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Amide bond synthesis is ranked as the second most important challenge in key green chemistry research areas identified by the ACS Green Chemistry Institute. While developing more sustainable amide bond forming reactions has been in focus, significantly less attention has been given to human toxicity and environmental aspects of the underlying amine and acid substrates and their corresponding coupled products, a potentially important contribution to the overall sustainability of the amide-bond-forming reactions. Here, we explore biocatalytic amide bond formation from a safer-and-more-sustainable-by-design perspective in which commercially available amines and acids as well as their corresponding amide products were evaluated in silico based on potential human toxicity and environmental fate and exposure. This in silico filtering resulted in a panel of 188 amine and 54 acid building blocks that could be classified as safe, referred to herein as "safechems". To enable couplings of safechems, we generated a panel of robust and promiscuous ancestral ATP-dependent amide bond synthetases (ABS) using McbA from Marinactinospora thermotolerans SCSIO 00652 as a template. Ancestral ABS enzymes exhibited complementary specificities in the coupling of a representative safechem subset of 17 amines and 16 acids while showing an increased thermostability of up to 20 °C compared to the extant biocatalyst. Finally, the pool of safechems and their corresponding amides were evaluated by USEtox (the UNEP-SETAC toxicity model), analysing not only the intrinsic properties of the compounds but evaluating their complete impact pathway including fate, exposure and effects. The amides were in general predicted as more toxic compared to the starting acids and amines through non-additive effects, emphasising that focusing on the toxicity of the building blocks alone is not sufficient to strive towards low human and ecotoxicity impact. Pursuing a safer and more sustainable by design perspective in the implementation of safechems did not prevent us from generating an array of novel products with potentially potent applications as exemplified here by enzymatic synthesis of substructures that are part of drug candidates for e.g. cancer treatment. [ABSTRACT FROM AUTHOR]

ABSTRACT A detailed mechanistic investigation of the Zn (II)‐catalyzed Csp–Csp2 (Sonogashira‐type) cross‐coupling reaction is reported herein, using the Density Functional Theory method. The present study unveiled an unconventional non‐redox mechanism for Zn‐catalyzed cross‐coupling reaction, where the oxidation state of Zn remains intact throughout the catalytic cycle. Our study further revealed the significant role of the base in controlling the feasibility of cross‐coupling reactions that are catalyzed by electron‐deficient metal centers. Our study indicates that K3PO4 acts as an ancillary ligand (Lewis base) for the electron‐deficient Zn (II) catalytic center rather than as a proton abstractor for the nucleophilic coupling partner (phenylacetylene) in this reaction. The active catalyst was identified to be a four‐coordinate bis‐DMEDA Zn (II) complex. The mechanism proceeds via the initial activation of the nucleophilic coupling partner (phenylacetylene), followed by the electrophilic coupling partner (organic halide) activation liberating the cross‐coupled product by a concerted nucleophilic substitution pathway. The turn‐over limiting step was identified to be the activation of the electrophilic coupling partner. The activation barrier obtained for the reaction, 31.0 kcal/mol concords well with experimental temperature requirements (125°C). The coordination by base is found to stabilize the rate‐determining intermediates and transition states involved in the reaction. The mechanistic insights gained from this study could aid in the rational design and development of sustainable cross‐coupling reactions using zinc as the catalyst. [ABSTRACT FROM AUTHOR]

As part of its move towards net zero, the chemical industry, over time, will transition away from fossil-based chemical feedstocks towards more sustainable, 'green' carbon—biomass, recycled waste and captured carbon dioxide. One gateway to transforming these feedstocks into the vital chemicals and fuels society relies on is via synthesis gas or 'syngas'—a gaseous mixture of chemical building blocks (H2, CO and CO2). While today the majority of syngas is produced via steam reforming of natural gas, commercially available technologies are enabling syngas production and transformation from sustainable feedstocks. The optimization of sustainable syngas technologies would not be possible without the integrated development of both catalyst and process technology and the associated skills in chemistry and chemical engineering. This paper covers three example technologies that are unlocking the role of syngas as a gateway to sustainable fuels and chemicals and highlights the innovative developments in catalyst and process design that have enabled their optimization and commercialization. This article is part of the discussion meeting issue 'Green carbon for the chemical industry of the future'. [ABSTRACT FROM AUTHOR]

Due to strict governmental regulations, manufacturers have increasingly focused on recovering end-of-life (EoL) products through disassembly lines, aiming to achieve economic benefits while addressing the environmental aspects of supply chain sustainability. Disassembly line balancing (DLB) has become a key challenge for enterprises seeking to perform environmentally conscious manufacturing as part of a closed-loop supply chain policy. Therefore, designing a sustainable closed-loop supply chain requires analyzing interrelated problems by focusing on strategic-, tactical-, and operational-level decisions simultaneously. This study introduces an integrated problem that addresses multi-manned DLB, lot sizing, and reverse supply chain (RSC) design problems. To mathematically represent the problem, a generic optimization model is developed to minimize overall costs, including station opening, inventory holding, shortage, transportation, and collection center/facility opening costs. This study addresses several research questions to explore the impact of distribution strategies (centralized and decentralized) on multi-manned DLB and lot size decisions within the context of reverse supply chain design. [ABSTRACT FROM AUTHOR]

Chitosan (Ch), a natural polysaccharide, is known for its biocompatibility, biodegradability, and various beneficial properties, including antioxidant and antibacterial activities. The objective of this study is to investigate the functionalization of zinc oxide (ZnO) with chitosan to develop a novel ZnO@Ch adduct for use in cosmetic formulations, specifically as a sun protection agent. The functionalization was achieved through ionotropic gelation, which enhanced the stability and reduced the photocatalytic activity of ZnO, thereby improving its safety profile for skin applications. FTIR spectroscopy confirmed the successful functionalization, while TGA and DSC characterized the thermal properties and stability. The Zeta potential and particle size analyses demonstrated improved stability of ZnO@Ch across various pH levels compared to uncoated ZnO. The structure of the obtained adduct was also confirmed by SEM analysis. The ZnO@Ch adduct exhibited enhanced stability at neutral and slightly alkaline pH values, reduced photocatalytic activity compared to pure ZnO, and had lower cytotoxicity in 3T3 cells compared to pure ZnO, particularly at higher concentrations. The ZnO@Ch adduct provided a higher Sun Protection Factor (SPF) and UVA Protection Factor (UVA-PF) than pure ZnO, indicating enhanced UV protection. The adduct's ability to provide higher SPF at lower ZnO concentrations offers economic and environmental benefits, aligning with sustainable product design principles. Future studies will focus on optimizing the formulation and testing the efficacy and safety at higher concentrations to fully realize its potential as a natural, eco-friendly sunscreen ingredient. [ABSTRACT FROM AUTHOR]

