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1. Synthesis of Cytimidine through a One-Pot Copper-Mediated Amidation Cascade.

Author

Catherine M. Serrano and Ryan E. Looper

Subjects
*ORGANIC synthesis, *COPPER, *FRAGMENTATION reactions, *BENZAMIDE, *NUCLEOTIDE sequence, *BIODIVERSITY
Abstract

A concise synthesis of cytimidine was developed utilizing tandem Cu-mediated N-aryl amidations followed by global deprotection. This sequence exploits a regioselective coupling of an iodobenzamide with a halopyrimidine that allows the union of three fragments in a single synthetic manipulation and will permit the efficient and rapid diversification of the cytimidine core. [ABSTRACT FROM AUTHOR]

Published
2011
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