phase transition during sodiation/desodiation and the Jahn-Teller effect induced by Mn3+ have hindered its steps towards industrialization. Herein, we propose a doping strategy to enhance the structural stability of O3-type NaNi 1/3 Fe 1/3 Mn 1/3 O 2 through Zr doping. On the one hand, the Na+ transport channels are broadened due to the enlarged layer spacing, which accelerates the kinetic processes. On the other hand, Zr doping maintains structural integrity, inhibiting the decay of the layered structure. As a result, the uniquely designed material NNFMZO-6000 exhibited a discharge specific capacity of 113.8 mAh g−1 at 1 C and a capacity retention of 67.54 % after 200 cycles. This work presents an effective modification method to optimize the properties of O3-type NaTMO 2 materials. [ABSTRACT FROM AUTHOR]

Leveraging xanthated cellulose nanofibers (XCNF) from a modified rayon process, this study explores their use as stabilizers in Pickering emulsion polymerization for nanocomposite production. XCNF was produced from softwood pulp through a xanthation process that utilized a reduced NaOH concentration of 8.5 %, lower than the typical rayon process, and was followed by mechanical defibrillation, resulting in fiber widths under 10 nm. Following the protective allylation of xanthate groups and hydrophobic modification, 1H NMR analysis was conducted, revealing a xanthation degree of 0.144. When stored at 4 °C, a 0.5 wt% XCNF dispersion gelled by the fifth day, as confirmed by visual and rheological assessments. UV and TEM analyses indicated xanthate detachment and nanofiber aggregation over time, respectively. The addition of a low-temperature initiator to the XCNF-stabilized styrene-water emulsion enabled polymerization, yielding nanofiber-encapsulated polystyrene latex. This led to transparent sheets upon thermal pressing, demonstrating the potential of XCNF in developing polymer nanocomposites. [Display omitted] • Xanthated cellulose nanofiber (XCNF) was prepared by modified rayon process. • The gelation behavior of XCNF aqueous dispersion was investigated. • Fresh XCNF acted as a stabilizer for Pickering emulsion system with styrene monomer. • Emulsion polymerization gave polystyrene spheres encapsulated by nanofibers. • Thermal pressing the polymerized products yielded transparent sheets. [ABSTRACT FROM AUTHOR]