1. Second-generation biofuels by co-processing catalytic pyrolysis oil in FCC units.
- Author
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Thegarid, N., Fogassy, G., Schuurman, Y., Mirodatos, C., Stefanidis, S., Iliopoulou, E.F., Kalogiannis, K., and Lappas, A.A.
- Subjects
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BIOMASS energy , *CATALYTIC activity , *PYROLYSIS , *CATALYTIC cracking , *DEOXYGENATION - Abstract
Abstract: Previous research showed that hydrodeoxygenated (HDO) pyrolysis-oils could successfully be co-processed with vacuum gasoil (VGO) in a labscale fluid catalytic cracking (FCC) unit to bio-fuels. Typically the hydrodeoxygenation step takes place at ∼300°C under 200–300bar of hydrogen. Eliminating or replacing this step by a less energy demanding upgrading step would largely benefit the FCC co-processing of pyrolysis oils to bio-fuels. In this paper a bio-oil that has been produced by catalytic pyrolysis (catalytic pyrolysis oil or CPO) is used directly, without further upgrading, in catalytic cracking co-processing mode with VGO. The results are compared to the co-processing of upgraded (via HDO) thermal pyrolysis oil. Though small but significant differences in the product distribution and quality have been observed between the co-processing of either HDO or CPO, they could be corrected by further catalyst development (pyrolysis and/or FCC), which would eliminate the need for an up-stream hydrodeoxygenation step. Moreover, the organic yield of the catalytic pyrolysis route is estimated at approximately 30wt.% compared to an overall yield for the thermal pyrolysis followed by a hydrodeoxygenation step of 24wt.%. [Copyright &y& Elsevier]
- Published
- 2014
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