Search

In this work, the photoconversion of 1-chloronaphthalene (CN-1) and 2,3-dichlornaphthalene (CN-10) under the simulated sunlight had been studied. The results showed that the photoconversion of CN-1 and CN-10 obeyed the first-order kinetics model. NO2−, NO3−, Fe3+ and Fe2+ extensively present in natural water can accelerate CN-1 photoconversion via generating ·OH, which may induce indirect photooxidation of CN-1. The photoproducts were treated by the derivatization method and analyzed by GC-MS after being irradiated for 6 h. Ten products were characterized for CN-1 and CN-10, and there were six common products. On this basis, the photoconversion pathways of CN-10 and CN-1 were proposed, and both of them have a similar conversion mechanism. [ABSTRACT FROM AUTHOR]

Four earthquakes above magnitude 5.0 in Yunnan and Tibet, China occurred from 2010 to 2011. By calculating the tidal-force changes induced by celestial bodies in this region, we found that the earthquakes occurred when tidal-forces continuously grew from low to peak levels and approached the maximum amplitude phase, which indicated a tidal-force that had a trigger or inducing effect of active tectonic earthquakes when the ground stress reached a critical point. At the same time analyzing the abnormal changes of outgoing longwave radiation (OLR), along with the tidal cycle, indicated that the regional distribution of the enhancement region of OLR anomalies was closely related to geologic structure, especially active faults. The OLR radiation anomaly evolved: an initial infrared rise, followed by an enhancement reaching peak, attenuation, and then a return to normal. The entire process was similar to changes observed in rock-breaking process under stress loads. Our investigation showed that the tidal-force changes caused by celestial bodies could trigger an earthquake when tectonic stress reached its critical breaking point, and the OLR anomaly was the radiation signature of the change in seismic tectonic stress. Therefore, the method of combining measurements of the tidal-force changes induced by celestial bodies with those of thermal-anomaly changes has some practical value for detecting the precursor state of impending earthquakes. [ABSTRACT FROM AUTHOR]

The cycle process of the tidal force of celestial body for Lushan M7.0 earthquake, occurred in Lushan county of Sichuan, China on April 20, 2013, was calculated. The earthquake occurred at the lowest point phase. It indicated that the type of seismogenic fault that the tide force acted on belonged to the thrust fault. According to the tidal cycle, the abnormal air temperature change was analyzed based on National Center for Environmental Prediction satellite data around the whole China before and after the earthquake. The result showed that the air temperature changed evidently with the tide force changing. In temporal, the change went through: initial air temperature rise → strength → reaching abnormal peak → gradually decline; in spatial, the abnormal area winded its way along the margin of the southern Qinghai-Tibet Plateau and went through: scattered→conversion→ scattered procession. The procession was similar to the change procession of a rock breaking under the stress loading. This shows that the stress change of rock may cause the air temperature change in the atmosphere before and after earthquake. It indicated that the tidal force of celestial body could trigger the earthquake, when the tectonic stress reaches its critical broken point and the air temperature anomaly was proportional to the seismic tectonic stress change. It was useful to combine air temperature and tidal force in earthquake precursory. [ABSTRACT FROM AUTHOR]

The photochemistry of organic pollutants has received increasing attention in ice and snow. In this work, the photoconversion of gamma-hexachlorocyclohexane (γ-HCH) under UV irradiation was investigated in water, snow and ice. The photoconversion rate, products and mechanisms were inspected, and the effect of inorganic ions (NO2-, NNO3-, HCNO3- and Fe2+) was discussed. The results showed that γ-HCH could be photoconverted in water, snow and ice, with the photoconversion rate being fastest in snow, and slowest in ice. All photoconversion could be described by the first-order kinetics model. In water, snow and ice, the common photoproducts of γ-HCH were alphahexachlorocyclohexane (α-HCH) and pentachlorocyclohexene. α-HCH was generated by a change in the bonding of a chlorine atom in γ-HCH; pentachlorocyclohexene was generated by the removal of a molecule of chlorine hydride from a molecule of γ-HCH. Different concentrations of NO2 -, NNO3- and HCNO3- all inhibited the photoconversion of γ-HCH, and the inhibition effect decreased with increasing concentrations of NO2 - and NNO3-, but increased with the increasing concentrations of HCNO3-. Different concentrations of Fe2+ promoted the photoconversion of γ-HCH in water and ice, but had little effect in snow. [ABSTRACT FROM AUTHOR]

Abstract: Our analysis of the continuous outgoing long wave earth radiation (OLR) indicates anomalous variations prior to a number of medium to large earthquakes. The most recent analysis of OLR is from the M9.0 Sumatra Andaman Islands mega trust event. We compared the reference fields for December 2001 to 2004 and found OLR anomalous values, >80 W/m2, (2σ) within the epicentral area on Dec 21, 2004, 5 days before the event. We used the NOAA/IR daily (one degree) and monthly (two and half degree) gridded data to differentiate between the global and seasonal variability and the transient local anomalies. The cause of such anomalies is not fully understood; one possible explanation is the existence of thermal outgoing radiation as a result of near ground air ionization and latent heat change due to change of air humidity and temperature. This phenomenon is hypothesized to be part of a relationship between tectonic stresses, electrochemical and thermodynamic processes in the atmosphere and increasing mid IR flux, all part of a family of electromagnetic (EM) phenomena related to earthquake activity. The time scale of the observed variations is a few weeks before the onset of the seismic event. In comparison with several years of data, the observed time-series preceding the earthquake had unusually high OLR. The OLR anomaly corresponds to a large area of ground coverage and coincides with the main epicentral zone. The significance of these observations is explored using data from most recent East Asian earthquake swarm of December 2004 and three other earthquakes. [Copyright &y& Elsevier]