1. Microkinetic insights into temperature pulsing for accelerating ammonia decomposition.
- Author
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Railkar, Rucha and Vlachos, Dionisios G.
- Subjects
- *
HEAT pulses , *HYDROGEN storage , *LOW temperatures , *HIGH temperatures , *CARBON dioxide mitigation - Abstract
We investigate ammonia decomposition under temperature pulsing toward enhancing H 2 production. We observed up to a 10x increase in conversion with rapid pulsing under certain conditions. Our kinetic analysis identified the association of N 2 as the rate-limiting step, showing significant rate enhancement by pulsing at high frequencies and temperature amplitudes. These findings highlight that rapid heat addition and removal, through joule heating, can boost performance and assist with decarbonization. [Display omitted] • Rapid pulse heating of ammonia decomposition can increase ∼10x the ammonia conversion compared to conventional heating. • Pulse heating enhances the N 2 dissociation step by promoting NH 2 ∗ and reducing the N∗ coverage. • Low average temperatures and high frequency-temperature amplitude maximize performance enhancement. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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