In the food packaging industry, ventilated corrugated paperboard boxes are crucial for sustainable transport of fresh products. While these boxes' ventilation holes advance air circulation, they also impact the material's compression or buckling strength. Variations in hole geometry and location affecting this strength are explored, considering the composite material, multi-layered structure. Traditional mechanical analyses, which often require simplifications, may not fully capture this complexity, leading to less accurate predictions of the paperboard's strength. To address these challenges, a machine learning (ML) approach was utilized, employing the Light Gradient Boosting Machine (LGBM) to develop a predictive model for the buckling strength of corrugated paperboard boxes with ventilation cutouts. This physics-informed ML model, trained on a compression dataset resulting from experimental tests for plates with a single cutout in three shapes and Finite Element Method (FEM) simulations for plates with various patterns of circular cutouts, provides highly accurate estimates of the plates' buckling strength. It achieved 91.7% accuracy on experimental data and 94.68% on FEM simulation data, showcasing its reliability. A new tool for predicting the buckling strength of corrugated paperboard is provided by this research, along with insights that can inform the design of more sustainable packaging solutions. Furthermore, the methodology and findings have broader applications, potentially benefiting sectors like aerospace and construction, where similar structural materials are used. • ML predicted compression strength of sustainable VCP plates with high efficiency. • Improved VCP design reduces package's material waste in distribution cycles. • Shape, size, location, & pattern of cutouts influence VCP plate buckling strength. • ML ranks factor importance, efficiently enhancing VCP box designs. • Findings apply to various scales and industries beyond packaging. [ABSTRACT FROM AUTHOR]

Despite the strong interest concerning the responsive façades, today there are still few built examples and few tools to assess their benefits due to the complex description of the phenomenon. Energy simulations should consider the interactions between a time-varying environment and an environment-dependent envelope, increasing the intricacy of the problem; moreover, these strong environment–envelope interlinkages increase the importance of the location and climate scenarios considered. The aim of this study is to provide a tool to easily model these phenomena in different geographical and climate contexts. For this purpose, an innovative interactive computational platform (ICP) was developed based on EnergyPlus as a simulation engine, Python as a simulation manager, and Grasshopper as a user interface. Thanks to a single user-friendly environment, the users can simply select the climate scenario, the location, the responsive technology, and its main properties to set and run the dynamic energy simulation. After an overview of the current state of the art, this study provides a description of the structure and workflow adopted for developing this platform and details regarding its functioning and input management. Finally, the platform was tested to run an evolutionary optimization of an electrochromic window control strategy in different climate scenarios. [ABSTRACT FROM AUTHOR]

Purpose: The credibility crisis of science is a growing topic of investigation. This study approaches the problem from the sustainability of the scholarly communication system by merging argumentation with information science. Design/methodology/approach: Coding and content analysis drawing from a well-established textual argumentative tradition; a novel non-textual approach to complex communication and, an overlooked definition of sustainable information, were applied to 34 research works. The retrieval was carried out using Inciteful, a tool exploring literature networks. Additional information, such as keywords, mapping to Sustainable Development Goals (SDGs) and citations were acquired through the OpenAlex API. Operationalisation of concepts from the theoretical framework underpinned the selection and analysis of documents. Findings: Scholars virtually involve peers, funding agencies, research councils, policymakers, experts, practitioners and representatives of the public in their formal written production. The described coalitions are occasional, while the needed ones are deep. Three forms of scholarly communication were found: traditional, dialogical and complex depending on the involved audiences. The sample tells us about the sustainability of the scientific communication system and the impact it may have on the public construction of imaginaries of science. Originality/value: This investigation frames scholars, their products and societies as intertwined dialogical entities constantly communicating and impacting each other. Direct and indirect forms of scholarly communications are addressed too, showing how poor sustainability in these processes may entail a failure to reach different layers of societies. [ABSTRACT FROM AUTHOR]

The challenge of implementing industrialized construction to achieve sustainable future-proof healthcare facilities is not only about construction methods themselves but also about how to shift design methodologies. COVID-19 has raised the attention of research and practices in using modular design and construction for healthcare facilities. However, the lifespan and functional differences between general and emergency healthcare facilities mean that their sustainable design requirements are not exactly the same. Drawing from 27 interviews and design review sessions with 19 international groups of experts, this research proposes a modular adaptable hospital design (MAHD) approach based on the Open Building Concept (OBC). This includes an evaluation framework composed of five design categories and 23 subcategories complemented with a set of design guidelines and it concludes by identifying a future implementation pathway. This research extends the implementation of OBC through theoretical contributions for modular and adaptable designs and practical guidelines for future design implementation. [ABSTRACT FROM AUTHOR]

The major challenge for the construction industry is to design and produce sustainable construction materials that are efficient in their performance and can be affordable for construction projects. The objective of this study is to determine the viability of incorporating waste products such as sugarcane bagasse ash (SCBA) to produce concrete with polypropylene (PP) fibers. SCBA is an industry waste that has certain pozzolanic properties, however, it shows limited mechanical properties when used as a cement replacement. To improve the mechanical and durability performance, metakaolin (15%) and PP fiber (0.5%, 1%, and 1.5%) were incorporated in the SCBA blend as a ternary additive. Some of the important characteristics explored include compressive strength, tensile strength, density, water absorption, acid resistance, and sorptivity. The study reveals that the incorporation of 15% metakaolin in the composite enhanced the compressive strength by 7%, 8.2%, and 9.1% for PP fiber additions of 0.5%, 1%, 1.5%, while the acid resistance enhanced by 4%, 6% and 8% relative to the control mix for the same value of pp fiber. Furthermore, cost evaluation confirms that the overall costs of concrete with 15% metakaolin and 5% SCBA were 12.2% less than the control concrete, thus making this option economically feasible. This research proves that the inclusion of SCBA, metakaolin, and PP fibers into the concrete mixture brings a sustainable approach that enhances mechanical properties and durability while assisting sugar manufacturing plants in the proper disposal of wastes. [ABSTRACT FROM AUTHOR]

High‐current‐density water electrolysis is considered a promising technology for industrial‐scale green hydrogen production, which is of significant value to energy decarbonization and numerous sustainable industrial applications. To date, substantial research advancements are achieved in catalyst design for laboratory‐based water electrolysis. While the designed catalysts demonstrate remarkable performance at laboratory‐based low current densities, they suffer from marked deteriorations in both activity and long‐term stability under industrial‐level high‐current‐density operations. To provide a timely assessment that helps bridge the gap between laboratory‐scale fundamental research and industrial‐scale practical water electrolysis technology, here the current advancements in various commercial water electrolyzers are first systematically analyzed, then the key parameters including work temperature, current density, lifetime of stacks, cell efficiency, and capital cost of stacks are critically evaluated. In addition, the impact of high current density on the electrocatalytic behavior of catalysts, including intrinsic activity, long‐term stability, and mass transfer, is discussed to advance the catalyst design. Therefore, by covering a range of critical issues from fundamental material design principles to industrial‐scale performance parameters, here the future research directions in the development of highly efficient and low‐cost catalysts are presented and a procedure for screening laboratory‐designed catalysts for industrial‐scale water electrolysis is outlined. [ABSTRACT FROM AUTHOR]

Green technology (GT) and the utilization of renewable energy (RE) are widely acknowledged as a catalyst for energy efficiency, economic growth, and a tool for combating environmental degradation. Although various studies have examined the ecological repercussions of these two improvements, they have primarily used traditional pollution indicators (namely, carbon emissions and ecological footprint) and ignored nations with the highest cleaner energy adoption. To bridge this gap, the present research seeks to analyze the relationship between GT, RE consumption, economic growth, trade, and load capacity factor in the top‐10 renewable economies. In addition to environmental pollution indicators, the study utilizes the load capacity factor as a novel proxy for environmental quality and investigates the load capacity curve hypothesis using the Cross‐sectional‐autoregressive distributed lag model from 1990 to 2021. According to the empirical findings, all explanatory variables have a significant long‐term effect on the load capacity. More precisely, GT and RE consumption contribute to the sustainability of the ecosystem, while trade increases the ecological deficit. Furthermore, the findings do not support the validity of the load capacity curve hypothesis, implying that the environmental restorative benefits of economic well‐being may not manifest in the latter stages of economic growth. Given these findings, policymakers in the top‐10 renewable economies should seize the environmental prospects offered by GT and RE and update trade and growth policies in a way that promotes biocapacity while simultaneously reducing the ecological footprint to reach the long‐term sustainable development goals (SDGs), particularly SDGs 7 and 13. [ABSTRACT FROM AUTHOR]

