1. Improving the electrochemical performance of sodium-ion batteries with Zn1-xMnxO anode (0≤x≤0.2).
- Author
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Hussain, Abrar, Hussain, Muneer, Hussain, Anjum, Alam, Manawwer, Khan, Asim, Idrees, Memona, Ahmad, Nisar, Abbas, Syed Mustansar, and Khan, Muhammad Tahir
- Subjects
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SODIUM ions , *BAND gaps , *DOPING agents (Chemistry) , *ENERGY bands , *STORAGE batteries - Abstract
The facile co-precipitation technique is used to synthesize Zn 1-x Mn x O (0≤x ≤ 0.2) nanoparticles. It has been investigated that Mn-doped ZnO significantly improves the electrochemical performance of sodium-ion batteries (SIBs) anode. The PXRD measurements confirm the wurtzite structure of bare and doped ZnO. The FESEM reveals that the synthesized samples have almost identical morphologies, and the doping concentration is confirmed by the EDX analysis. DRS analysis reveals that increasing the concentration of Mn leads to a decrease in band gap energy. The specific surface area and pore size of the Zn 0.8 Mn 0.2 O is 304.5 m2 g−1 and 10–15 nm, respectively. Among all the prepared samples, the Zn 0.8 Mn 0.2 O demonstrates the largest specific capacity (312.4 mAh g−1) with better cycling stability after 200 cycles, rapid charge/discharge capability (239.9 mAh g−1 at 5 A g−1) than those of pure ZnO which exhibit specific capacity of only 167.1 mAh g−1 at the completion of 200th cycle. [Display omitted] • Mn-doped ZnO was fabricated through a co-precipitation technique. • Electrochemical performance was investigated in SIBs. • Hexagonal wurtzite structure of Mn-doped ZnO facilities Na+ ion transportation. • Zn 0.8 Mn 0.2 O has the highest specific capacity (312.4 mAh g−1) after 200 cycles. • Zn 0.8 Mn 0.2 O presents an excellent rate performance of 239.9 mAh g−1 at 5 A g−1. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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