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1. Synthesis of Alkyl Indium Reagents by Using Unactivated Alkyl Chlorides and Their Applications in Palladium-Catalyzed Cross-Coupling Reactions with Aryl Halides.

Author

Bing-Zhi Chen, Man-Ling Zhi, Chuang-Xin Wang, Xue-Qiang Chu, Zhi-Liang Shen, and Teck-Peng Loh

Subjects
*ETHANOL, *ALKYL bromides, *PALLADIUM catalysts, *ARYL halides, *INDIUM alloys
Abstract

An efficient method for the preparation of alkyl indium reagents by using unactivated and cheap alkyl chlorides as substrates in the presence of indium and LiI was developed. The thus-formed alkyl indium species effectively underwent palladium-catalyzed cross-coupling reactions with aryl halides with wide functional group tolerance. [ABSTRACT FROM AUTHOR]

Published
2018
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