Advancing the energy‐intensive Haber–Bosch process faces significant challenges due to the intrinsic constraints of scaling relations in heterogeneous catalysis. Herein, we reported an approach of bending the "seesaw effect" to regulate the scaling relations over a tailored α‐Fe metallic material (α‐Fe‐110s), realizing highly efficient light‐driven thermal catalytic ammonia synthesis with a rate of 1260 μmol gcatalyst−1 h−1 without additional heating. Specifically, the thermal catalytic activity of α‐Fe‐110s was significantly enhanced by the novel stepped {110} surface, exhibiting a 3.8‐fold increase compared to the commercial fused‐iron catalyst with promoters at 350 °C. The photo‐induced hot electron transfer further accelerates the dinitrogen dissociation and hydrogenation simultaneously, effectively overcoming the limitation of scaling relation over identical sites. Consequently, the ammonia production rate of α‐Fe‐110s was further enhanced by 30 times at the same temperature with irradiation. This work designs an efficient and sustainable system for ammonia synthesis and provides a novel approach for regulating the scaling relations in heterogeneous catalysis. [ABSTRACT FROM AUTHOR]

In order to improve the low specific surface area and high recombinant light generation carriers of BiOBr, loading BiOBr onto suitable Metal Organic Frameworks (MOFs) is an effective strategy to unleash its efficient visible light response and intrinsic catalytic activity. In this study, using classic MOF CAU‐17 as a precursor, using a straightforward co‐precipitation technique, four BiOBr/CAU‐17 composites with distinct MOF contents values BCAU‐1, BCAU‐2, BC, AU‐3, and BCAU‐4 were created, and their photo‐catalytic characteristics were examined. The BCAU‐2 composite exhibited much higher photo‐catalytic degradation efficiency for Rhodamine B (RhB) and Tetracycline (TC) than the pristine materials, counter compositions, and early reported materials. XRD, SEM, TEM, XPS, and EDX results revealed the strong synergistic photo‐catalytic effect of BiOBr and CAU‐17. The photocatalytic degradation of TC was significantly enhanced by the BiOBr bimetal modification, with the 2 wt.% BiOBr/CAU‐17 nanocomposite achieving an 87.2 % degradation of TC and 82 % Total Organic Carbon (TOC) removal within 60 min. The high photo‐degradation efficiency of BCAU‐2 composite should be attributed to the efficient transfer of photo‐generated carriers at interfaces and the synergistic effect between BiOBr/CAU‐17. Furthermore, the experiments on the capture of the active species proved that the main active free radicals involved in the degradation of RhB and TC are attributed to the photo‐induced holes h+ and ⋅ O2− under visible light. The catalyst's efficacy is corroborated by the outcomes of photoluminescence spectroscopy and photo current response. This study offers a new understanding for the design of green synthesis schemes for photo‐catalytic dye degradation and removal of certain antibiotics from the aquatic environment. [ABSTRACT FROM AUTHOR]

Advancing the energy‐intensive Haber–Bosch process faces significant challenges due to the intrinsic constraints of scaling relations in heterogeneous catalysis. Herein, we reported an approach of bending the "seesaw effect" to regulate the scaling relations over a tailored α‐Fe metallic material (α‐Fe‐110s), realizing highly efficient light‐driven thermal catalytic ammonia synthesis with a rate of 1260 μmol gcatalyst−1 h−1 without additional heating. Specifically, the thermal catalytic activity of α‐Fe‐110s was significantly enhanced by the novel stepped {110} surface, exhibiting a 3.8‐fold increase compared to the commercial fused‐iron catalyst with promoters at 350 °C. The photo‐induced hot electron transfer further accelerates the dinitrogen dissociation and hydrogenation simultaneously, effectively overcoming the limitation of scaling relation over identical sites. Consequently, the ammonia production rate of α‐Fe‐110s was further enhanced by 30 times at the same temperature with irradiation. This work designs an efficient and sustainable system for ammonia synthesis and provides a novel approach for regulating the scaling relations in heterogeneous catalysis. [ABSTRACT FROM AUTHOR]

The article in the journal "Advanced Functional Materials" discusses the evolution and impact of reticular materials, such as metal-organic frameworks (MOFs), zeolite imidazolate frameworks (ZIFs), and covalent organic frameworks (COFs), in academic and industrial settings. It highlights the exponential growth in research interest and publications on reticular materials, with MOFs being the most explored subclass. The article also emphasizes the increasing industrial relevance of reticular materials, particularly in applications like sensing, water harvesting, gas storage, and separation. The text underscores the need for interdisciplinary collaborations and closer academia-industry partnerships to unlock the full technological potential of reticular materials to address societal challenges and generate societal benefits. [Extracted from the article]

To help ensure a prosperous future on Earth for coming generations, academia and industry need to transform the way they plan and carry out the synthesis of novel materials to make them more environmentally sustainable. In particular, the field of reticular materials, i.e., metal‐organic frameworks, zeolitic imidazolate frameworks, and covalent organic frameworks, has great potential to outperform other materials and revolutionize various fields of applications. This review highlights several key aspects from the choice of their starting materials, solvents and synthetic methodologies that fall under the umbrella of the Green Chemistry principles, and incorporates a Circular Economy perspective by providing relevant strategies such as reuse, regeneration, or recycling to maximize the value of the Earth's available resources. Moreover, it will shed light on the life cycle assessment results of selected reticular materials and consider how constraints imposed by Green Chemistry principles, life cycle assessment metrics, and circular patterns will shape the future rational sustainable design and discovery of reticular materials. [ABSTRACT FROM AUTHOR]

Despite advancements in sustainable apparel design, upcycling practices still face challenges limiting creativity and efficiency. This study develops a Modular Redesign System (MRS) using 3D digital technology to improve the upcycling process. The MRS was created with CLO3D and Aftereffects, producing ten redesign samples and demonstration videos. In-depth interviews with South Korean upcycling apparel designers were conducted to assess the system’s perceived effectiveness and explore key issues in upcycling design. The MRS involves four stages: Selection, Virtualisation, Virtual Ideation, and Construction and Fitting. Findings highlight the MRS’s ability to enhance ideation, reduce material waste, and save time and costs, offering practical solutions to current challenges in apparel redesign. The MRS also shows potential for mass customisation, serving as an effective communication tool for personalised upcycling services. This study bridges a gap in the literature by integrating 3D virtual simulation with modular design to advance sustainable and efficient upcycling practices. [ABSTRACT FROM AUTHOR]

