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The efficiency of photocatalysts depends largely on the accessibility of reaction species to the active centre, the electron transfer and geometric matching between the active surface of the catalyst and reaction species. In this work, we successfully synthesized and designed one two-dimensional Mn(II) MOF with [Mn2(H2L1)(H2O)2(DMF)2]n·(CH3CH2OH)n (HSTC 3) by using MnCl2·4H2O and 5,5′-(anthracene-9,10-diyl)diisophthalic acid (H4L1), in which the adjacent layers are stacked with weak interactions, and the huge gap leads to the interpenetration between layers to form a 2D + 2D → 3D interpenetration frame. Based on the particularity of the structure of HSTC 3, ultrasonic wall breaking methods were tried to successfully peel HSTC 3 into nanosheets (HSTC 3-NS), thus achieving a significant improvement in a series of optoelectronic properties due to exposure to more active centres for HSTC 3-NS. These results significantly enhance the photocatalytic selective oxidation of thioether. This study provides a new insight into the post-synthesis modification of MOF photocatalyst and their application in photocatalytic organic synthesis. [ABSTRACT FROM AUTHOR]

Non-isothermal crystallization kinetics of montmorillonite (MMT)/polyamide 610 (PA610) composites were readily prepared by in situ melt polymerization followed by a full investigation in terms of their microstructure, performance, and crystallization kinetics. The kinetic models of Jeziorny, Ozawa, and Mo were used in turn to fit the experimental data, in all of which Mo's analytical method was found to be the best model for the kinetic data. Differential scanning calorimetry (DSC) and transmission electron microscopy (TEM) studies were used to investigate the isothermal crystallization behavior and MMT dispersion levels in the MMT/PA610 composites. The experiment results revealed that low MMT content can promote the PA610 crystallization, whilst high MMT content result in MMT agglomeration, and reduce the PA610 crystallization rate. [ABSTRACT FROM AUTHOR]

C16H17N, orthorhombic, Pbca (no. 61), a = 10.3706(10) Å, b = 8.3879(7) Å, c = 29.555(3) Å, V = 2,570.9(4) Å3, Z = 8, Rgt(F) = 0.0579, wRref(F2) = 0.1327, T = 293(2) K. [ABSTRACT FROM AUTHOR]