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1. Oxidative Synthesis of α‐Nitroketones from α‐Substituted Malononitrile and Nitromethane Using Molecular Oxygen without Condensation Reagents.

Author

Hayashi, Yujiro, Cocco, Emanuele, Odaira, Hinata, Matoba, Hiroaki, and Mori, Naoki

Subjects
*NITROMETHANE, *MALONONITRILE, *CONDENSATION, *OXYGEN
Abstract

We developed an oxidative synthetic method for α‐nitroketones from α‐substituted malononitriles and nitromethane under molecular oxygen. Only base and molecular oxygen are necessary without condensation reagents; this is an environmentally benign synthesis. [ABSTRACT FROM AUTHOR]

Published
2024
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