Highlights Polypropylene composites with different contents of zinc‐ammonium salts (3, 5 and 7 wt%) and nanocellulose (1 wt%) after enzymatic bioconversion were characterized by structural, dispersion‐morphological, thermal, antimicrobial and mechanical analysis. It was shown that the use of a newly synthesized salt significantly affected the formation of the supermolecular structure of the polymer matrix and increased the nucleation activity, thermostability and flexibility of the composite materials. Moreover, the addition of the inorganic filler allowed to obtain composites with very good antimicrobial properties against Staphylococcus aureus, Escherichia coli and Candida albicans. An interesting relationship between the degree of filler dispersion in the polymer matrix and the formation of polymorphic varieties was elucidated in the study, which contributes to the improvement of final performance characteristics of composite materials. It is noteworthy that a hybrid filler in the form of nanometric cellulose and a biocidal additive containing zinc‐ammonium complex salt was used for the first time. Research has shown that such polymer composites can find application during the manufacture of smart packaging materials with enhanced barrier properties against oxygen and water vapor as well as improved biocidal characteristics, which will notably extend food storage time. At the same time, the presented process of obtaining the innovative composite materials is an excellent example of sustainable technologies for the design of antimicrobial treatments, while guaranteeing the possibility of further processing of these composite materials through material recycling. Zinc‐ammonium complex with antimicrobial properties was obtained The strength properties and thermal stability of the composites were improved Degree of filler dispersion in polymer affects formation of polymorphic varieties The composites can be applied in the production of smart packaging materials [ABSTRACT FROM AUTHOR]

Herein we demonstrate the formation of new stimuli‐responsive aqueous biphasic systems (ABS), able to respond simultaneously to temperature and pH, or just to one stimulus, therefore allowing the design of more sustainable separation processes. This dual behavior is achieved with ABS formed by mono‐ or dicationic protic ionic liquids as phase‐forming components, being defined by the ionic liquid cation chemical structure or its basicity. While ABS comprising monocationic ionic liquids only respond to the effect of temperature, systems comprising dicationic ionic liquids are simultaneously affected by both temperature and pH variations. Dicationic ionic liquids are here identified as the key to unlock a double response to stimuli, which is due to the presence of two pKa values afforded by the cation. The reported findings contribute to increase the customizability of double stimuli‐responsive ABS based on ionic liquids, whose development was up to date limited to ionic liquids bearing pH‐responsive anions, opening the door towards the development of more sustainable separation processes. [ABSTRACT FROM AUTHOR]

The recent breakthroughs in heterogeneous catalysis emphasize the need for novel materials capable of driving organic transformations. The present study explores two copper phosphonate hybrid framework materials, 2D Cu3[(Hhedp)2(C4H4N2)].2H2O (Cu(II)Pyz‐P) and 3D Cu3[(H3hedp)2(C4H4N2)4(SO4)].2H2O (Cu(I/II)Pyz‐P), as single crystals isolated via hydrothermal synthetic strategy using H4hedp (1‐hydroxyethane 1,1‐diphosphonic acid) and N‐donor secondary ligand (Pyrazine; C4H4N2). Cu(II)Pyz‐P contains exclusively +2 oxidation state of copper, while Cu(I/II)Pyz‐P is characterized by a mixed oxidation state, where copper +2 phosphonate is embedded within the network formed by copper +1 state. Moreover, magnetic study elucidates the distinct oxidation states of both compounds by showing deviations from each other. The aforementioned compounds are exceedingly effective for catalyzing multicomponent reactions, that is, A3 coupling reaction and click reaction. Cu(I/II)Pyz‐P ensures the regioselective synthesis of triazole with high purity, while A3 coupling reaction is facilitated by both the compounds. Solvent‐ and additive‐free efficient multicomponent reactions are explored for the first time in the copper phosphonate hybrid framework structures. The present study reveals the promise of copper‐based hybrid phosphonate frameworks as durable and efficient catalysts for organic synthesis, providing cost‐effective and sustainable ways for advanced catalytic transformations. [ABSTRACT FROM AUTHOR]

This study investigates the impact of vertical greenery systems (VGSs) applied to several typical wall configurations on indoor thermal conditions in a building module situated in the Mediterranean climate of Catania, Italy. By means of dynamic simulations in TRNSYS vers.18, the research compares the thermal behavior of walls made of either hollow clay blocks (Poroton) or lava stone blocks against a lightweight wall setup already in place at the University of Catania. The primary focus is on evaluating the VGSs' capability of reducing peak inner surface temperatures and moderating heat flux fluctuations entering the building. The findings indicate that adding an outer vertical greenery layer to heavyweight walls can decrease the peak inner surface temperature by up to 1.0 °C compared to the same bare wall. However, the greenery's positive impact is less pronounced than in the case of the lightweight wall. This research underscores the potential of green facades in enhancing the indoor thermal environment in buildings in regions with climates like the Mediterranean one, providing valuable insights for sustainable building design and urban planning. [ABSTRACT FROM AUTHOR]

Lithium‐ion batteries (LIBs) are increasingly encouraged to enhance their environmental friendliness and safety while maintaining optimal energy density and cost‐effectiveness. Although various electrolytes using greener and safer glyme solvents have been reported, the low charge voltage (usually lower than 4.0 V vs Li/Li+) restricts the energy density of LIBs. Herein, tetraglyme, a less‐toxic, non‐volatile, and non‐flammable ether solvent, is exploited to build safer and greener LIBs. It is demonstrated that ether electrolytes, at a standard salt concentration (1 m), can be reversibly cycled to 4.5 V vs Li/Li+. Anchored with Boron‐rich cathode‐electrolyte interphase (CEI) and mitigated current collector corrosion, the LiNi0.8Mn0.1Co0.1O2 (NMC811) cathode delivers competitive cyclability versus commercial carbonate electrolytes when charged to 4.5 V. Synchrotron spectroscopic and imaging analyses show that the tetraglyme electrolyte can sufficiently suppress the overcharge behavior associated with the high‐voltage electrolyte decomposition, which is advantageous over previously reported glyme electrolytes. The new electrolyte also enables minimal transition metal dissolution and deposition. NMC811||hard carbon full cell delivers excellent cycling stability at C/3 with a high average Coulombic efficiency of 99.77%. This work reports an oxidation‐resilient tetraglyme electrolyte with record‐high 4.5 V stability and enlightens further applications of glyme solvents for sustainable LIBs by designing Boron‐rich interphases. [ABSTRACT FROM AUTHOR]

ABSTRACT This paper investigates the green design of rate‐splitting multiple access (RSMA) for multicell, multiantenna downlink communication systems to maximize rate fairness under quality of service (QoS) constraints. An optimization framework is developed to minimize the weighted sum power consumption by jointly optimizing transmit beamformers, power allocation, and common/private rate split while ensuring per‐user minimum rate requirements. The algorithm design explicitly considers the rate fairness among users via a newly proposed green fairness index. The nonconvex transceiver design problems are transformed into tractable forms and efficiently solved by applying tools from alternating optimization and successive convex approximation. Extensive simulations demonstrate that the proposed green RSMA optimization framework can effectively balance the throughput among cell‐edge and cell‐center users, hence combating the near‐far effect. Simulation results show that at 20‐dB SNR, green RSMA achieves over 20% and 50% sum rate improvement compared with NOMA and OMA, respectively. Moreover, green RSMA maintains high fairness among users, even when the channel conditions are disparate. When the weakest user is located 120 m from the base station, green RSMA exhibits a 21.2% higher fairness index than NOMA, showcasing its ability to ensure equitable service quality across users. The framework also achieves substantial energy efficiency gains, consuming less power while providing higher data rates than baseline schemes. These results demonstrate the effectiveness of green RSMA in enhancing spectral efficiency, user fairness, and energy efficiency in multicell, multiantenna communication systems, making it a promising solution for sustainable and high‐performance wireless networks. [ABSTRACT FROM AUTHOR]

