1. A new method for reducing impurities in clay minerals.
- Author
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Lopes, Joaldo S., Morais, Marcelo L., Morais, Alan I.S., Bezerra, Roosevelt D.S., Furtini, Josy A.O., and Silva Filho, Edson C.
- Subjects
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X-ray fluorescence , *SOIL formation , *HETEROGENEOUS catalysis , *ADSORPTION capacity , *MATERIALS analysis - Abstract
The processing of clay minerals consists, among other steps, in the removal of isolated mineral impurities, that is, not associated to crystalline structure of clay minerals, such as fractions of quartz and feldspars, originating from the process of soil formation. Thus, this work evaluated a sustainable method to reduction of isolated mineral impurities, in 4 in natura soil samples from Maranhão/Brazil, containing clay minerals. The method consisted of dispersing the samples only in water under high rotation and separating the impurities by sieving and decanting. The water and clay fraction were recovered from a manufactured solar evaporator and the clay fraction analyzed: X-ray diffraction (XRD) revealed a reduction in the intensities of mineral impurities, largely quartz, and a significant increase in the intensity corresponding to clay minerals; X-ray fluorescence (XRF) demonstrated a decrease in the SiO 2 /Al 2 O 3 ratio, indicating quartz removal; Fourier transform infrared analysis (FTIR) indicated removal of organic material; thermal analysis (TG/DTG) revealed an increase in the percentage of structural water loss, suggesting an increase in clay mineral content, and adsorption/desorption isotherms of N 2 demonstrated an increase in the surface areas and adsorption capacity of the benefited samples. The process yields obtained demonstrated compatibility with the particle size of the samples, with more expressive results for the more clayey ones. Thus, the investigated method, low cost and sustainable, proved to be viable and effective in obtaining clay minerals with reduced presence of isolated impurities, promoting considerable improvements in their properties, and favoring various technological applications, such as adsorption, heterogeneous catalysis, synthesis of mesoporous materials, among others. • A sustainable processing method for clay minerals has proven effective in reducing isolated impurities. • Significant reduction in the intensities of reflections from impurities and an increase in those from clay minerals. • Significant reduction of free quartz of in natura samples, with a decrease in the SiO 2 /Al 2 O 3 ratio. • Significant increase in the N 2 adsorption capacity and surface areas of the benefited samples. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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