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Pure chitosan (CS) and hybrid ionic liquid-chitosan membranes loaded with 5 wt% 1-ethyl-3-methylimidazolium acetate ([emim][Ac]) ionic liquid were prepared in order to improve the thermal behavior of supported ionic liquid membranes (SILMs) for CO2 separation. Gas permeability, solubility and diffusivity were evaluated in the temperature range 298-323 K. The temperature influence was well described in terms of the Arrhenius-van't Hoff exponential relationships. Activation energies were calculated and compared with those obtained for SILMs with the same ionic liquid. The introduction of this ionic liquid in the hybrid solid membrane decreases the permeability activation energy, leading to a lower influence of the temperature in the permeability and diffusivity. Moreover, the thermal behavior is similar to pure chitosan membranes, and the mechanical strength and flexibility were improved due to the introduction of the ionic liquid in the polymer matrix. [ABSTRACT FROM AUTHOR]

The Kardar-Parisi-Zhang (KPZ) equation is a paradigmatic model of nonequilibrium low-dimensional systems with spatiotemporal scale invariance, recently highlighting universal behavior in fluctuation statistics. Its space derivative, namely the noisy Burgers equation, has played a very important role in its study, predating the formulation of the KPZ equation proper, and being frequently held as an equivalent system. We show that, while differences in the scaling exponents for the two equations are indeed due to a mere space derivative, the field statistics behave in a remarkably different way: while the KPZ equation follows the Tracy-Widom distribution, its derivative displays Gaussian behavior, hence being in a different universality class. We reach this conclusion via direct numerical simulations of the equations, supported by a dynamic renormalization group study of field statistics. [ABSTRACT FROM AUTHOR]

Symmetries play a conspicuous role in the large-scale behavior of critical systems. In equilibrium they allow us to classify asymptotics into different universality classes, and out of equilibrium, they sometimes emerge as collective properties which are not explicit in the "bare" interactions. Here we elucidate the emergence of an up-down symmetry in the asymptotic behavior of the stochastic scalar Burgers equation in one and two dimensions, manifested by the occurrence of Gaussian fluctuations even within the time regime controlled by nonlinearities. This robustness of Gaussian behavior contradicts naive expectations due to the detailed relation--including the lack of up-down symmetry--between the Burgers equation and the Kardar-Parisi-Zhang equation, which paradigmatically displays non-Gaussian fluctuations described by Tracy-Widom distributions. We reach our conclusions via a dynamic renormalization group study of the field statistics, confirmed by direct evaluation of the field probability distribution function from numerical simulations of the dynamical equation. [ABSTRACT FROM AUTHOR]