Computational predictions of vaporization properties aid the de novo design of green chemicals, including clean alternative fuels, working fluids for efficient thermal energy recovery, and polymers that are easily degradable and recyclable. Here, we developed chemically explainable graph attention networks to predict five physical properties pertinent to performance in utilizing renewable energy: heat of vaporization (HoV), critical temperature, flash point, boiling point, and liquid heat capacity. The predictive model for HoV was trained using ∼150 000 data points, considering their uncertainties and temperature dependence. Next, this model was expanded to the other properties through transfer learning to overcome the limitations due to fewer data points (700–7500). The chemical interpretability of the model was then investigated, demonstrating that the model explains molecular structural effects on vaporization properties. Finally, the developed predictive models were applied to design chemicals that have desirable properties as efficient and green working fluids, fuels, and polymers, enabling fast and accurate screening before experiments. [ABSTRACT FROM AUTHOR]

An innovative approach was pursued for sustainable packaging design using Cycle Generative Adversarial Networks (CycleGANs), tailored for wood packaging engraving. The methodology includes four phases: user participatory design, assembly scheme design, detailed Finite Element Analysis (FEA) optimization, and computer numerical control (CNC) engraving production. Each phase targets sustainability from design to final product, minimizing environmental impact and economic costs. Emphasizing early user participation helps adapt designs to user needs and environmental standards. Innovations such as real-time updates of packaging patterns via cloud-based iterations and an FEA optimization system enhance durability and aesthetics. This approach improves the environmental footprint and recyclability of conventional wood packaging. The research aims to shift perceptions in the packaging industry towards more sustainable practices, showcasing the practical applications of advanced digital tools in traditional manufacturing. It offers a scalable model for integrating sustainability into packaging design, providing valuable insights and inspiring future innovations in environmentally friendly practices across the industry. [ABSTRACT FROM AUTHOR]

Understanding the dynamics of rocket plume impingement on flat surfaces is critical for designing effective and sustainable landing pads. The current near vacuum study measures the surface pressures and temperature profiles arising on a flat surface due to highly underexpanded, axisymmetric plume impingement. The experiments were conducted in a dedicated, large-volume plume-regolith facility situated at the University of Glasgow. A total of eight tests were conducted, comprising of both constant and pulsed firing modes. The impingement plate is located at stand-off distances equal to 4 and 16 times the nozzle exit diameters and plate inclinations of 0 ° and 30 °. Reduced stand-off distance increases impingement pressure, with a transient peak in the early stages of impingement indicating the presence of a primary shock wave. Higher stand-off distance resulted in decreased impingement pressure without an initial peak, but with a spike at the end of impingement once the nozzle had stopped firing. For inclined plates, the centerline impingement pressure magnitude decreased by around 40% compared with the 0 ° inclination. The measured pressures at lower stand-off height are then compared with the results of both a two-way coupled direct simulation Monte Carlo/Navier–Stokes–Fourier solver and an analytical theory. The results from all methods are in good agreement with each other, with the simulation and experimental centerline pressures being within 1% of each other. As the optical thickness of the gas is very low in the experimental case, the numerical method is used to generate a Schlieren image to analyze the shock structure. [ABSTRACT FROM AUTHOR]

The wettability of lubricant oil produces a velocity slip at the water–lubricant oil interface when the lubricant oil contacts the rectangular microgroove, leading to a reduction in the friction resistance at the boundary wall. However, lubricant oil is highly susceptible to changes in external shear force and can escape from the rectangular microgroove, degrading its slippery properties. This study investigated the influence of wettability and structure width on the stability and drag reduction performance of lubricant oil via simulation. The results indicated that lubricant oil stability is related to wettability and structural width. The lubricant oil remained stable at contact angles of 1° and 150° and a width of 0.4 mm. Based on slip velocity, the maximum drag reduction at a width of 0.6 mm in a turbulent environment was 13.4%. Our findings could provide valuable insights into surface design using lubricant oil, helping researchers avoid detrimental designs and enhance sustainable drag reduction performance. [ABSTRACT FROM AUTHOR]

Reactive power has gained acknowledgment as an ancillary service, indispensable for generators to ensure the dependable process of power systems. Moreover, it carries the potential to significantly enhance the effectiveness of delivering active power to consumers. Additionally, a strategic injection of reactive power at specific points holds the capability to alleviate transmission constraints, enabling cost-effective power distribution to heavily loaded regions. Given the inherent characteristics of reactive power provision, it necessitates efficient and dependable local procurement and management strategies. However, prevailing models fail to encompass the diverse dimensions of reactive power costs, leading to inefficiencies. Thus, an optimal resolution is imperative to rectify these complexities. This study introduces an innovative market mechanism for delivering reactive power ancillary services (RPAS), with a specific emphasis on its localized implementation. The proposed approach leverages the Sailfish Optimizer and is implemented on the General Algebraic Modeling System platform. The effectiveness of this novel mechanism is demonstrated through application to the IEEE 30-bus and PJM 5-bus systems, incorporating wind energy sources. The objective function takes into account the critical role of reactive power in maintaining bus voltage within acceptable limits and evaluates the availability of reactive power reserves within the system. The adoption of this utility function results in a noteworthy reduction in the total payment associated with RPAS, concurrently leading to an improvement in system-wide bus voltage and the preservation of necessary reactive power reserves across the network. [ABSTRACT FROM AUTHOR]

This study explores hydraulic rams, a technology that exploits the effect of water hammer to pump water without the need for external artificial energy. Although first developed in the 18th century, a comprehensive numerical model elucidating the dynamics of each element, including valve manoeuvres, remains absent. Few authors have contributed specific models, often relying on simplistic approaches like rigid water column theory, or the method of characteristics (MOC) for water hammer equations with either instantaneous valve manoeuvre boundary conditions, or depicting the hydraulic ram as a single-node boundary condition. Some use sophisticated computational fluid dyamics (CFD) based models, primarily for optimizing individual components like the waste valve. Addressing this gap, this work introduces a novel comprehensive numerical model detailing full system dynamic – pipes, junctions, and valve behaviour. Analytical validation and experimental verification, using original laboratory-scale data, affirm the model's reliability. This advance improves understanding of hydraulic ram performance and encourages innovative, environmentally sustainable designs. [ABSTRACT FROM AUTHOR]

This paper sets out to analyse the role of axiological variables — values, pro-environmental identity and moral obligation — in pro-environmental behaviours. To do this, we carried out two studies with a non-experimental cross-sectional design: the first on sustainable clothing consumption (n = 480; 70.6% women; Mage = 26.62, SD = 10.63) and the second on the adoption of a vegetarian lifestyle (n = 217; 73.5% women; Mage = 32.04, SD = 10.75). The data were collected in Spain by means of an online questionnaire using the snowball technique. In both studies, regression analysis showed that pro-environmental identity and moral obligation predict both sustainable clothing consumption and vegetarian lifestyle. Moral obligation is the main predictor of both pro-environmental behaviours. The axiological variables explain 53% of the variance for sustainable clothing consumption and 41% of the variance for a vegetarian lifestyle, highlighting that the axiological route is key to reversing our impact on the environment. [ABSTRACT FROM AUTHOR]

