1. Paramagnetic behaviour of silver nanoparticles generated by decomposition of silver oxalate.
- Author
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Le Trong, Hoa, Kiryukhina, Kateryna, Gougeon, Michel, Baco-Carles, Valérie, Courtade, Frédéric, Dareys, Sophie, and Tailhades, Philippe
- Subjects
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SILVER nanoparticles , *PARAMAGNETISM , *CHEMICAL decomposition , *OXALATES , *MAGNETIC susceptibility - Abstract
Silver oxalate Ag 2 C 2 O 4 , was already proposed for soldering applications, due to the formation when it is decomposed by a heat treatment, of highly sinterable silver nanoparticles. When slowly decomposed at low temperature (125 °C), the oxalate leads however to silver nanoparticles isolated from each other. As soon as these nanoparticles are formed, the magnetic susceptibility at room temperature increases from −3.14 10 −7 emu.Oe −1 .g −1 (silver oxalate) up to −1.92 10 −7 emu.Oe −1 .g −1 (metallic silver). At the end of the oxalate decomposition, the conventional diamagnetic behaviour of bulk silver, is observed from room temperature to 80 K. A diamagnetic-paramagnetic transition is however revealed below 80 K leading at 2 K, to silver nanoparticles with a positive magnetic susceptibility. This original behaviour, compared to the one of bulk silver, can be ascribed to the nanometric size of the metallic particles. [ABSTRACT FROM AUTHOR]
- Published
- 2017
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