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1. Nature's Inventory of Halogenation Catalysts: Oxidative Strategies Predominate.

Author

Vaillancourt, Frédéric H., Ellen Yeh, David A. Vosburg, Sylvie Garneau!Tsodikova, and Christopher T. Walsh

Subjects
*CATALYSTS, *OXIDATION, *HALOGENATION, *NATURAL products, *ENZYMES, *CHEMICAL bonds, *CHLORINATION, *CATALYSIS
Abstract

The article provides insights into oxidative strategies to create halogenated natural catalysts. It also discusses oxidating logic in chlorinating, brominating and iodinating enzymes, nonoxidative construction of the C-F bond, timing of chlorination during assembly line catalysis, cryptic chlorination during cyclopropyl ring construction at unactivated carbons and unifying perspective for oxidative catalysis during biological halogenations.

Published
2006
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