The leave-one-out (LOO) green fluorescent protein (GFP) approach to biosensor design combines computational protein design with split protein reconstitution. LOO-GFPs reversibly fold and gain fluorescence upon encountering the target peptide, which can be redefined by computational design of the LOO site. Such an approach can be used to create reusable biosensors for the early detection of emerging biological threats. Enlightening biophysical inferences for nine LOO-GFP biosensor libraries are presented, with target sequences from dengue, influenza, or HIV, replacing beta strands 7, 8, or 11. An initially low hit rate was traced to components of the energy function, manifesting in the over-rewarding of over-tight side chain packing. Also, screening by colony picking required a low library complexity, but designing a biosensor against a peptide of at least 12 residues requires a high-complexity library. This double-bind was solved using a "piecemeal" iterative design strategy. Also, designed LOO-GFPs fluoresced in the unbound state due to unwanted dimerization, but this was solved by fusing a fully functional prototype LOO-GFP to a fiber-forming protein, Drosophila ultrabithorax, creating a biosensor fiber. One influenza hemagglutinin biosensor is characterized here in detail, showing a shifted excitation/emission spectrum, a micromolar affinity for the target peptide, and an unexpected photo-switching ability. [ABSTRACT FROM AUTHOR]

The given document is an index of articles and book reviews published in Design Issues, a journal focused on design research and theory. The articles cover a wide range of topics, including design culture, technology, branding, graphic design, urban design, and more. The book reviews discuss publications on various design-related subjects. The index provides library patrons with a comprehensive list of articles and reviews, allowing them to easily locate and access specific resources for their research. [Extracted from the article]

Developing high‐activity non‐noble metal catalysts for improving the ability of water dissociation and H* adsorption/desorption in the hydrogen evolution reaction (HER) process in alkaline and neutral electrolytes is essential but remains challenging. Herein, a Mo‐doped NiCoCu alloy with tuned tensile strain and localized electrons is designed and synthesized by combining the solvothermal and annealing methods for achieving ampere‐level HER performance. Theoretical calculation results prove that Mo doping induces lattice tensile strain and localized electrons (electrons from Mo to the Ni/Co/Cu atoms), promoting the adsorption of O* and H* from H2O molecules on the Mo and Co sites and accelerating water dissociation. Therefore, NiCoCu‐Mo0.078/CF (CF = copper foam) shows low water dissociation energy, providing sufficient H* during the HER process. Meanwhile, its H* Gibbs free energy value is near zero, implying a rapid H* adsorption/desorption process. Electrochemical results show that NiCoCu‐Mo0.078/CF achieves better HER intrinsic activity in both a 1.0 m KOH (η−10/η−1000 = 35/212 mV) and a 1.0 m phosphate buffer solution (η−10/η−1000 = 24/256 mV) compared to NiCoCu‐Mo0/CF and NiCoCu‐Mo0.163/CF, and it can continuously operate for 100 h at −1000 mA cm−2. This work shows a sustainable way to design high‐performance catalysts for water electrolysis and proposes a well‐performing HER catalyst. [ABSTRACT FROM AUTHOR]

Sugarcane smut is the most important bottleneck in sugarcane production in Ethiopia. Previous management attempts couldn't protect the crop from smut sustainably. Therefore, experiments were conducted with the objective to assess the combined effect of varietal resistance, fungicide, and Trichoderma harzianum seed cane treatments on smut, cane, and sugar yields at Metehara and Wonji, Ethiopia. Thirty-six treatments were planted in a split plot design, with three varieties as main plots and twelve seed cane treatments as subplots in three replications. Consequently, untreated NCo-334 variety demonstrated greater smut intensity (incidence and severity), followed by untreated Mex 54-245 at Wonji in plant cane. Ratoon crops prevailed similar trends of infection except that Mex 54-245 treated with Apron, Triadimefon + Native Trichoderma harzianum (NT) and NT were unable to protect smut. Moreover, NCo-334 with all treatments at ratoon showed different levels of smut intensity at Wonji. On the other hand, greater mean smut intensity prevailed at Metehara than at Wonji. Overall, up to 30.75 and 29.80%, increase in cane and sugar yield respectively, could be achieved with seedcane treatments as compared to untreated control at the two locations. In general, the results of disease intensity, sugar yield, and economic analysis demonstrated that Opera and Opera + NT could be used as seedcane treatments after verification and demonstration for end users. The better protection against smut up to ratoon crop cycle, and economic return were the main reason to consider these treatments as candidates. [ABSTRACT FROM AUTHOR]

Herein, we have designed a greener and efficient microwave-assisted route for the synthesis of functionalized 2-arylbenzoxazoles, 2-arylbenzothiazoles, and 2-arylbenzimidazoles. These compounds were produced through the condensation reaction involving 2-aminophenol, 2-aminothiophenol, and 1,2-phenylenediamine, respectively, with corresponding aldehydes. Remarkably, this reaction was conducted employing waste curd water as a catalytic solvent and under the influence of microwave radiation. Curd water, a liquid byproduct obtained from the coagulation process during cheese or yogurt production, was harnessed as catalytic solvent for the reaction. The application of emerging microwave-assisted chemistry techniques in combination with greener reaction media dramatically reduces reaction time as well as chemical waste. This investigation not only demonstrates a waste-to-wealth paradigm but also contributes to the mitigation of environmental waste. [ABSTRACT FROM AUTHOR]

In order to study the effect of support on the antibacterial activity of ZnO nanoparticles formed in the bioinspired process, a series of palygorskite (Pal) supported ZnO nanocomposites (ZnO/Pal) were fabricated using licorice extract and the antibacterial actions related to the structure of loaded ZnO nanocomposites was elucidated. The samples were characterized by the means of UV–vis, XRD, TEM, FTIR, TG and XPS, and the antibacterial properties were determined by the agar disk diffusion assay and colony counting assay. The structural analysis revealed that pure ZnO nanoparticles with average grain diameter of about 11 nm were formed in the green bioinspired process and anchored on the surface of Pal nanorods. And with Pal amount decreasing (ZnO loading increased from 10 % to 40 %), the ZnO NPs aggregated intensify and promoted the assembling of ZnO/Pal nanorods into bigger clusters, and four kinds of ZnO/Pal with different morphologies were formed. Among them, 20 % loading of ZnO/Pal showed antibacterial activity comparable to that of 30 % and better than that of 40 %, because ZnO nanoparticles in 20 % ZnO/Pal are monodispersed on Pal nanorods that maintained full exposure and high activity of ZnO NPs as well as better killing efficiency than those with clustered ZnO NPs. The mechanism analysis demonstrated that the bacteria-adsorbed capacity of Pal and the enhanced contact of small ZnO NPs with bacterial cells leading to intensified membrane-damage and intracellular metabolic imbalance are the main bactericidal actions of ZnO/Pal nanocomposites. This study first gave insight into the structure-related antibacterial behavior of ZnO/Pal nanocomposites, and provides an improved green way to design efficient clay-supported ZnO antibacterial nanomaterials. [ABSTRACT FROM AUTHOR]

In recent years, a relatively novel paradigm known as sustainable development has been introduced in response to concerns regarding the adverse impact of industrial activities on the environment and society. Managers in the food sector have been attempting to incorporate the principle of sustainable development in their supply chains owing to the paramount importance of social and environmental considerations in creating a competitive advantage for food products. To this end, we propose a multi-objective linear mathematical model considering the three dimensions of sustainability, i.e. economic, environmental, and social, to design a sustainable food supply chain. Given today's volatile business environment, we employ a robust optimization model by incorporating Conditional Value-at-Risk into the configuration of two-stage stochastic programming to tackle uncertainty and take up a risk-averse strategy in supply chain design. The model aims to identify the optimal production and delivery times of the products, investigate the effects of their perishability characteristic on inventory decisions, and assess the financial and environmental advantages of transportation decisions to improve the sustainability of logistics operations. A novel version of fuzzy goal programming approach is applied to solve the proposed model. Next, the applicability of the proposed model and its solution method is verified based on computational experiments on a real-world case study of a processed food company. Lastly, conflicts between the sustainability aspects are examined, and several sensitivity analyses on risk-aversion parameters are performed to provide managerial insights for industry executives seeking to optimize their network concerning sustainability issues and well-performance under worst-case scenarios. [ABSTRACT FROM AUTHOR]

