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1. Trifluoromethylation of Alkenes by Visible Light Photoredox Catalysis.

Author

Naeem Iqbai, Sungkyu Choi, Eunjin Kim, and Eun Jin Cho

Subjects
*TRIFLUOROMETHYL compounds, *ALKENES, *HYDROCARBONS, *CATALYSIS, *STEREOCHEMISTRY
Abstract

A method for trifluoromethylation of alkenes has been developed employing visible light photoredox catalysis withCF3I, Ru(Phen)3Cl2, and DBU. This process works especially well for terminal alkenes to give alkenyl-CF3 products with only E-stereochemistry. The mild reaction conditions enable the trifluoromethylation of a range of alkenes that bear various functional groups. [ABSTRACT FROM AUTHOR]

Published
2012
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