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1. [CoAu2(CN)4(MITpPY)2(H2O)2]n: A new 2-D Interdigitating Complex Containing Dicyanoaurate(I) Anion, a Radical, and Cobalt(II) Ion Incorporating Gold···Gold and Hyd.

Author

Hui-Bo Zhou, Shun-Ping Wang, Wen Dong, Zhan-Quan Liu, Qing-Lun Wang, Dai-Zheng Liao, Zong-Hui Jiang, Shi-Ping Yan, and Peng Cheng

Subjects
*COBALT compounds, *ANIONS, *HYDROGEN bonding, *MAGNETIC properties, *SPECTRUM analysis, *METAL complexes
Abstract

A novel complex, {[CoAu2(CN)4(NITpPy)2(H2O)2]}n, containing the cobalt(II) ion, dicyanoaurate(I) anion, and nitronyl nitroxide radical building blocks, has been prepared and structurally characterized by single-crystal X-ray analysis. The structure of complex 1 illustrates that aurophilicity and hydrogen bonding interactions increase dimensionality, generating a 2-D interdigitating system. The spectroscopic and magnetic properties have been investigated. rogen Bonding Interactions. [ABSTRACT FROM AUTHOR]

Published
2004
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