A two‐step experimental design was followed to develop a potentiometric solid contact ion‐selective electrode for sertaconazole (STN) determination. A full factorial design was first employed in screening for the best cation exchanger, ionophore and conducting polymer. Amounts of the selected cation exchanger; tetrakis[3,5‐bis(trifluoromethyl)phenyl] borate (TFPB), and ionophore; calix[6]arene (CX6), incorporated in STN sensing membrane were then optimized with the aid of face centered composite design. Calibration slope, detection limit and electrode selectivity in presence of another imidazole‐classified drug; econazole, were the selected responses in both designs. The optimized ion‐sensing membrane, containing 1.0 mg TFPB and 9.9 mg CX6, showed enhanced responses compared to the primarily screened ones. This optimized electrode exhibited a linear response over a concentration range of 1.0×10−6‐−1.0×10−3 M with a Nernstian slope of 57.50 mV/decade. The detection limit was lowered by about one order of magnitude via this optimization to equal 3.16×10−7 M. The proposed electrode was successfully challenged for STN determination in the presence of other imidazoles. It was then used for STN determination in cream and spiked plasma as an example of biological fluid. Our proposed potentiometric method was finally compared to the reported chromatographic ones in terms of sensitivity, and greenness evaluation by the widely applicable Analytical GREEnness (AGREE) tool. The comparison revealed the superiority of our method in terms of sensitivity and sustainability. [ABSTRACT FROM AUTHOR]

Designing and making sustainable plastics is especially urgent to reduce their ecological and environmental impacts. However, it remains challenging to construct plastics with simultaneous high sustainability and outstanding comprehensive performance. Here, a composite strategy of in situ polymerizing a petroleum‐based monomer with the presence of an industrialized bio‐derived polymer in a quasi‐solvent‐free system is introduced, affording the plastic with excellent mechanical robustness, impressive thermal and solvent stability, as well as low energy, consumes during production, processing, and recycling. Particularly, the plastic can be easily processed into diverse shapes through 3D printing, injection molding, etc. during polymerization and further reprocessed into other complex structures via eco‐friendly hydrosetting. In addition, the plastic is mechanically robust with Young's modulus of up to 3.7 GPa and tensile breaking strength of up to 150.2 MPa, superior to many commercially available plastics and other sustainable plastics. It is revealed that hierarchical hydrogen bonds in plastic predominate the well‐balanced sustainability and performance. This work provides a new path for fabricating high‐performance sustainable plastic toward practical applications, contributing to the circular economy. [ABSTRACT FROM AUTHOR]

Background: The COVID-19 pandemic disrupted health systems around the globe. Lessons from health systems responses to these challenges may help design effective and sustainable health system responses for future challenges. This study aimed to 1/ identify the broad types of health system challenges faced during the pandemic and 2/ develop a typology of health system response to these challenges. Methods: Semi-structured one-on-one online interviews explored the experience of 19 health professionals during COVID-19 in a large state health system in Australia. Data were analysed using constant comparative analysis utilising a sociotechnical system lens. Results: Participants described four overarching challenges: 1/ System overload, 2/ Barriers to decision-making, 3/ Education or training gaps, and 4/ Limitations of existing services. The limited time often available to respond meant that specific and well-designed strategies were often not possible, and more generic strategies that relied on the workforce to modify solutions and repair unexpected gaps were common. For example, generic responses to system overload included working longer hours, whilst specific strategies utilised pre-existing technical resources (e.g. converting non-emergency wards into COVID-19 wards). Conclusion: During the pandemic, it was often not possible to rely on mature strategies to frame responses, and more generic, emergent approaches were commonly required when urgent responses were needed. The degree to which specific strategies were ready-to-hand appeared to dictate how much a strategy relied on such generic approaches. The workforce played a pivotal role in enabling emergent responses that required dealing with uncertainties. [ABSTRACT FROM AUTHOR]

In recent years, the demand for environmentally sustainable materials has led to the exploration of biodegradable composites as alternatives to fossil‐based polymeric matrices. Among these, poly‐ε‐caprolactone (PCL) has emerged for its versatility and broad applicability. However, challenges such as limited mechanical strength and thermal stability demand innovative approaches for enhancement. This study focuses on the development and characterization of hierarchical composites of PCL, ramie fibers, and graphene oxide (GO) to address these challenges. Differential scanning calorimetry (DSC), x‐ray diffraction (XRD), contact angle, surface energy, mechanical properties (impact and tensile), scanning electron microscopy (SEM), and ecotoxicity assays were employed for evaluation. Results indicate that the inclusion of GO and ramie fibers alters the thermal properties, increasing melting enthalpy and crystallinity due to GO's nucleating effect and fiber‐induced steric hindrance. Increased hydrophilicity and surface free energy suggest enhanced biodegradation potential. Ecotoxicity tests confirm non‐toxicity, while SEM reveals low interfacial adhesion between the fiber and matrix. Tensile tests reveal no synergistic effects, although GO enhances biodegradation without compromising mechanical integrity. The presence of GO and ramie fibers does not induce toxicity, as evidenced by normal seedling growth. While hybridization does not significantly impact mechanical properties, GO offers avenues for enhancing biodegradability and expanding ramie fiber applications. This study highlights the impacts of filler integration on the properties of PCL, indicating pathways for tailored material design aimed at sustainable solutions. [ABSTRACT FROM AUTHOR]

In an era marked by increasing environmental challenges affecting human well‐being, traditional acoustic materials struggle to effectively handle the diverse and multi‐frequency nature of harmful environmental noises. This has spurred a demand for innovative acoustic metamaterial solutions by utilizing sustainable design strategies. This research introduces tunable Schwarz metamaterial capable of transforming into a soft meta‐foam to solve the complex problems of varying environmental noises. This study primarily focuses on adjusting single to multiple sound‐blocking bandgaps mechanism using a multi‐layered approach, incorporating the Schwarz P‐type triply periodic minimal surface (TPMS) and its elective soft foam counterpart, known as tunable Schwarz meta‐foams (TSMF‐x). The tunable design parameters of the unit cell, multi‐layered TPMS, and soft programmable TSMF‐lichen version are comprehensively explored including a fire‐safety test. The results demonstrate these enhanced flame retardant meta‐foam families have the potential to be used for mid‐to‐high‐frequency environmental noises in industrial equipment and smart homes for sustainable architecture and environmental health applications. [ABSTRACT FROM AUTHOR]

While some green solutions and advanced materials have been proposed in recent decades to improve on traditional conservation processes, conservation practice still uses petroleum-based compounds and procedures that lack time- or energy-efficiency, and are not sustainable. Tackling these issues, the GREENART project (GREen ENdeavor in Art ResToration, Horizon Europe, 2022–2025) is developing green and sustainable systems for the remedial and preventive conservation of works of art, following a 'safe and sustainable by design' approach where green components are firstly screened and then used to formulate new materials. This contribution reviews traditional and state-of-the-art materials used in protective coatings, foams and packaging materials, consolidants, cleaning systems, and monitoring tools, and introduces the novel solutions the GREENART project is developing for each of these classes. Some of the new products are already being assessed, and the main processes in the formulation of the solutions are outlined. Life cycle assessment will be carried out before the commercial production of the new systems to demonstrate their full sustainability. Finally, perspectives are discussed, highlighting the role of GREENART in promoting a green transition for cultural heritage preservation. [ABSTRACT FROM AUTHOR]

