Unal, Fatma Aydin, Ok, Semih, Unal, Murat, Topal, Sebahat, Cellat, Kemal, and Şen, Fatih
In this paper, we present the synthesis of different metal-doped TiO 2 compounds (pure TiO 2 , Fe doped TiO 2 (Fe x Ti 1-x O 2), Ni doped TiO 2 (Ni x Ti 1-x O 2), Zr doped TiO 2 (Zr x Ti 1-x O 2)) thin films in order to improve the performance of dye-sensitized solar cell (DSSC). Undoped TiO 2 particles and Ni, Fe and Zr transition metals doped TiO 2 particles were synthesized by the sol-gel method for the utilization of the anodic part of the DSSC. The cathode of the DSSC was a carbon electrode. Fluorine Doped Tin Oxide (FTO) coated electrodes on the glass surfaces and electrolyte solution containing I/I 2 was obtained a dye-sensitized solar cell. Pure TiO 2 and Ni, Fe and Zr doped TiO 2 nanopowders were characterized by DLS, XRD, SEM/EDX, and UV–Vis Spectroscopy. The thin films have been deposited on the glass substrate by the doctor blade method. The effect of synthesized nano-materials on the cell performance of DSSC was investigated by J-V curves. J-V characterization of solar cell module shown that the highest power conversion efficiency was the solar cell module that fabricated with 10% of Zr doped TiO 2 with the short circuit current (Jsc) and the efficiency was at 0.13 mA cm−2 and 0.020%, respectively. However, yields on the cell performance of other nanomaterials were obtained as 0.019%, 0.017% and 0.015% for pure TiO 2 , Fe doped TiO 2, and Ni doped TiO 2 , respectively. • Different metal-doped TiO 2 compounds were synthesized by the sol-gel method. • Pore size distribution, energy differences of valance band and band gap affected photocatalytic activity. • J-V characterization of solar cell module showed Ni-doped TiO 2 gives best efficiency. [ABSTRACT FROM AUTHOR]