1. Polymer-fibre characterisation and its role in optimum sintering and densification in rotational moulding.
- Author
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Castellanos, D., McCourt, M., Martin, P., Kearns, M., Butterfield, J., and Cassidy, P.
- Subjects
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GLASS fibers , *BIOPOLYMERS , *CONTACT angle , *MANUFACTURING processes , *COMPOSITE structures , *SINTERING - Abstract
The present work investigated the effect of polymer and fibre properties on the sintering and densification of a rotationally moulded composite part. Previous researchers have concluded that polymer characterisation is fundamental to achieving optimum composite materials processing in rotational moulding. Nevertheless, a disperse phase during sintering directly impacts the current understanding of how sintering and densification work. Lack of pressurisation during rotational moulding implies an absence of driving forces to strongly bond two materials together as necessary in composite structures. It means that sintering and densification are the fundamental phases in which two or more materials can create an interface that can transmit stresses. The present work focuses on the characterisation of the continuous and dispersed composite phases and how their properties affect the mechanisms of sintering and densification. The effect of polymer-fibre interaction during sintering was investigated by a penetration test based on a variation of the Wilhemly technique (PenTest). Attempts to automate the contact angle measurement proved challenging, so manual measurement proved to be more effective. Sintering results showed that fibre treatment has a natural effect on the polymer sintering, and the treatment chemistry can optimise adhesion. Glass fibres treated with silane in combination with rotomoulding grade resins proved to be the best fibre-resin combination for the manufacture of fibre-reinforced rotomoulding parts. Finally, results showed that polymer-fibre characterisation plays a crucial role in sintering and densification, and work is ongoing to present conclusions about how sintering and densification affect the full-scale manufacturing process. [ABSTRACT FROM AUTHOR]
- Published
- 2023
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