Renewable energy sources are playing a leading role in today's world. However, integrating these sources into the distribution network through power electronic devices can lead to power quality (PQ) challenges. This work addresses PQ issues by utilizing a shunt active power filter in combination with an Energy Storage System (ESS), a Wind Energy Generation System (WEGS), and a Solar Energy System. While most previous research has relied on complex methods like the synchronous reference frame (SRF) and active-reactive power (pq) approaches, this work proposes a simplified approach by using a neural network (NN) for generating reference signals, along with the design of a five-level reduced switch voltage source converter. The gain values of the proportional-integral controller (PIC), as well as the parameters for the shunt filter, boost, and buck-boost converters in the WEGS and ESS, are optimally selected using the horse herd optimization algorithm. Additionally, the weights and biases for the neural network (NN) are also determined using this method. The proposed system aims to achieve three key objectives: (1) stabilizing the voltage across the DC bus capacitor; (2) reducing total harmonic distortion (THD) and improving the power factor; and (3) ensuring superior performance under varying demand and PV irradiation conditions. The system's effectiveness is evaluated through three different testing scenarios, with results compared against those obtained using the genetic algorithm, biogeography-based optimization (BBO), as well as conventional SRF and pq methods with PIC. The results clearly demonstrate that the proposed method achieves THD values of 3.69%, 3.76%, and 4.0%, which are lower than those of the other techniques and well within IEEE standards. The method was developed using MATLAB/Simulink version 2022b. [ABSTRACT FROM AUTHOR]

This account summarizes the impact that the quest for sustainability is having on the field of organic polyconjugate molecules and polymers for plastic (opto)electronics. While at the proof-of-concept level, the design criteria as well as the preferred synthetic strategies to access new and improved materials have been dominated by the need for performance. The ongoing transition from the lab environment to the industrial scale imposes strict limitations on the cost and overall environmental impact of new materials. We here summarize our efforts on the development of new design criteria and synthetic strategies aimed at improving sustainability – without compromising performance – in organic polyconjugated molecules. The article is composed of three sections: Introduction and motivation, sustainability through improved synthetic methods and through improved design. Outline 1 Introduction and Motivation 2 Sustainable Reaction Methods 2.1 The New Tools: Reactions in Aqueous Solution of Surfactants 2.2 Intrinsically More Sustainable Reactions: Direct Arylation 2.3 Sustainable Multistep Protocols: Combining Micellar, Solventless, and Mechanochemical Methods 3 Sustainability as a Design Criterion: De Novo Design 4 Conclusion [ABSTRACT FROM AUTHOR]

This paper reports recent advancements in chitosan‐based antimicrobial biomaterials that aim to address the issue of antimicrobial resistance (AMR). Today, AMR is one of the most significant public health challenges the world is facing. To combat the overuse of antibiotics, a range of materials, including advanced nanosized polymers, have been explored as potential antimicrobial agents. In this direction, chitosan scores highly because of its unique combination of properties such as biodegradability, biocompatibility, bioactivity, non‐toxic, and, most importantly, its intrinsic antibacterial and antifungal activity. Herein, an overview of chitosan and its derivatives as potential alternatives to conventional antimicrobial therapeutics is reported. This review starts with understanding the AMR mechanism, which is critical for developing suitable materials for treating infectious diseases. Then, the inherent characteristics, modes of antimicrobial action, and factors that impact the antimicrobial effectiveness of chitosan and its derivatives are discussed. The authors further summarize various clinical trial results of chitosan‐based materials as antimicrobial agents. Finally, various antimicrobial applications of chitosan‐based materials are reported. In summary, this review offers new insights into the design of chitosan‐based sustainable materials for various antimicrobial applications. [ABSTRACT FROM AUTHOR]

Vernacular architecture offers valuable technological and typological solutions rooted in knowledge systems that connect environmental, social, economic, and cultural contexts. This paper introduces the Heritage for People Platform, a collaborative digital tool developed under the VerSus+ project (Creative Europe Program), aimed at organising and disseminating vernacular architectural knowledge with a focus on sustainable practices that are both culturally and environmentally conscious. The platform builds upon lessons learned from similar projects, offering key improvements such as the adoption of a Case-Based Reasoning methodology, which organises examples by geographic location, materials, and intervention types. A structured classification system based on sustainability principles and strategies enables cross-disciplinary research and comparison. The design process was highly participatory, incorporating user feedback at every stage to ensure the platform is accessible to a wide range of users, including designers, scholars, craftspeople, and the general public. A cross-device, user-centered approach further broadens its accessibility. The platform provides a public, web-based geospatial repository where users can create, update, and explore a dynamic collection of artefacts, design models, people, and institutions from across the globe. This tool marks a significant advance in promoting and preserving both physical and intangible heritage, with strong educational and practical applications for sustainable architecture. The paper details the theoretical framework and real-world potential of the platform as a critical resource for promoting sustainability in the built environment. [ABSTRACT FROM AUTHOR]

Definition: Japanese prefabricated housing manufacturers have gained international recognition for their innovative approaches to the whole design process, ranging from initial design to innovative cutting-edge technologies, state-of-the-art automated production lines, meticulous workmanship, and mass customisation. In this entry, three manufacturers (Daiwa House, Sekisui House, and Misawa Homes) were selected as case studies for close examination. By studying these leading companies, researchers and industry professionals can gain valuable insights into best practices, challenges, and innovations within the Japanese prefabricated housing sector. The research methods involved a desktop study of available information on websites, articles, and reports, as well as undertaking two study tours on residential sustainable design in Japan in 2022 and 2023. These three manufacturers were discussed and compared with respect to their development trajectories, design customisation, research capabilities and technological advancements, sustainable initiatives and procurement, as well as their after-sale services. They have demonstrated their adaptability and flexibility in response to natural disasters and the transformation of the needs in society. They are all keen on reducing the environmental impacts of their work towards zero carbon emissions and a sustainable future. [ABSTRACT FROM AUTHOR]

This study presents an innovative approach to interdisciplinary education by integrating biology, engineering and art principles to foster holistic learning experiences for middle-schoolers aged 11–12. The focus lies on assembling mycelium bricks as engineered living materials, with promising applications in sustainable construction. Through a collaborative group task, children engage in the hands-on creation of these bricks, gaining insights into mycology, biomaterials engineering and artistic expression. The curriculum introduces fundamental concepts of mycelial growth and its potential in sustainable material development. Children actively participate in fabricating 3D forms (negative and positive) using mycelium bricks, thereby gaining practical knowledge in shaping and moulding living materials. This hands-on experience enhances their understanding of biological processes and cultivates an appreciation for sustainable design principles. The group task encourages teamwork, problem-solving and creativity as children collaboratively compose structures using mycelium bricks. Integrating art into the activity adds a creative dimension, allowing participants to explore aesthetic aspects while reinforcing the project's interdisciplinary nature. Conversations about the material's end-of-life and decomposition are framed within the broader context of Nature's cycles, facilitating an understanding of sustainability. This interdisciplinary pedagogical approach provides a model for educators seeking to integrate diverse fields of knowledge into a cohesive and engaging learning experience. The study contributes to the emerging field of nature-inspired education, illustrating the potential of integrating living materials and 3D-understanding activities to nurture a holistic understanding of science, engineering and artistic expression in young learners. [ABSTRACT FROM AUTHOR]